Simple extended constant capacitance surface complexation models have been developed to represent the adsorption of polyaromatic dyes (9-aminoacridine, 3,6-diaminoacridine, azure A and safranin O) to kaolinite, and the competitive adsorption of the dyes with Cd. The formulation of the models was based on data from recent publications, including quantitative adsorption measurements over a range of conditions (varying pH and concentration), acid-base titrations and attenuated total reflectance-Fourier transform infrared spectroscopic data. In the models the dye molecules adsorb as aggregates of three or four, forming outer-sphere complexes with sites on the silica face of kaolinite. Both electrostatic and hydrophobic interactions are implicated in the adsorption processes. Despite their simplicity, the models fit a wide range of experimental data, thereby supporting the underlying hypothesis that the flat, hydrophobic, but slightly charged silica faces of kaolinite facilitate the aggregation and adsorption of the flat, aromatic, cationic dye molecules.

The strong adsorption to kaolinite of four polyaromatic, cationic dyes (9-aminoacridine, 3,6-diaminoacridine, azure A and safranin O), which adsorb much less to alumina or silica, was investigated by means of acid-base titrations, measurements of adsorption at varying pH and dye concentration, and by ATR-FTIR spectroscopy. The four dyes adsorb to kaolinite to similar extents, with little change over the pH range 3–10, but at higher pH (above the pKas of the dyes) the adsorption of 9-aminoacridine and 3,6-diaminoacridine decreases, that of azure A increases, and that of safranin O stays approximately constant. Although the dyes adsorb to kaolinite much more strongly than metal ions do, titration and spectroscopic data show that there is only limited chemical interaction between the adsorbed dyes and the kaolinite surface. The results indicate that electrostatic interaction between the dye molecules and the kaolinite surface is necessary for adsorption, but that hydrophobic interactions also contribute. It is proposed that the relatively hydrophobic silica faces of kaolinite, which carry low-density permanent negative charge, facilitate aggregation and adsorption of the positively charged, flat, aromatic dye molecules.

The competitive adsorption to kaolinite between Cd(II) and four polyaromatic dyes (9-aminoacridine, 3,6-diaminoacridine, azure A and safranin O) was studied in 5 mM KNO3 at 25°C. Under these conditions, Cd adsorbs to the silica face of kaolinite between about pH 4 and 6.5, but at higher pH, adsorbed Cd is progressively relocated to the crystal edges. In the presence of dye, less Cd adsorbed to kaolinite below pH 7. If sufficient dye was added to saturate the kaolinite surface, Cd adsorption was totally suppressed up to ∼pH 6. At higher pH, Cd followed the characteristic pattern for edge adsorption. In separate experiments 9-aminoacridine and azure A displaced pre-adsorbed Cd from kaolinite. The displacement curves were initially linear, with one Cd ion being displaced for every 13 dye molecules adsorbed at pH 5.5, and one Cd ion for every 35 dye molecules at pH 7.5. The interpretation of these results is that the dyes bind to kaolinite much more strongly than Cd(II) does, but only to the silica face.

Greenhouse experiments in central Texas assessed the relative importance of above- and belowground interactions of semidwarf Mit wheat and Marshall ryegrass during vegetative growth. One experiment used partitions to compare the effect of no (controls), aboveground only, belowground only, and full interaction for 75 d after planting (DAP) one wheat and nine ryegrass plants in soil volumes of 90, 950, and 3,800 ml. The results with the different soil volumes were similar. Wheat growth in the aboveground interaction only did not differ from controls. However, the full or belowground only interaction of wheat with ryegrass reduced wheat height, leaf number, tillering, leaf area, percent total nonstructural carbohydrates in shoot, and dry weights of leaves, stems, and roots 45 and 75 DAP compared to controls. Wheat in full and belowground interaction only did not differ from one another in growth. A replacement series experiment of 56 d also showed that the competitive advantage of ryegrass was relatively greater in root than in shoot growth. No allelopathic response of wheat to ryegrass occurred. While the tallness of the semidwarf wheat minimized aboveground interference by ryegrass, the root growth of the thinner and more fibrous roots of ryegrass greatly enhanced its belowground competitiveness.

