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New powder diffraction data of some derivatives of N-(hydroxyalkyl)-4-chlorophenoxyacetamide—Potential pesticides

Published online by Cambridge University Press:  29 February 2012

E. Olszewska*
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr. 3, 20-031 Lublin, Poland
B. Tarasiuk
Affiliation:
Department of Organic Chemistry, Faculty of Chemistry, Maria Curie Sklodowska University, Gliniana Str. 33, 20-614 Lublin, Poland
S. Pikus
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr. 3, 20-031 Lublin, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: ela_ol@wp.pl

Abstract

Five new derivatives of N-(ω-hydroxyalkyl)-4-chlorophenoxyacetamide [namely, 2-(4-chlorophenoxy)-N-(2-hydroxyethyl) acetamide, 2-(4-chlorophenoxy)-N-(3-hydroxypropyl) acetamide, 2-(4-chlorophenoxy)-N-[1-(hydroxymethyl) propyl] acetamide, 2-(4-chlorophenoxy)-N-(2-hydroxy-1,1-dimethylethyl) acetamide, and 2-(4-chlorophenoxy)-N-{2-[(2-hydroxyethyl) amino] ethyl} acetamide] and one 2-(4-chlorophenoxy) acetohydrazide have been characterized by X-ray powder diffraction. These organic compounds are potential pesticides. New diffraction data including experimental and calculated 2θ peaks positions, values of d, experimental relative peak intensities, and Miller indices as well as unit-cell parameters are reported.

Type
New Diffraction Data
Copyright
Copyright © Cambridge University Press 2009

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References

Berhenke, L. F., Begin, L. E., Williams, B. M., and Beman, F. L. (1951). “Some aryloxyaliphatic acids,” J. Am. Chem. Soc.JACSAT 73, 44584458.10.1021/ja01153a504CrossRefGoogle Scholar
de Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr.JACGAR 1, 108113.10.1107/S002188986800508XCrossRefGoogle Scholar
Gruzdyev, G. S., Zinchenko, V. A., Kalinin, V. A., and Slovtsov, R. I. (1988). The Chemical Protection of Plants (Mir Publishers, Moscow), pp. 364374.Google Scholar
Hayes, N. V. and Branch, G. E. (1943). “The acidic dissociation constants of phenoxyacetic acid and its derivatives,” J. Am. Chem. Soc.JACSAT 65, 15551564.10.1021/ja01248a031CrossRefGoogle Scholar
Marciniak, H. and Diduszko, R. (1994). XRAYAN: computer program for X-ray diffraction phase analyzes, version 2.90, Warsaw, Poland.Google Scholar
Melnikov, N. N. (1987). in Pesticide: Khimiya, Tekhnologiya i Prymenenye, edited by Nowozyw, K. W. (Khimiya, Moscow), pp. 222245.Google Scholar
Newman, M. S., Fones, W., and Renoll, M. (1947). “New compounds as plant growth regulators,” J. Am. Chem. Soc.JACSAT 69, 718723.10.1021/ja01195a604CrossRefGoogle ScholarPubMed
Olszewska, E., Pikus, S., and Tarasiuk, B. (2008). “New powder diffraction data of some derivatives of N-alkyl (aryl)-2,4-dichlorophenoxyacetamide-new potential pesticides,” Powder Diffr.PODIE2 23, 338349.10.1154/1.3009636CrossRefGoogle Scholar
Smith, G. S. and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr.JACGAR 12, 6065.10.1107/S002188987901178XCrossRefGoogle Scholar
Tarasiuk, B. (2007). “Syntheses, structures and properties of halogenoanilides derivatives of dichlorophenoxyacetic acids,” Annales Uniwersytet Maria Curie-Skłodowska, Sectio AA Chemia 62, 234249.Google Scholar
Tarasiuk, B., Podkościelny, W., Zimińska, Z., and Krawczyk, M. (2000). “1H-1,2,4-triazoles derivatives of halogenphenoxyalkane acids with herbicidal activity,” Pestycydy 1–2, 515.Google Scholar
Werner, P. F. (1984). TREOR, Trial and Error Program for Indexing of Unknown Powder Patterns (University of Stockholm, Stockholm, Sweden).Google Scholar