The knowledge of thermophysical properties of active metals is critical to understand their metallurgical processes and further industrial applications. However, due to high reactivity and melt contamination from a crucible and gaseous environment, accurate values of the properties are hard to obtain using conventional methods such as the sessile-drop method. In the present study, a vacuum electrostatic levitator was used to circumvent these difficulties and enabled the noncontact determination of thermophysical properties of liquid cerium even in an undercooled state. The data of density, surface tension, and viscosity of molten cerium were reported, as well as their temperature dependence.