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Sorption of Metribuzin and Metolachlor in Alaskan Subarctic Agricultural Soils

Published online by Cambridge University Press:  12 June 2017

Jeff S. Graham  and
Jeffery S. Conn
Jeff S. Graham
Affiliation:
Res. Agron's, USDA-ARS, Subarctic Agric. Res. Unit, 309 O'Neill Bldg., Univ. Alaska, Fairbanks, AK 99775
Jeffery S. Conn
Affiliation:
Res. Agron's, USDA-ARS, Subarctic Agric. Res. Unit, 309 O'Neill Bldg., Univ. Alaska, Fairbanks, AK 99775
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Abstract

Adsorption and desorption of metribuzin and metolachlor were studied for 0- to 15- and 30- to 45-cm soil depths and at 5 and 28 C temperatures for two subarctic Alaskan agricultural soils. Surface soils had five to eight times the organic carbon content of deeper soils and had lower Freundlich isotherm slopes (1/n) for both herbicides. Surface soil Freundlich coefficients (Kf) were affected by both soil type and equilibration temperature, with soil type accounting for greater than 80% of the variation in Kf. Surface soil mean Kf values ranged from 1.5 to 2.4 for metribuzin and 4.4 to 9.2 for metolachlor. For soils from the 30- to 45-cm depth, neither soil type nor temperature affected Kf. Isotherm slopes for desorption were less than adsorption, indicating hysteresis. Regressions between desorption Kf and maximum herbicide adsorbed prior to desorption were highly significant with coefficients of determination (r2) between 0.50 and 0.99.

Keywords

Metribuzin, 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-onemetolachlor, 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamideHysteresissoil organic carbonlow soil temperatures
Type
Soil, Air, and Water
Information
Weed Science , Volume 40 , Issue 1 , March 1992 , pp. 155 - 160
Copyright
Copyright © 1992 by the Weed Science Society of America 

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References

Literature Cited

1. Bouchard, D. C., Lavy, T. L., and Marx, D. B. 1982. Fate of metribuzin, metolachlor, and fluometuron in soil. Weed Sci. 30:629–632.CrossRefGoogle Scholar
2. Bowman, B. T. and Sans, W. W. 1985. Partitioning behavior insecticides in soil-water systems: II desorption hysteresis effects. J. Environ. Qual. 14:270–273.Google Scholar
3. Cavet, R. 1980. Adsorption-desorption phenomena. Pages 1–30 in Hance, R. J., ed. Interactions Between Herbicides and the Soil. Academic Press, London.Google Scholar
4. Clay, S. A. and Koskinen, W. C. 1990. Characteristics of alachlor and atrazine desorption from soils. Weed Sci. 38:74–80.Google Scholar
5. Cochran, V. L., Elliott, L. F., and Lewis, C. E. 1989. Soil microbial biomass and enzyme activity in subarctic agricultural and forest soils. Biol. Fertil. Soils 7:283–288.CrossRefGoogle Scholar
6. van Genuchten, M. Th., Davidson, J. M., and Wierenga, P. J. 1974. An evaluation of kinetic and equilibrium equations for the prediction of pesticide movement through porous media. Soil Sci. Soc. Am. J. 38:29–35.Google Scholar
7. Hamaker, J. W. and Thompson, J. M. 1972. Adsorption. Pages 49–143 in Goring, C.A.I. and Hamaker, J. W., eds. Organic Chemicals in the Soil Environment. Vol. 1. Marcel-Dekker, New York.Google Scholar
8. Hance, R. J. 1988. Adsorption and bioavailability. Pages 1–19 in Grover, R., ed. Environmental Chemistry of Herbicides. CRC Press, Inc., Boca Raton, FL.Google Scholar
9. Hance, R. J. and Hayes, R. A. 1981. The kinetics of linuron and metribuzin decomposition in soil using different laboratory systems. Weed Res. 21:87–92.CrossRefGoogle Scholar
10. Harper, S. S. 1988, Sorption of metribuzin in surface and subsurface soils of the Mississippi delta region. Weed Sci. 36:84–89.Google Scholar
11. Hornsby, A. G. and Davidson, J. M. 1973. Solution and adsorbed fluometuron concentration distribution in a water-saturated soil: experimental and predicted evaluation. Soil Sci. Soc. Am. J. 37:823–828.Google Scholar
12. Koskinen, W. C., O'Connor, G. A., and Cheng, H. H. 1979. Characterization of hysteresis in the desorption of 2,4,5-T from soils. Soil Sci. Soc. Am. J. 43:871–874.CrossRefGoogle Scholar
13. Knight, C. W. and Lewis, C. E. 1986. Conservation tillage in the subartic. Soil Tillage Res. 7:341–353.Google Scholar
14. Nelson, D. W. and Sommers, L. E. 1982. Total carbon, organic carbon, and organic matter. Pages 539–579 in Methods of Soil Analysis. Part 2 Chemical and microbiological properties. 2nd ed. Am. Soc. Agron., Madison, WI.Google Scholar
15. Obrigawitch, T., Hons, F. M., Abernathy, J. R., and Gipson, J. R. 1981 Adsorption, desorption, and mobility of metolachlor in soils. Weed Sci. 29:332–336.Google Scholar
16. Peter, C. J. and Weber, J. B. 1985. Adsorption, mobility, and efficacy of metribuzin as influenced by soil properties. Weed Sci. 33:868–873.CrossRefGoogle Scholar
17. Peter, C. J. and Weber, J. B. 1985. Adsorption, mobility, and efficacy of alachlor and metolachlor as influenced by soil properties. Weed Sci. 33:874–881.Google Scholar
18. Rao, P.S.C. and Davidson, J. M. 1980. Estimation of pesticide retention and transformation parameters required in nonpoint source pollution models. Pages 23–67 in Overcash, M. R. and Davidson, J. M., eds. Environmental Impact of Nonpoint Source Pollution. Ann Arbor Science Publishers, Inc., Ann Arbor, MI.Google Scholar
19. SAS. 1985. SAS User's Guide: Statistics. Version 5 ed. SAS Inst., Inc., Cary, NC. 956 pp.Google Scholar
20. Savage, K. E. 1976. Adsorption and mobility of metribuzin in soil. Weed Sci. 24:525–528.Google Scholar
21. Sharom, M. S. and Stephenson, G. R. 1976. Behavior and fate of metribuzin in eight Ontario soils. Weed Sci. 24:153–160.Google Scholar
22. Siddoway, F. H., Lewis, C. E., and Cullum, R. F. 1984. Conservation-tillage and residue-management systems for interior Alaska. Agroborealis 16:35–40.Google Scholar
23. Swanson, R. A. and Dutt, G. R. 1973. Chemical and physical processes that affect atrazine and distribution in soil systems. Soil Sci. Soc. Am. J. 37:872–876.Google Scholar
24. Talbert, R. E. and Fletchell, H. 1965. The adsorption of some s-triazines in soils. Weeds 13:46–52.Google Scholar
25. Wauchope, R. D. and Meyers, R. S. 1985. Adsorption-desorption kinetics of atrazine and linuron in freshwater-sediment aqueous slurries. J. Environ. Qual. 14:132–136.Google Scholar
26. Weber, J. B. and Peter, C. J. 1982. Adsorption, bioactivity, and evaluation of soil tests for alachlor, acetochlor, and metolachlor. Weed Sci. 30:14–20.Google Scholar
27. Zimdahl, R. L. and Clark, S. K. 1982. Degradation of three acetanilide herbicides in soil. Weed Sci. 30:545–548.CrossRefGoogle Scholar