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Structure and Thermal Stability of Nanostructured Iron-doped Zirconia Prepared by High-energy Ball Milling

Published online by Cambridge University Press:  31 January 2011

J. Z. Jiang ,
F. W. Poulsen  and
S. Mørup
J. Z. Jiang
Affiliation:
Department of Physics, Building 307, Technical University of Denmark, DK-2800, Lyngby, Denmark
F. W. Poulsen
Affiliation:
Materials Research Department, Risø National Laboratory, DK-4000 Roskilde, Denmark
S. Mørup
Affiliation:
Department of Physics, Building 307, Technical University of Denmark, DK-2800, Lyngby, Denmark
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Abstract

Fully stabilized cubic zirconia doped with iron oxide has been synthesized by high-energy ball milling from powder mixtures of monoclinic zirconia and hematite. It is found that the iron ions dissolved in cubic ZrO2 are in substitutional positions with a maximum solubility of approximately 18.5 mol% α–Fe2O3. The unit-cell volume of the cubic ZrO2 phase decreases with increasing iron content. During heating the cubic-to-tetragonal transition occurs at approximately 827 °C and the tetragonal-to-monoclinic transition seems to be absent at temperatures below 950 °C. During cooling the tetragonal-to-monoclinic transition occurs at 900–1100 °C.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 4 , April 1999 , pp. 1343 - 1352
Copyright
Copyright © Materials Research Society 1999

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