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1 - The Antarctic Ozone Hole, a Human-Caused Chemical Instability in the Stratosphere: What Should We Learn from It?

Published online by Cambridge University Press:  04 August 2010

Lennart O. Bengtsson
Affiliation:
Max-Planck-Institut für Meteorologie, Hamburg
Claus U. Hammer
Affiliation:
University of Copenhagen
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Summary

ABSTRACT

Atmospheric ozone plays a critical role in limiting the penetration of biologically harmful, solar ultraviolet radiation to the Earth surface. Furthermore, the absorption of ultraviolet radiation from the Sun and infrared radiation emitted from the Earth's warm surface influence temperatures in the lower stratosphere, creating dynamically stable conditions with strongly reduced vertical exchange. Through industrial emissions, ozone-depleting catalysts have increasingly been produced in the stratosphere, leading to reductions in ozone. The situation is especially grave during springtime over Antarctica, where, since the 1980s, each year almost all ozone in the 14–22 km height region is chemically destroyed. This so-called “ozone hole” was not predicted by any model and came as a total surprise to all scientists. The ozone hole developed at a least likely location. Through the emissions of chlorofluorocarbons, humankind has created a chemical instability, leading to rapid loss of ozone. A question is whether there may be other instabilities that might be triggered in the environment by human activities.

Introduction

The study of the chemistry of the atmosphere is both of immediate scientific interest and of high social relevance. We first note that the gases that are most significant for atmospheric chemistry and for the Earth's climate are not its main components – nitrogen (N2), oxygen (O2), and argon (Ar), which together with variable amounts of water vapor make up greater than 99.9% of the molecules in the Earth's atmosphere – but rather are many gases that are found only in very low concentrations. The main gases cannot be influenced significantly by human activities.

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Publisher: Cambridge University Press
Print publication year: 2001

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