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Synthesis of intermetallic NiAl and Ni3Al fine powders through organometallic precursors

Published online by Cambridge University Press:  31 January 2011

Osami Abe  and
Akira Tsuge
Osami Abe
Affiliation:
Government Industrial Research Institute, Nagoya, 1–1 Hirate-cho, Kita-ku, Nagoya 462, Japan
Akira Tsuge
Affiliation:
Government Industrial Research Institute, Nagoya, 1–1 Hirate-cho, Kita-ku, Nagoya 462, Japan
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Abstract

Fine powders of intermetallic NiAl and Ni3Al were synthesized through organometallic precursors, which were coprecipitated from aqueous solutions of NiCl2 and AlCl3 by the addition of ammonium benzoate and hydradinium monochloride as precipitants. Ni3Al and NiAl were synthesized by a two-step heat treatment of the precursors. The initial step was the thermal decomposition of organic groups to form homogeneous mixtures of Ni3C, amorphous Al2O3, and free C below 1000 °C. The other step was the reaction above 1300 °C to form the intermetallics. Single phase powders of NiAl and Ni3Al with the particle size less than 3 μm were obtained above 1300 and 1400 °C, respectively.

Type
Articles
Information
Journal of Materials Research , Volume 6 , Issue 5 , May 1991 , pp. 928 - 934
Copyright
Copyright © Materials Research Society 1991

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References

1Benn, R. C., Michandani, P. K., and Watwe, A. S., Proc. Conf. Modern Developments in Powder Metallurgy (Am. Powder Metall. Inst., East Princeton, NJ, 1988), Vol. 20, p. 491.Google Scholar
2Yamaguchi, S. and Makoshi, Y., in Kinzoku-kan-kagoubutu (Intermetallic Compounds) (Kikkan-Kogyo-Sinbun-Sya, Tokyo, Japan, 1985), p. 33.Google Scholar
3Costa, P., in Research and Development of High-Temperature Materials for Industry (Elsevier Appl. Sci., London, England, 1989), p. 107.Google Scholar
4Strutt, P. R. and Kear, B. H., in High-Temperature Ordered Intermetallic Alloys, edited by Koch, C. C., Liu, C. T., and Stoloff, N. S. (Mater. Res. Soc. Symp. Proc. 39, Pittsburgh, PA, 1985), p. 279.Google Scholar
5Ball, A. and Smallman, R. E., Acta Metall. 14, 1349 (1966).CrossRefGoogle Scholar
6Rozner, A. G. and Wasilewski, R. J., J. Inst. Metals 94, 169 (1966).Google Scholar
7Hahn, K. H. and Vedula, K., Scripta Metall. 23, 7 (1989).CrossRefGoogle Scholar
8Schulson, E. M. and Barker, D. R., Scripta Metall. 17, 519 (1983).CrossRefGoogle Scholar
9Kim, M. S., Hanada, S., Watanabe, S., and Izumi, O., J. Jpn. Inst. Metall. 52, 1020 (1988).Google Scholar
10Whittenberger, J. D., J. Mater. Sci. 23, 235 (1988).CrossRefGoogle Scholar
11Takeyama, M. and Liu, C. T., Acta Metall. 37, 2681 (1989).CrossRefGoogle Scholar
12Huang, S. C. and Ritter, A. M., J. Mater. Res. 4, 288 (1989).Google Scholar
13Huang, S. C., Field, R. D., and Krueger, D. D., Metall. Trans. A 21A, 959 (1990).CrossRefGoogle Scholar
14Ivanov, E., Grigorieva, T., and Golubkove, G., Mater. Lett. 7, 51 (1988).CrossRefGoogle Scholar
15Kondo, Y., in Kagaku-Dai-Iiten (Encyclopaedia Chimica), edited by Mizushima, S. (Kyoritsu-Shuppan, Tokyo, Japan, 1980), p. 701.Google Scholar