Greenhouse experiments were conducted to assess the storage of nonstructural carbohydrates in the stems and roots of honey mesquite and their mobilization and utilization following defoliation by hand or clopyralid. All leaves were removed by hand from one group of plants while leaving stems intact. Another group received a foliar spray of clopyralid at a sublethal acid equivalent rate of 0.07 kg ha−1. Samplings at treatment on day 0 and at 14, 28, 42, and 58 d after treatment measured leaf area; dry weight of leaves, stems, and roots; and grams and percent total nonstructural carbohydrates in stems and roots. Controls accumulated dry weight and grams total nonstructural carbohydrates in stems and roots, while maintaining a constant percent total nonstructural carbohydrates throughout the experiment. Percent and grams total nonstructural carbohydrates in stems and roots of hand defoliated plants decreased by about one-half from day 0 to 14 as new leaf growth occurred, but increased and returned to pretreatment levels on day 28. A similiar, though slower, pattern of decline and recovery of total nonstructural carbohydrates in stems and roots occurred in response to defoliation by clopyralid. These results showed that the nonstructural carbohydrates in stems and roots of honey mesquite were important sources of carbohydrates to support new leaf regrowth following defoliation by hand or herbicide.

A greenhouse experiment compared the vegetative growth in pure cultures and mixtures of winter Triticum aestivum cultivar ‘Mit’ and Lolium multiflorum cultivar ‘Marshall’ in continuously watered controls and drought treatments. Control L. multiflorum in pure culture 14 wk after planting produced more leaf area, tillers, and dry weights of stem and root than control T. aestivum in pure culture. The greater seed size, larger initial leaf area, and height allowed T. aestivum to produce greater final leaf area and dry stem weight in control mixtures than L. multiflorum. Watering following drought shifted the relative performance of the two species in pure cultures and mixtures compared to controls. The ability of T. aestivum to maintain a greater leaf expansion rate during drought and a greater leaf area afterward than L, multiflorum allowed T. aestivum to attain greater growth than L. multiflorum in pure cultures exposed to temporary drought followed by watering. Conversely, drought and its relief enhanced the relative competitiveness of L. multiflorum compared to controls in mixtures with T. aestivum. During 4 wk of watering following the drought, L. multiflorum in mixtures grew vigorously and was similar to T. aestivum in all measures except in height and dry stem weight. Thus, L. multiflorum was similar in root growth with T. aestivum in control and drought mixtures and had its aboveground competitiveness amplified by the cycle of drought and watering in this study. There was no evidence of an allelopathic interaction between the two species.

A greenhouse experiment used a replacement series design to compare the vegetative growth 6 wk after emergence in pure cultures and mixtures of winter wheat and Italian ryegrass, with phosphorus (P) levels recommended by soil testing. The planting proportions of wheat and Italian ryegrass were 100 and 0%, 75 and 25%, 50 and 50%, 25 and 75%, and 0 and 100%, respectively. There was no alleopathic interaction between the species. Both species in all pure and mixed cultures had substantially less growth in the low-P than in the recommended P treatment. However, the relative performance of the two species differed between P treatments. In the recommended P treatment in pure culture, Italian ryegrass had more tillers and greater root weight and length than wheat. Pure culture wheat in the low-P treatment exceeded pure culture Italian ryegrass in leaf area, weights of leaves, stems, and roots, and root length. Thus, the growth of wheat was inhibited less by P deficiency than the growth of Italian ryegrass in pure culture. In the 50:50 mixture of the recommended P treatment, wheat had greater leaf, stem, and root weights than Italian ryegrass. In the 50:50 mixture of the low-P treatment, the two species were very similar in growth, except that Italian ryegrass had about three times more tillers than did wheat. Whereas P deficiency limited the growth of wheat less than Italian ryegrass in pure culture, P deficiency did not affect the relative competitiveness of Italian ryegrass as much as wheat in mixed cultures. The ability of Italian ryegrass to compete with wheat when P was limiting may result from a difference in root growth. Italian ryegrass had a greater fresh root length to fresh root weight ratio than did wheat in the low-P treatment in pure culture and in the 50:50 mixture. The greater surface area of Italian ryegrass roots likely enhanced the competitiveness of Italian ryegrass relative to wheat under P-deficit conditions. Thus, the use of the recommended P nutrition from soil testing may be a key component to diminish Italian ryegrass competition in wheat fields.

