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Inorganic coordination polymer quantum sheets@graphene oxide composite photocatalysts: Performance and mechanism

Published online by Cambridge University Press:  15 July 2019

Shixiong Li Open the ORCID record for Shixiong Li [Opens in a new window] ,
Qiaoling Mo ,
Xiaoxia Lai ,
Yufeng Chen ,
Chuansong Lin ,
Yan Lu  and
Beiling Liao
Shixiong Li*
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Qiaoling Mo
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Xiaoxia Lai
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Yufeng Chen
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Chuansong Lin*
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Yan Lu
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Beiling Liao*
Affiliation:
School of Chemistry and Biological Engineering, Hechi University, Hechi 546300, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: lsx1324@163.com
b)e-mail: liaobeiling1324@163.com
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Abstract

Heterogeneous photocatalytic oxidation technology is currently a technology with the potential to solve environmental pollution and energy shortages. The key to this technology is to find and design efficient photocatalysts. Here, a series of inorganic coordination polymer quantum sheets (ICPQS)@graphene oxide (GO) composite photocatalysts are synthesized by adding GO to the synthesis process of ICPQS: {[CuII(H2O)4][CuI4(CN)6]}n. These composite photocatalysts were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, cyclic voltammetry, scanning electron microscopy, transmission electron microscopy, Zeta potential, and N2 adsorption/desorption isotherms. The photocatalytic degradation of methylene blue showed that the activity of ICPQS@GO composite photocatalysts is better than that of ICPQS. Among ICPQS@GO composite photocatalysts, the 10.6% ICPQS@GO composite photocatalyst has the best activity, which can reach 3.3 mg/(L min) at pH 3. This method of loading low–specific surface area photocatalysts onto GO to improve photocatalytic performance indicates the direction for the synthesis of highly efficient photocatalysts.

Keywords

graphene oxidecompositephotocatalystsquantum sheets
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 18 , 30 September 2019 , pp. 3220 - 3230
Copyright
Copyright © Materials Research Society 2019 

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