We present here results of our investigation of the isotopic chemical composition of groundwater and carbonates in the Surdulica geothermal aquifer, Serbia. We considered the effects of carbonate dissolution and measured 13C, 14C, D, 18O, 3H, field pH, temperature, Na+, Ca2+, Mg2+, HCO−3; and other aqueous species from 30 springs and boreholes. Geothermal waters are supersaturated with calcite. Carbon isotope compositions vary with carbonate mineral dissolution. The δD and δ18O of groundwater samples fit the meteoric water line, and indicate that groundwater is recharged mainly from higher altitudes and the cold season. Different groundwater residence times point out two mechanisms for their formation: fissure flow for young waters and standard diffusion processes for old ones.

The availability of absolutely (dendrochronologically) dated German oak has allowed the Belfast laboratory to extend its published high-precision 14C measurements of Irish oak (Pearson et al. 1986) by 2680 yr. The samples were selected at contiguous 20-yr intervals, following a precedent adopted and considered satisfactory in previous publications. All samples were measured for at least 200,000 counts within the 14C channel. The statistical counting error, together with the error on standards, backgrounds and applied corrections, give a realistic precision quoted on each sample of ± 2.5‰ (± 20 yr). This error is considered high-precision for sample ages of 7000–8000 BP.

The important problem of contamination of old samples by younger 14C necessitates treatment of organic and carbonate samples to ensure more complete removal of contaminating carbon. Here we present studies of chemical procedures for the liquid scintillation method of 14C dating undertaken since 1960 in the former USSR. We discuss new procedures such as lithium carbide synthesis from charred organic samples and benzene synthesis on a V2O5·Al2O3·SiO2 catalyst, as well as memory effect in the carbide synthesis procedure and characteristics of two homemade counters.

On 23 November 1980, a major earthquake (Ms = 6.9) struck a large area of the southern Apennines (Campania and Lucania regions, southern Italy). This seismic event, the largest in Italy over the last 80 years, almost completely destroyed 15 villages and caused extensive damage to other towns, including Naples. The quake produced the first well-documented example in Italy of surface dislocation, represented by a fault scarp 38 km long. We undertook a study that included 14C dating of organic materials from layers displaced by paleoseismic events to assess the seismologic hazard for the area. We collected peat and charred wood samples from the walls of two trenches excavated across the 1980 fault at Piano di Pecore di Colliano, Salerno, where the sedimentary suite is faulted and warped by five quakes (including that of 1980). This produced comparable vertical throw and deformation patterns. Chronological data for pre-1980 events, coupled with detailed stratigraphic analysis, yielded a dip-slip rate and a recurrence interval of 0.4 mm/yr and 1700 yr, respectively.

We have developed a method of graphitization from CO2 samples for accurate 14C measurements by accelerator mass spectrometry. Our batch method, using a sealed Vycor tube, reduces the risk of contamination during graphitization and makes it possible to prepare many samples in a short time (typically 20 samples per day).

14C chronology of Late Pleistocene paleogeographical events in the Black Sea–Caspian Sea region shows that the following transgressions partly correlate with each other: Karangat and Khazarian; Neo-Euxinian and Khvalyn; Holocene and Neo-Caspian. The main climatic events were synchronous in intercontinental Siberia. In the far eastern region, the Middle-Wisconsinan transgression is reflected by Chukotka and western Kamchatka terraces and by submerged ancient shorelines in Primorye.

We present here 14C data representing previously published material (Pearson et al. 1986) with minor corrections. All corrections used for calculations published in Pearson et al. (1986) have been re-evaluated, and only one was found to be significantly different. This correction, namely, ‘the variation of efficiency with time', being additional to all other corrections for changes in efficiency, was more subjective; the others could be checked and accounted for by experimentation.

Radiocarbon calibration data derived from German oak chronologies, ranging back to 7200 BC, have been published in the previous Calibration Issue (Stuiver & Kra 1986). In recent years, the German oak chronology has been extended to 7938 BC (Becker, this issue). For earlier intervals, tree-ring chronologies must be based on pine, because oak re-emigrated to central Europe at the Preboreal/Boreal transition, at about 8000 BC. We have established a 1784-yr pine chronology centered in the Preboreal, and have linked it tentatively to the absolutely dated oak master. We present here calibration data based on this link, for the age range, 7145–9439 BC.

Owing to the large basin area of the Caspian Sea, fluctuations in its level reflect climatic changes in the northern hemisphere. To reconstruct these fluctuations, I collected mollusk shells, plant debris, carbonates and organic matter samples for 14C dating from deposits of ancient salt marshes, depressions and bars formed during significant sea-level decline. I studied the impact of eolian sedimentation via parallel dating of carbonates and other materials. The data demonstrate that sea level rises during periods of cooling and falls during warming periods; this is true for both long-term (2–2.5 ka) and short-term climatic changes.

In July 1986, an AMS radiocarbon target preparation laboratory was established at the Woods Hole Oceanographic Institution to produce graphite to be analyzed at the NSF-Accelerator Facility for Radioisotope Analysis at the University of Arizona (Tucson). By June 1991, 923 graphite targets had been prepared and 847 analyzed. Our lab procedures during this time included the careful documentation of weights of all starting samples, catalysts and final graphite yields, as well as the volume of CO2 gas evolved during CaCO3 hydrolysis or closed-tube organic carbon combustions. From these data, we evaluate the methods used in general and in our lab.

