Hostname: page-component-76fb5796d-skm99 Total loading time: 0 Render date: 2024-04-28T00:11:44.937Z Has data issue: false hasContentIssue false
  • English
  • Français

X-ray powder diffraction analysis of a silver(I) cyclamate complex

Published online by Cambridge University Press:  01 March 2012

R. Putvinskis ,
C. O. Paiva Santos ,
M. Cavicchioli  and
A. C. Massabni
R. Putvinskis
Affiliation:
Laboratório Computacional de Análises Cristalográficas e Cristalinas - LabCACC, Instituto de Química, UNESP, 14800-900, Rua Prof. Francisco Degni s/n, Araraquara, SP, Brazil
C. O. Paiva Santos
Affiliation:
Laboratório Computacional de Análises Cristalográficas e Cristalinas - LabCACC, Instituto de Química, UNESP, 14800-900, Rua Prof. Francisco Degni s/n, Araraquara, SP, Brazil
M. Cavicchioli
Affiliation:
Departamento de Química Geral e Inorgânica, Instituto de Química, UNESP, 14800-900, Rua Prof. Francisco Degni s/n, Araraquara, SP, Brazil
A. C. Massabni
Affiliation:
Departamento de Química Geral e Inorgânica, Instituto de Química, UNESP, 14800-900, Rua Prof. Francisco Degni s/n, Araraquara, SP, Brazil
Get access Rights & Permissions [Opens in a new window]

Abstract

X-ray powder diffraction data collected for the complex silver(I) cyclamate [Ag(C6H12NO3S)] are reported. This material was obtained from a stoichiometric mixture of sodium cyclamate and AgNO3. The analysis of the data using the Le Bail method showed that the complex has monoclinic symmetry (space group C2/c). The unit cell parameters are a=31.85852(16) Å, b=6.25257(6) Å, c=8.46165(7) Å, and β=95.7651(5)°.

Keywords

silver(I)cyclamateX-ray powder diffractionLe Bail method
Type
New Diffraction Data
Information
Powder Diffraction , Volume 22 , Issue 1 , March 2007 , pp. 68 - 70
Copyright
Copyright © Cambridge University Press 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Coelho, A. A. and Cheary, R. W. (1997). X-ray Line Profile Fitting Program, XFIT. School of Physical Sciences, University of Technology, Sydney, New South Wales, Australia.Google Scholar
De Gracia, C. G. (2001). “An open study comparing topical silver sulfadiazine and topical silver sulfadiazine-cerium nitrate in the treatment of moderate and sever burns,” BurnsZZZZZZ 27, 67–74.CrossRefGoogle ScholarPubMed
Klasen, H. J. (2000a). “Historical review of the use of silver in the treatment of burns, I. Early uses,” BurnsZZZZZZ 26, 117–130.CrossRefGoogle Scholar
Klasen, H. J. (2000b). “A historical review of the use of silver in the treatment of burns, II. Renewed interest for silver,” BurnsZZZZZZ 26, 131–138.CrossRefGoogle ScholarPubMed
Larson, A. C. and von Dreele, R. B. (2001). “GSAS - General Structure Analysis System,” Los Alamos National Laboratory. Los Alamos, EUA. Copyright 1985–2000, The Regents of the University of California.Google Scholar
Modak, S., Stanford, J., Friendlaender, J., Fox, P., and Fox, C. L. (1983). “Control of burn wound infections by pentafloxacin and its silver derivative,” BurnsZZZZZZ 10, 170–178.CrossRefGoogle Scholar
Nomiya, K., Kondoh, Y., Onoue, K., Kasuga, N. C., Nagano, H., Oda, M., Sudoh, T., and Sakuma, S. (1995). “Synthesis and characterization of polymeric, anionic thiosalicylato-Ag(I) complexes with antimicrobial activities,” J. Inorg. Biochem.JIBIDJ10.1016/0162-0134(94)00059-J 58, 255–267.CrossRefGoogle Scholar
Nomiya, K., Tsuda, K., Sudoh, T., and Oda, M. (1997). “Ag(I)-N bond-containing compound showing wide spectra in effective antimicrobial activities: polymeric silver(I) imidazolate,” J. Inorg. Biochem.JIBIDJ10.1016/S0162-0134(97)00006-8 68, 39–44.CrossRefGoogle Scholar
Nomiya, K. and Yokoyama, H. (2002). “Synthesis, crystal structures and antimicrobial activities of polymeric silver(I) complexes with three amino-acids [aspartic acid (H2asp), glycine (Hgly) and asparagine (Hasn)],” J. Chem. Soc. Dalton Trans.JCDTBI 12, 2483–2490.CrossRefGoogle Scholar
Shirley, R. (2002). The Crysfire 2002 System for Automatic Powder Indexing: User’s Manual (Lattice, Guildford, England).Google Scholar
Silverstein, R. M., Bassler, G. C., and Morrill, T. C. (1991). Spectrometric Identification of Organic Compounds, 5th ed. (Wiley, Singapore).Google Scholar