Skip to main content Accessibility help
×
Hostname: page-component-77c89778f8-gq7q9 Total loading time: 0 Render date: 2024-07-19T06:19:07.270Z Has data issue: false hasContentIssue false

17 - Dynamical foundations of the Boltzmann equation

Published online by Cambridge University Press:  25 January 2010

J. R. Dorfman
Affiliation:
University of Maryland, College Park
Get access

Summary

We can now assemble many but, as we shall see, not all, of the pieces we need to construct a consistent picture of the dynamical foundations of the Boltzmann equation and similar stochastic equations used to describe the approach to equilibrium of a fluid or other thermodynamic system. While there are many fundamental points which still are in need of clarification and understanding, our study of hyperbolic systems with few degrees of freedom has pointed us in some interesting directions. In earlier chapters, we saw that the baker's transformation is ergodic and mixing. Moreover, when one defines a distribution function in the unstable direction, one obtains a ‘Boltzmann-like’ equation with an Htheorem. That is, there exists an entropy function which changes monotonically in time until the distribution function reaches its equilibrium value, provided the initial distribution is sufficiently well behaved, e.g., not concentrated on periodic points of the system. Moreover, the approach to equilibrium takes place on a timescale which is determined by the positive Lyapunov exponent and is typically shorter than the time needed for the full phase-space distribution function function to be uniformly distributed over the phase-space. Although we can make all of this clear for the baker's transformation it is not so easy to reproduce these arguments in any detail for realistic systems of physical interest. However, we can study more complicated hyperbolic maps to isolate the features we expect to use in a deeper discussion of the Boltzmann equation itself.

Type
Chapter
Information
Publisher: Cambridge University Press
Print publication year: 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×