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Quasicrystalline phase formation in Al62Cu22.5Fe12.5 and Al55Cu22.5Fe12.5Be7 alloys

Published online by Cambridge University Press:  31 January 2011

S. M. Lee*
Affiliation:
Foundry Process Research Team, Korea Institute of Industrial Technology, 472 Kajwa 4-dong, Seo-ku, Inchon, 404-254, Korea
B. H. Kim
Affiliation:
Center for Noncrystalline Materials, Department of Metallurgical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-ku, Seoul, 120-749, Korea
D. H. Kim
Affiliation:
Center for Noncrystalline Materials, Department of Metallurgical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-ku, Seoul, 120-749, Korea
W. T. Kim
Affiliation:
Center for Noncrystalline Materials, Department of Metallurgical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-ku, Seoul, 120-749, Korea
*
a)Address all correspondence to this author. e-mial: smlee@kitech.re.kr
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Abstract

Formation of the icosahedral quasicrystalline phase in conventionally cast Al62Cu25.5Fe12.5 and Al55Cu25.5Fe12.5Be7 alloys were investigated. The icosahedral phase (I-phase) forming ability was greatly improved by partial replacement of Al by 7 at.% Be. The as-cast Al55Cu25.5Fe12.5Be7 alloy consisted of dendritic primary I-phase and interdendritic τ-phase, whereas that of an as-cast Al62Cu25.5Fe12.5 alloy consisted of various phases such as the β-, I-, and τ-phases, together with a small amount of the λ- and η-phases. The kinetic barrier for transformation into single I-phase by heat treatment was greatly reduced in an Al55Cu25.5Fe12.5Be7 alloy. The I-phase in an Al55Cu25.5Fe12.5Be7 alloy has the same face centered icosahedral structure as that in an Al62Cu25.5Fe12.5 alloy and is of high quality without phason strain.

Type
Articles
Copyright
Copyright © Materials Research Society 2001

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