Hostname: page-component-8448b6f56d-wq2xx Total loading time: 0 Render date: 2024-04-23T17:11:11.074Z Has data issue: false hasContentIssue false

Liquid metal extraction of Nd from NdFeB magnet scrap

Published online by Cambridge University Press:  31 January 2011

Y. Xu
Affiliation:
Ames Laboratory and the Materials Science & Engineering Department, Iowa State University, Ames, Iowa 50011
L. S. Chumbley
Affiliation:
Ames Laboratory and the Materials Science & Engineering Department, Iowa State University, Ames, Iowa 50011
F. C. Laabs
Affiliation:
Ames Laboratory and the Materials Science & Engineering Department, Iowa State University, Ames, Iowa 50011
Get access

Abstract

This research involves using molten magnesium (Mg) to remove neodymium (Nd) from NdFeB magnet scrap by diffusion. Mg was melted over pieces of NdFeB scrap and held at temperatures in the range 675–705 °C for 2–8 h. The Mg was allowed to solidify, and the castings were then sectioned and characterized using scanning electron microscopy, x-ray diffraction, and chemical analysis. Nd was found to have diffused out of the solid scrap into the molten Mg. The thickness of the diffusion layer was measured, the diffusion of Nd through the NdFeB scrap into liquid Mg was described, and the diffusion coefficient of Nd in liquid Mg was estimated.

Type
Articles
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Morrison, J.W. and Palmer, G.R., Second International Symposium, Recycling of Metals and Engineered Materials, Williamsburg, VA 28–31, pp. 593609 (Oct. 1990).Google Scholar
2.Lyman, J.W. and Palmer, G.R., High Temp. Mater. Processes (London) 11(1–4), 175187 (1993).CrossRefGoogle Scholar
3.Greenberg, B., Neodymium Recovery Process, U.S. Patent No. 5 362 459 (Nov. 8, 1994).Google Scholar
4.Peterson, D.T. and Kontrimas, R., J. Phys. Chem. 64, 362 (1960).CrossRefGoogle Scholar
5.Ellis, T.W., Schmidt, F.A., and Jones, L.L., Metals and Materials Waste Reduction, Recovery and Remediation (The Minerals, Metals & Materials Society, Warrendale, PA, 1994), pp. 199206.Google Scholar
6.Mukhina, I.Yu, Lebedev, V.M., Kim, Kyung-Hyun, and Kim, In-Bae, J. Adv. Mater. 3, 362 (1996).Google Scholar
7. Discussion with Ken Clark, then at Fansteel-Wellman Dynamics, of Creston, IA.Google Scholar
8.Zhang, W., Liu, G., and Han, K., J. Phase Equilib. 13, (1992).Google Scholar
9.Wecker, Joachim, Z. Metallkd. 81, 157 (1990).Google Scholar
10.Villars, P., Prince, A., and Okamoto, H., Handbook of Ternary Alloy Phase Diagram (ASM, Materials Park, OH, 1995), Vol. 5, p. 5599.Google Scholar
11.Binary Alloy Diagram, edited by Massalski, T.B. (American Society for Metals, Materials Park, OH, 1986), Vol. 1, p. 1085.Google Scholar
12.Shewmon, P.G., Diffusion in Solids (TMS, Warrendale, PA, 1989), pp. 131148.Google Scholar
13.Geiger, G.H. and Poirier, D.R., Transport Phenomena in Metallurgy (Addison-Wesley, Reading, MA, 1980). p. 431.Google Scholar