More than thirty complete specimens of Carcineretes planetarius Vega, Feldmann, Ocampo, and Pope, 1997, a member of the extinct decapod family Carcineretidae, have been collected from the upper part of the Ocozocuautla Formation in Chiapas, southeast Mexico. Stratigraphic occurrences of Carcineretes in the Caribbean Province suggest that this crab should be regarded as an index fossil for the early Maastrichtian. Six samples of this species may represent individuals that died during molting. The sudden disappearance of this family at the end of the Maastrichtian and its restricted paleobiogeographic distribution in the vicinity of the impact site suggest that the Carcineretidae may have been affected by the Chicxulub impact. Other decapod specimens collected from the same localities were assigned to the Xanthidae; Parazanthopsis meyapaquensis new genus and species, and Megaxantho zoque, new genus and species, are described. They constitute the second and third reports of Cretaceous xanthid crabs from Mexico. A lagoonal paleoenvironment is suggested, based on associated fauna and flora. Occurrences of index species of benthic and planktic foraminifera along with that of diagnostic rudist species confirm an early Maastrichtian age.

Collaboration is used by the US National Security Council as a means to integrate inter-federal government agencies during planning and execution of common goals towards unified, national security. The concept of collaboration has benefits in the healthcare system by building trust, sharing resources, and reducing costs. The current terrorist threats have made collaborative medical training between military and civilian agencies crucial.

This review summarizes the long and rich history of collaboration between civilians and the military in various countries and provides support for the continuation and improvement of collaborative efforts. Through collaboration, advances in the treatment of injuries have been realized, deaths have been reduced, and significant strides in the betterment of the Emergency Medical System have been achieved. This review promotes collaborative medical training between military and civilian medical professionals and provides recommendations for the future based on medical collaboration.

The onset of instability is investigated in a triply diffusive fluid layer in which the density depends on three stratifying agencies having different diffusivities. It is found that, in some cases, three critical values of the Rayleigh number are required to specify the linear stability criteria. As in the case of another problem requiring three Rayleigh numbers for the specification of linear stability criteria (the rotating doubly diffusive case studied by Pearlstein 1981), the cause is traceable to the existence of disconnected oscillatory neutral curves. The multivalued nature of the stability boundaries is considerably more interesting and complicated than in the previous case, however, owing to the existence of heart-shaped oscillatory neutral curves. An interesting consequence of the heart shape is the possibility of ‘quasi-periodic bifurcation’ to convection from the motionless state when the twin maxima of the heart-shaped oscillatory neutral curve lie below the minimum of the stationary neutral curve. In this case, there are two distinct disturbances, with (generally) incommensurable values of the frequency and wavenumber, that simultaneously become unstable at the same Rayleigh number. This work complements the earlier efforts of Griffiths (1979a), who found none of the interesting results obtained herein.

The results of a U.K. study of 145 cases of type 2 neurofibromatosis has shown generally very poor operative results in terms of hearing and facial nerve preservation. Only 9 out of 118 vestibular schwannoma (acoustic neuroma) operations resulted in any clinically detectable hearing preservation and only 32 left the patient with good or normal (House grade I or II) ipsilateral facial nerve function. Although operation is still the definitive treatment of vestibular schwannoma (acoustic neuroma) and may be a lifesaving procedure, it appears that the evidence in favour of early operation is only valid when carried out in highly specialized centres. The special problems of NF2 cases who may go on to develop multiple spinal and cranial tumours making them wheelchair bound and blind as well as deaf warrants a careful experienced approach. Timing of operations may be critical for the enhancement of useful years of quality life. We therefore propose the setting up of a national NF2 register, with the management of cases at a few supraregional centres.