Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-26T23:53:14.290Z Has data issue: false hasContentIssue false
  • English
  • Français

Water bath synthesis and enhanced photocatalytic performances of urchin-like micro/nanostructured α-FeOOH

Published online by Cambridge University Press:  05 May 2015

Shenghong Kang ,
Guozhong Wang ,
Ming Fang ,
Huiming Wang ,
Xianbiao Wang  and
Weiping Cai
Shenghong Kang
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Guozhong Wang
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Ming Fang
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Huiming Wang
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Xianbiao Wang
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Weiping Cai*
Affiliation:
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
*
a)Address all correspondence to this author. e-mail: wpcai@issp.ac.cn
Get access

Abstract

Micro/nanostructured goethite (α-FeOOH) was synthesized by a low-temperature water bath method based on the reaction of urea and FeSO4•7H2O at 95 °C. It has been shown that the as-prepared α-FeOOH consists of nearly spherical particles with about 0.5–1 μm in diameter. The microsized α-FeOOH particles are urchin-like in morphology and composed of nanosized leaf-like objects, with about 150–200 nm in length and about 30–50 nm in width, in radial arrangement, showing high specific surface area (∼118 m2/g). The formation of such urchin-like α-FeOOH could be described by a two-step process, or formation of spherical particles, and ethylene glycol-adsorption induced preferential growth of nanoleaves on the preformed spherical particles. Importantly, such micro/nanostructured α-FeOOH has exhibited much higher photocatalytic activity to the organic pollutants, such as Rhodamine 6G, and better re-usable performances than the goethite nanorod powders, exhibiting the good application potential in the environmental treatment. This study could provide a useful material for environmental pollution treatment.