Accurate high-precision 14C dating (i.e., ± 20 yr precision or less on the 14C date) provides the narrowest calendrical band width and, hence, the best age range determination possible. However, because of the structure in the 14C calibration curve, the calendar age range for a given 14C precision is not constant throughout the calibration range. In this study, we quantify the calendar band widths for a range of 14C precisions throughout the calibration range. We show that an estimate of the likely calendar band width in years can be obtained from the expression: Band width (yr) = 2.12 x 14C precision (1 σ) + 54.6. We also show that calendar band widths are widest around 4000 BP at the start of the Bronze Age, and become narrow through the later Bronze Age and Iron Age and back into the Neolithic.

The detailed radiocarbon age vs. calibrated (cal) age studies of tree rings reported in this Calibration Issue provide a unique data set for precise 14C age calibration of materials formed in isotopic equilibrium with atmospheric CO2. The situation is more complex for organisms formed in other reservoirs, such as lakes and oceans. Here the initial specific 14C activity may differ from that of the contemporaneous atmosphere. The measured remaining 14C activity of samples formed in such reservoirs not only reflects 14C decay (related to sample age) but also the reservoir 14C activity. As the measured sample 14C activity figures into the calculation of a conventional 14C age (Stuiver & Polach 1977), apparent 14C age differences occur when contemporaneously grown samples of different reservoirs are dated.

I constructed a Late Pleistocene geochronological scale for European Russia employing 14C dating and paleobotanical studies of several reference sections.

We propose a simplified approach to the calibration of radiocarbon dates. We use splines through the tree-ring data as calibration curves, thereby eliminating a large part of the statistical scatter of the actual data points. To express the age range, we transform the ± 1 σ and ± 2 σ values of the BP age to calendar dates and interpret them as the 68% and 95% confidence intervals. This approach bypasses the conceptual problems of the transfer of individual probability values from the radiocarbon to the calendar age. We have adapted software to make this calibration possible.

In 1988, Fairbanks conducted a drilling expedition off the south coast of Barbados to recover submerged corals contemporaneous with the last deglaciation. Core recovery was excellent and >30 different samples were dated by conventional β-counting techniques (Fairbanks 1989). At about the same time, we developed, at Lamont, the thermal ionization mass spectrometry (TIMS) technique to obtain precise U-Th ages (Edwards 1988), and to compare them with the 14C estimates measured on the same samples. A surprising result was that the discrepancy between 14C and U-Th ages increased through time to ca. 3000–3500 yr at ca. 15,000 14C BP (Bard et al. 1990a). Because the three youngest samples yielded U-Th ages in agreement with their calibrated 14C ages, we concluded initially that the TIMS U-Th determinations were not only precise, but also accurate, and that the 14C vs. U-Th data set could be used for a first-order 14C calibration.

Radiocarbon-dated paleobotanical and palynological samples record complex changes of vegetation and climate in northeastern Russia during the Late Pleistocene and Holocene. Since the Kargin Interval (middle Wisconsin equivalent), which started 50 ka ago, we can distinguish two periods that were colder than the present. The Kirgilyakh was the earliest Karginsk cool period, dating to 45–39 ka BP. The second significant cool period dates to 33–30 ka BP. The boundary between the Kargin Interval and the last Late Pleistocene glaciation (Sartan, late Wisconsin equivalent) dates from 27 ka BP. The sharp change from herbaceous mossy tundra (Sartan) to light-coniferous larch forests (Holocene) in northeastern Russia dates to 12.5 ka ago. The Holocene thermal maximum, linked to the expansion of woody plants into the modern barren-ground tundra, dates from 9.5–8 ka BP.

Sequences of dendrodated tree rings provide ideal sources for radiocarbon calibration. The wood structure of trees consists of continuous series of annual growth layers, the carbon content of which can be 14C-dated and calibrated to calendar yr. The cellulose and lignin of trees deposited in river gravels or peat-bog sediments below the water table are often very well preserved, even after several millennia. Such tree-trunk deposits are well protected from contamination by younger or older organic materials. Further, the physical and chemical structure of wood allows a strong chemical pretreatment of samples for 14C analysis.

We distinguished major stages of the last glaciation (Bølling, Older Dryas, Allerød, Younger Dryas) and the Holocene by radiocarbon dating and paleobotanical analyses. Our paleobotanical investigation of peatlands is well correlated with independent 14C data. We establish that the Atlantic and Subboreal stages of the Holocene have three divisions, and that the Subatlantic has two.

Between 1988 and 1991, I directed five archaeological research projects in American Samoa. The goal of that research was to reveal changes in the prehistoric settlement system of Samoa, from initial colonization of the archipelago to the time of significant European contact. The chronological placement of key sites was an essential facet of the research. A secondary goal was to locate sites with ceramic components, particularly sites with Lapita ceramics, and relate the ceramic assemblages typologically and chronologically to those known for Western Samoa. These investigations generated 16 14C dates from archaeological contexts. I present here the previously unpublished 14C data from those samples, and briefly summarize their importance for understanding Samoan prehistory.

The age calibration program, CALIB (Stuiver & Reimer 1986), first made available in 1986 and subsequently modified in 1987 (revision 2.0 and 2.1), has been amended anew. The 1993 program (revision 3.0) incorporates further refinements and a new calibration data set covering nearly 22,000 cal yr (≈18,400 14C yr). The new data, and corrections to the previously used data set, derive from a 6-yr (1986–1992) time-scale calibration effort of several laboratories.