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In situ spherical B2 CuZr phase reinforced ZrCuNiAlNb bulk metallic glass matrix composite

Published online by Cambridge University Press:  31 January 2011

Jinmin Liu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China; and School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
Zhuang-Qi Hu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Xiaoguang Yuan
Affiliation:
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
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Abstract

In situ microlevel spherical B2 CuZr phase reinforced Zr49.5Cu36.45Ni4.05Al9Nb1 bulk metallic glass matrix composite was prepared successfully by the copper mold casting method. It was found that mechanical properties of Zr50.5Cu36.45Ni4.05Al9 alloy were improved largely due to the Nb addition. The room-temperature compressive fracture strength and plastic strain for Zr49.5Cu36.45Ni4.05Al9Nb1 rod with a diameter of 5 mm reaches 2037 MPa and 8%, respectively. The improvements are attributed to the precipitation of the spherical B2 CuZr phase distributed uniformly in amorphous matrix, which effectively hampers the propagation of shear bands by deflecting them at the interface and by a multiplication mechanism.

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Articles
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Johnson, W.L.Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999)CrossRefGoogle Scholar
2.Inoue, A.Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000)CrossRefGoogle Scholar
3.Schuh, C.A., Hufnagel, T.C., Ramamurty, U.Mechanical behavior of amorphous alloys. Acta Mater. 55, 4067 (2007)CrossRefGoogle Scholar
4.Conner, R.D., Dandliker, R.B., Johnson, W.L.Mechanical properties of tungsten and steel fiber reinforced Zr41.25Ti13.75Cu12.5Ni10Be22.5 metallic glass matrix composites. Acta Mater. 46, 6089 (1998)CrossRefGoogle Scholar
5.Zhang, H.F., Li, H., Wang, A.M., Fu, H.M., Ding, B.Z., Hu, Z.Q.Synthesis and characteristics of 80 vol% tungsten (W) fibre/Zr-based metallic glass composite. Intermetallics 17, 1070 (2009)CrossRefGoogle Scholar
6.Choi-Yim, H., Conner, R.D., Szuecs, F., Johnson, W.L.Processing, microstructure and properties of ductile metal particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 50, 2737 (2002)CrossRefGoogle Scholar
7.Pan, D.G., Zhang, H.F., Wang, A.M., Hu, Z.Q.Enhanced plasticity in Mg-based bulk metallic glass composite reinforced with ductile Nb particles. Appl. Phys. Lett. 89, 261904 (2006)CrossRefGoogle Scholar
8.Choi-Yim, H., Busch, R., Köster, U., Johnson, W.L.Synthesis and characterization of particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 47, 2455 (1999)CrossRefGoogle Scholar
9.Hofmann, D.C., Suh, J.Y., Wiest, A., Duan, G., Lind, M.L., Johnson, W.L.Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085 (2008)CrossRefGoogle ScholarPubMed
10.He, G., Eckert, J., Löser, W., Schultz, L.Novel Ti-base nanostructure-dendrite composite with enhanced plasticity. Nat. Mater. 2, 33 (2003)CrossRefGoogle ScholarPubMed
11.Hays, C.C., Kim, C.P., Johnson, W.L.Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901 (2000)CrossRefGoogle ScholarPubMed
12.Hui, X., Dong, W., Chen, G.L., Yao, K.F.Formation, microstructure and properties of long-period order structure reinforced Mg-based bulk metallic glass composites. Acta Mater. 55, 907 (2007)CrossRefGoogle Scholar
13.Das, J., Tang, M.B., Kim, K.B., Wang, W.H., Eckert, J.“Work-hardenable” ductile bulk metallic glass. Phys. Rev. Lett. 94, 205501 (2005)CrossRefGoogle ScholarPubMed
14.Inoue, A., Zhang, W., Tsurui, T., Yavari, A.R., Greer, A.L.Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass. Philos. Mag. Lett. 85, 221 (2005)CrossRefGoogle Scholar
15.Yao, K.F., Ruan, F., Yang, Y.Q., Chen, N.Superductile bulk metallic glass. Appl. Phys. Lett. 88, 122106 (2006)CrossRefGoogle Scholar
16.Sun, Y.F., Wei, B.C., Shek, C.H.Plasticity-improved Zr–Cu–Al bulk metallic glass matrix composites containing martensite phase. Appl. Phys. Lett. 87, 051905 (2005)CrossRefGoogle Scholar
17.Das, J., Pauly, S., Duhamel, C., Wei, B.C., Eckert, J.Microstructure and mechanical properties of slowly cooled Cu47.5Zr47.5Al5. J. Mater. Res. 22, 326 (2007)CrossRefGoogle Scholar
18.Zhang, L.C., Jiang, F., Sun, J., Zhang, Z.F.The mechanical properties of Cu–Zr based BMG and its composites under compression and bending. Adv. Eng. Mater. 10, 943 (2008)CrossRefGoogle Scholar
19.Pauly, S., Das, J., Bednarcik, J., Mattern, N., Kim, K.B., Kim, D.H., Eckert, J.Deformation-induced martensitic transformation in Cu–Zr–(Al,Ti) bulk metallic glass composites. Scr. Mater. 60, 431 (2009)CrossRefGoogle Scholar
20.Pauly, S., Liu, G., Kühn, U., Mattern, N., Eckert, J.Microstructural heterogeneities governing the deformation of Cu47.5Zr47.5Al5 bulk metallic glass composites. Acta Mater. 57, 5445 (2009)CrossRefGoogle Scholar
21.Schryvers, D., Firstov, G.S., Seo, J.W., Van-Humbeeck, J., Koval, Y.N.Unit cell determination in CuZr martensite by electron microscopy and x-ray diffraction. Scr. Mater. 36, 1119 (1997)CrossRefGoogle Scholar
22.Eckert, J., Das, J., Pauly, S., Duhamel, C.Mechanical properties of bulk metallic glasses and composites. J. Mater. Res. 22, 285 (2007)CrossRefGoogle Scholar
23.Louzguine-Luzgin, D.V., Saito, T., Saida, J., Inoue, A.Influence of cooling rate on the structure and properties of a Cu–Zr–Ti–Ag glassy alloy. J. Mater. Res. 23, 515 (2008)CrossRefGoogle Scholar
24.Huang, Y.J., Shen, J., Sun, J.F.Bulk metallic glasses: Smaller is softer. Appl. Phys. Lett. 90, 081919 (2007)CrossRefGoogle Scholar
25.Jae-Chul, L., Yu-Chan, K., Jae-Pyoung, A., Kim, H.S.Enhanced plasticity in a bulk amorphous matrix composite: Macroscopic and microscopic viewpoint studies. Acta Mater. 53, 129 (2005)Google Scholar