Keywords

urchin-like micro/nanostructured α-FeOOHwater bath synthesisenhanced photocatalytic performances
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 10 , 28 May 2015 , pp. 1629 - 1638
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Domínguez, J.R., Beltrán, J., and Rodríguez, O.: Vis and UV photocatalytic detoxification methods (using TiO2, TiO2/H2O2, TiO2/O3, TiO2/S2O8 2−, O3, H2O2, S2O8 2−, Fe3+/H2O2 and Fe3+/H2O2/C2O4 2−) for dyes treatment. Catal. Today 101, 389–396 (2005).Google Scholar
Zhang, L.D. and Fang, M.: Nanomaterials in pollution trace detection and environmental improvement. Nano Today 5, 128–142 (2010).Google Scholar
Inoue, T., Fujishima, A., Konishi, S., and Honda, K.: Photoelectrocatalytic reduction of carbon-dioxide in aqueous suspensions of semiconductor powder. Nature 277, 637–638 (1979).CrossRefGoogle Scholar
Hoffmann, M.R., Martin, S.T., Choi, W., and Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69–96 (1995).Google Scholar
Chen, M.L., Bae, J.S., and Oh, W.C.: Characterization of AC/TiO2 composite prepared with pitch binder and their photocatalytic activity. Bull. Korean Chem. Soc. 27, 1423–1428 (2006).Google Scholar
Panniello, A., Curri, M.L., Diso, D., Licciulli, A., Locaputo, V., Agostiano, A., Comparelli, R., and Mascolo, G.: Nanocrystalline TiO2 based films onto fibers for photocatalytic degradation of organic dye in aqueous solution. Appl. Catal., B 121, 190–197 (2012).Google Scholar
Manning, B.A., Kiser, J.R., Kwon, H., and Kanel, S.R.: Spectroscopic investigation of Cr3+ and Cr6+ treated nanoscale zerovalent iron. Environ. Sci. Technol. 41, 586–592 (2007).Google Scholar
Wang, B., Wu, H.B., Yu, L., Xu, R., Lim, T., and Lou, X.W.: Template-free formation of uniform urchin-like α-FeOOH hollow spheres with superior capability for water treatment. Adv. Mater. 24, 1111–1116 (2012).Google Scholar
Wang, Y., Ma, J., and Chen, K.: Adsorptive removal of Cr(VI) from wastewater by α-FeOOH hierarchical structure: Kinetics, equilibrium and thermodynamics. Phys. Chem. Chem. Phys. 15, 19415–19421 (2013).CrossRefGoogle ScholarPubMed
Amstaetter, K., Borch, T., Larese-Casanova, P., and Kappler, A.: Redox transformation of arsenic by Fe(II)-activated goethite (α-FeOOH). Environ. Sci. Technol. 44, 102–108 (2010).Google Scholar
Iglesias, A., López, R., Gondar, D., Antelo, J., Fiol, S., and Florencio, A.: Adsorption of paraquat on goethite and humic acid-coated goethite. J. Hazard. Mater. 183, 664–668 (2010).CrossRefGoogle ScholarPubMed
Krýsa, J., Jirkovský, J., Bajt, O., and Mailhot, G.: Competitive adsorption and photodegradation of salicylate and oxalate on goethite. Catal. Today 161, 221–227 (2011).Google Scholar
Zhou, X., Yang, H., Wang, C., Mao, X., Wang, Y., and Liu, G.: Visible-light induced photocatalytic degradation of rhodamine B on one-dimensional iron oxide particles. J. Phys. Chem. C 114, 17051–17061 (2010).Google Scholar
Xu, L.J. and Wang, J.L.: A heterogeneous Fenton-like system with nanoparticulate zero-valent iron for removal of 4-chloro-3-methyl phenol. J. Hazard. Mater. 186, 256–264 (2011).Google Scholar
Hojamberdiev, M., Zhu, G.Q., Eminov, A., and Okada, K.: Template-free hydrothermal synthesis of hollow α-FeOOH urchin-like spheres and their conversion to α-Fe2O3 under low-temperature thermal treatment in air. J. Cluster Sci. 24, 97–106 (2013).Google Scholar
Kwan, W.P. and Voelker, B.M.: Rates of hydroxyl radical generation and organic compound oxidation in mineralcatalyzed Fenton-like systems. Environ. Sci. Technol. 37, 1150–1158 (2003).Google Scholar
He, J., Ma, W., He, J., Zhao, J., and Yu, J.C.: Photooxidation of azo dye in aqueous dispersions of H2O2/α-FeOOH. Appl. Catal., B 39, 211–220 (2002).Google Scholar
Murakami, N., Matsuo, T., Tsubota, T., and Ohno, T.: Photocatalytic reaction over iron hydroxides: A novel visible-light responsive photocatalyst. Catal. Commun. 12, 341–344 (2011).Google Scholar
Tong, G., Guan, J., and Zhang, Q.: Goethite hierarchical nanostructures: Glucose-assisted synthesis, chemical conversion into hematite with excellent photocatalytic properties. Mater. Chem. Phys. 127, 371–378 (2011).Google Scholar
Tang, B., Wang, G.L., Zhuo, L.H., Ge, J.H., and Cui, L.J.: Facile route to α-FeOOH and α-Fe2O3 nanorods and magnetic property of α-Fe2O3 nanorods. Inorg. Chem. 45, 5196–5200 (2006).CrossRefGoogle ScholarPubMed
