Hostname: page-component-7479d7b7d-qs9v7 Total loading time: 0 Render date: 2024-07-12T23:52:49.944Z Has data issue: false hasContentIssue false
  • English
  • Français

Structure and powder diffraction pattern of 2,4,6-Trimercapto-s-triazine, trisodium salt (Na3S3C3N3·9H2O)

Published online by Cambridge University Press:  10 January 2013

Kevin R. Henke ,
Jeffrey C. Bryan  and
Mark P. Elless
Kevin R. Henke
Affiliation:
P.O. Box 9018, Energy & Environmental Research Center, University of North Dakota, Grand Forks, North Dakota 58202-9018
Jeffrey C. Bryan
Affiliation:
P.O. Box 2008, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6119
Mark P. Elless
Affiliation:
Department of Plant and Soil Science, University of Tennessee, Knoxville, Tennessee 37996
Get access Rights & Permissions [Opens in a new window]

Abstract

2,4,6-Trimercapto-s-triazine, trisodium salt (ideally, Na3S3C3N3·9H2O), also known as TMT-55, is a white powder that is used to precipitate heavy metals from contaminated waters. Chemical analyses confirmed the nominal composition. TMT-55 crystals are uniaxial negative with indices of refraction (25 °C) of nε=1.520 and nω=1.675. The structure was determined by single-crystal methods at 25 and −110 °C. A powder pattern was determined and compared to a simulated pattern based on the 25 °C structure data. Crystal data at 25 °C are: R3;Z=6; a=17.600(1) Å and c=9.720(2) Å; V=2607.5(5) Å3; Dx=1.55 g/cm3.

Type
Research Article
Information
Powder Diffraction , Volume 12 , Issue 1 , March 1997 , pp. 7 - 12
Copyright
Copyright © Cambridge University Press 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ainscough, E. W., Brodie, A. M.Coll, R. K.Mair, A. J. A.Waters, J. M.(1993). “The synthesis and single-crystal X-ray structure of [{Os3H(CO)10}3(S3C3N3)]; a novel osmium cluster containing three linked osmium triangles,” Inorg. Chim. Acta 214, 21–22.CrossRefGoogle Scholar
American Society for Testing and Materials (ASTM) (1992). Annual Book of ASTM Standards. Philadelphia, PA.Google Scholar
Appleman, D. E., and Evans, H. T. (1973). “Indexing and Least Squares Refinement of Powder Diffraction Data,” U.S. Geological Survey Report PB 216188, U.S. Dept. of Commerce, Nat. Tech. Info. Serv., 5285 Port Royal Rd., Springfield, VA 22151.Google Scholar
Degussa Corporation (1993). Data Sheets on TMT-15. Ridgefield Park, NJ 07660.Google Scholar
de Wolff, P. M. (1968). “A Simplified Criterion for the Reliability of a Powder Pattern Indexing,” J. Appl. Cryst. 1, 108–113.CrossRefGoogle Scholar
Garvey, R. G. (1986). “LSUCRI Least Squares Unit Cell Refinement for the Personal Computer,” Powder Diffr. 1, 114.Google Scholar
Mighell, A. D., Hubbard, C. R., and Stalick, J. K. (1981). NBS*AIDS80: A FORTRAN Program for Crystallographic Data Evaluation, Nat. Bur. Stand. (U.S.A.) Tech. Note 1141. (NBS*AIDS83 is an expanded version of NBS*AIDS80.)CrossRefGoogle Scholar
Siemens Industrial Automation, Inc. (1994). SHELXTL Version 5. Madison, WI.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “F N: A Criterion for Rating Powder Diffraction Patterns and Evaluating the Reliability of Powder-Pattern Indexing,” J. Appl. Cryst. 12, 60–65.CrossRefGoogle Scholar
Smith, K. L., and Smith, D. K. (1993). “Micro-POWD, ver. 2.31,” Materials Data Inc., Livermore, CA.Google Scholar
U.S. Environmental Protection Agency (1990). Test Methods for Evaluating Solid Wastes. SW-846, Revision, Office of Solid Waste and Emergency Response, U.S. Environmental Protection Agency, Washington, DC 20460.Google Scholar