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ART. 253 - The Law of Partition of Kinetic Energy

Published online by Cambridge University Press:  05 July 2011

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Summary

The law of equal partition, enunciated first by Waterston for the case of point molecules of varying mass, and the associated Boltzmann-Maxwell doctrine respecting steady distributions have been the subject of much difference of opinion. Indeed, it would hardly be too much to say that no two writers are fully agreed. The discussion has turned mainly upon Maxwell's paper of 1879, to which objections have been taken by Lord Kelvin and Prof. Bryan, and in a minor degree by Prof. Boltzmann and myself. Lord Kelvin's objections are the most fundamental. He writes: “But, conceding Maxwell's fundamental assumption, I do not see in the mathematical workings of his paper any proof of his conclusion ‘that the average kinetic energy corresponding to any one of the variables is the same for every one of the variables of the system.’ Indeed, as a general proposition its meaning is not explained, and it seems to me inexplicable. The reduction of the kinetic energy to a sum of squares leaves the several parts of the whole with no correspondence to any defined or definable set of independent variables.”

In a short note written soon afterwards I pointed out some considerations which appeared to me to justify Maxwell's argument, and I suggested the substitution of Hamilton's principal function for the one employed by Maxwell.

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Scientific Papers , pp. 433 - 451
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1903

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