Cwiertny, D.M., Hunter, G.J., Pettibone, J.M., Scherer, M.M., and Grassian, V.H.: Surface chemistry and dissolution of α-FeOOH nanorods and microrods: Environmental implications of size-dependent interactions with oxalate. J. Phys. Chem. C 113, 2175–2186 (2009).Google Scholar
Musi, S., Krehula, S., and Popovi, S.: Effect of HCl additions on forced hydrolysis of FeCl3 solutions. Mater. Lett. 58, 2640–2645 (2004).Google Scholar
Morterra, C., Chiorlno, A., and Borello, E.: An IR spectroscopic characterization of α-FeOOH (goethite). Mater. Chem. Phys. 10, 119–138 (1984).Google Scholar
Wang, X.B., Cai, W.P., Lin, Y.X., Wang, G.Z., and Liang, C.H.: Mass production of micro/nanostructured porous ZnO plates and their strong structurally enhanced and selective adsorption performance for environmental remediation. J. Mater. Chem. 20, 8582–8590 (2010).Google Scholar
Sun, C.T. and Xue, D.F.: Tailoring anisotropic morphology at the nanoregime: Surface bonding motif determines the morphology transformation of ZnO nanostructures source. J. Phys. Chem. C 117, 5505–5511 (2013).Google Scholar
Sun, C.T. and Xue, D.F.: Chemical bonding theory of single crystal growth and its application to phi 3. CrystEngComm 16, 2129–2135 (2014).Google Scholar
Igarashi, K., Maeda, M., Takao, T., Oki, Y., and Kusama, H.: Dominant factors of preventing rhodamine 6G from dimer formation in aqueous solutions. Bull. Chem. Soc. Jpn. 72, 1197–1202 (1999).Google Scholar
Arbeloa, F.L., Tapia Estévez, M.J., Arbeloa, T.L., and Arbeloa, I.L.: Spectroscopic study of the adsorption of rhodamine 6G on clay minerals in aqueous suspensions. Clay Miner. 32, 97 (1997).CrossRefGoogle Scholar
Li, X. and Kikugawa, N.: A comparison study of rhodamine B photodegradation over nitrogen-doped lamellar niobic acid and titanic acid under visible-light irradiation. Chem. - Eur. J. 15, 3538–3545 (2009).Google Scholar
Zhang, L., Ding, Q.Q., and Zhou, Y.: Hydrothermal synthesis of anatase flower-like nanostructures for photocatalytic degradation of dye. Cryst. Res. Technol. 46, 1202–1206 (2011).Google Scholar
Yu, J.G., Yu, X.X., Huang, B.B., Zhang, X.Y., and Dai, Y.: Hydrothermal synthesis and visible-light photocatalytic activity of novel cage-like ferric oxide hollow spheres. Cryst. Growth Des. 9, 1474–1480 (2009).Google Scholar
Xie, H., Li, Y.Z., Jin, S.F., Han, J.J., and Zhao, X.J.: Facile fabrication of 3D-Ordered macroporous nanocrystalline iron oxide films with highly efficient visible light induced photocatalytic activity. J. Phys. Chem. C 114, 9706–9712 (2010).Google Scholar
Li, X.H., Chen, G.Y., Yang, L.B., Jin, Z., and Liu, H.: Multifunctional Au-coated TiO2 nanotube arrays as recyclable SERS substrates for multifold organic pollutants detection. Adv. Funct. Mater. 20, 2815–2824 (2010).Google Scholar
Jiang, Y., Zhang, P., Liu, Z.W., and Xu, F.: The preparation of porous nano-TiO2 with high activity and the discussion of the cooperation photocatalysis mechanism. Mater. Chem. Phys. 99, 498–504 (2006).Google Scholar
Lu, F., Cai, W.P., and Zhang, Y.G.: ZnO hierarchical micro/nanoarchitectures: Solvothermal synthesis and structurally enhanced photocatalytic performance. Adv. Funct. Mater. 18, 1047–1056 (2008).Google Scholar
Ye, C.H., Bando, Y., Shen, G.Z., and Golberg, D.: Thickness-dependent photocatalytic performance of ZnO nanoplatelets. J. Phys. Chem. B 110, 15146–15151 (2006).Google Scholar
Chen, X.B., Shen, S.H., Guo, L.J., and Mao, S.S.: Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110, 6503–6570 (2010).Google Scholar
Xiao, Q., Si, Z.C., Zhang, J., Xiao, C., and Tan, X.K.: Photoinduced hydroxyl radical and photocatalytic activity of samarium-doped TiO2 nanocrystalline. J. Hazard. Mater. 150, 62–67 (2008).Google Scholar
Chen, J. and Zhu, L.: J. Photochem. Photobiol., A 188, 56 (2007).Google Scholar
Li, K.Y., Li, M., and Xue, D.F.: Solution-phase electronegativity scale: Insight into the chemical behaviors of metal ions in solution. J. Phys. Chem. A 116, 4192 (2012).Google Scholar
Chen, X., Chen, K.F., Wang, H., Song, S.Y., and Xue, D.F.: Crystallization of Fe3+ in an alkaline aqueous pseudocapacitor system. CrystEngComm 16, 6707–6715 (2014).Google Scholar
Supplementary material: File

Kang supplementary material

Figures S1-S5

Download Kang supplementary material(File)
File 744.4 KB