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In situ coordination of pyridine, quinoline, and quinoxaline with copper(I) iodide at the solid–liquid interface: Formation, characterization, and function of the microcrystal films

Published online by Cambridge University Press:  31 January 2011

Baoqiang Lv ,
Changming Cheng ,
Hongyan Yuan ,
Dan Xiao  and
Martin M.F. Choi
Baoqiang Lv
Affiliation:
College of Chemistry and College of Chemical Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Changming Cheng
Affiliation:
College of Chemistry and College of Chemical Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Hongyan Yuan
Affiliation:
College of Chemistry and College of Chemical Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Dan Xiao*
Affiliation:
College of Chemistry and College of Chemical Engineering, Sichuan University, Chengdu 610065, People’s Republic of China
Martin M.F. Choi
Affiliation:
Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: xiaodan@scu.edu.cn
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Abstract

An in situ surface-reaction approach has been developed for the synthesis of microcrystals Cu4I4(C6H5N)4, Cu4I4(C9H7N)4, and Cu2I2(C8H6N2) in solid films. Microcrystals of Cu4I4(C6H5N)4, Cu4I4(C9H7N)4, and Cu2I2(C8H6N2) were easily formed on a copper substrate at the solid Cu–liquid pyridine (C6H5N),–quinoline (C9H7N), and–quinoxaline (C8H6N2) interfaces. The resulting microcrystal films were characterized by photoluminescence spectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive x-ray spectroscopy, x-ray diffraction, and electrochemical impedance spectroscopy. The effect of ligands on the morphology of the film materials and their chemical properties were also discussed. These microcrystal films possessing reversible photocurrent and photovoltage properties were studied in detail. The photoactive and mechanically stable complex films described here may provide new strategies for fabricating photoluminescence solid films, photomodulation potential, and current films. The potential applications of the microcrystal films are for small light-induced electronic junction and photoluminescence sensors.

Keywords

Crystal growthFilmSurface reaction
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 6 , June 2008 , pp. 1722 - 1731
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Choi, K.S., Lichtenegger, H.C.Stucky, G.D.: Electrochemical synthesis of nanostructured ZnO films utilizing self-assembly of surfactant molecules at solid-liquid interfaces. J. Am. Chem. Soc. 124, 12402 2002CrossRefGoogle ScholarPubMed
2Didenko, V.V., Moore, V.C., Baskin, D.S.Smalley, R.E.: Visualization of individual single-walled carbon nanotubes by fluorescent polymer wrapping. Nano Lett. 5, 1563 2005CrossRefGoogle ScholarPubMed
3Jaramillo, T.F., Baeck, S., Kleiman-Shwarsctein, A., Choi, K., Stucky, G.D.McFarland, E.W.: Automated electrochemical synthesis and photoelectrochemical characterization of Zn1–xCoxO thin films for solar hydrogen production. J. Comb. Chem. 7, 264 2005CrossRefGoogle Scholar
4Vamvounis, G., Nystrom, D., Antoni, P., Lindgren, M., Holdcroft, S.Hult, A.: Self-assembly of poly(9,9’-dihexylfluorene) to form highly ordered isoporous films via blending. Langmuir 22, 959 2006CrossRefGoogle Scholar
5Kharlampieva, E., Izumrudov, V.A.Sukhishvili, S.A.: Electrostatic layer-by-layer self-assembly of poly(carboxybetaine)s: Role of zwitterions in film growth. Macromolecules 40, 3663 2007CrossRefGoogle Scholar
6Du, Y., Wei, H., Kang, J., Yan, J., Yin, X., Yang, X.Wang, E.: Microchip capillary electrophoresis with solid-state electrochemiluminescence detector. Anal. Chem. 77, 7993 2005CrossRefGoogle ScholarPubMed
7Shimazaki, Y., Mitsuishi, M., Ito, S.Yamamoto, M.: Preparation of the layer-by-layer deposited ultrathin film based on the charge-transfer interaction. Langmuir 13, 1385 1997CrossRefGoogle Scholar
8Yu, A., Liang, Z., Cho, J.Caruso, F.: Nanostructured electrochemical sensor based on dense gold nanoparticle films. Nano Lett. 3, 1203 2003CrossRefGoogle Scholar
9Matsui, J., Mitsuishi, M.Miyashita, T.: A study on fluorescence behavior of pyrene at the interface of polymer Langmuir-Blodgett films. J. Phys. Chem. B 106, 2468 2002CrossRefGoogle Scholar
10Cao, L., Spiess, F., Huang, A.Suib, S.L.: Heterogeneous photocatalytic oxidation of 1-butene on SnO2 and TiO2 films. J. Phys. Chem. B 103, 2912 1999CrossRefGoogle Scholar
11Liang, K., Mitzi, D.B.Prikas, M.T.: Synthesis and characterization of organic-inorganic perovskite thin films prepared using a versatile two-step dipping technique. Chem. Mater. 10, 403 1998CrossRefGoogle Scholar
12Ignatova, M., Labaye, D., Lenoir, S., Strivay, D., Jerome, R.Jerome, C.: Immobilization of silver in polypyrrole/polyanion composite coatings: Preparation, characterization, and antibacterial activity. Langmuir 19, 8971 2003CrossRefGoogle Scholar
13Kharlampieva, E.Sukhishvili, S.A.: Release of a dye from hydrogen-bonded and electrostatically assembled polymer films triggered by adsorption of a polyelectrolyte. Langmuir 20, 9677 2004CrossRefGoogle ScholarPubMed
14Ichinose, I., Senzu, H.Kunitake, T.: A surface sol-gel process of TiO2 and other metal oxide films with molecular precision. Chem. Mater. 9, 1296 1997CrossRefGoogle Scholar
15Fan, J., Boettcher, S.W.Stucky, G.D.: Nanoparticle assembly of ordered multicomponent mesostructured metal oxides via a versatile sol-gel process. Chem. Mater. 18, 6391 2006CrossRefGoogle Scholar
16Nicolau, Y.F.: Solution deposition of thin solid compound films by a successive ionic-layer adsorption and reaction process. Appl. Surf. Sci. 22/23, 1061 1985CrossRefGoogle Scholar
17Tamulevicius, S., Valkonen, M.P., Laukaitis, G., Lindroos, S.Leskela, M.: Stress and surface studies of SILAR grown CdS thin flms on GaAs(100). Thin Solid Films 355, 430 1999CrossRefGoogle Scholar
18Gong, H., Yin, M.Liu, M.: in situ coordination-induced Langmuir film formation of water-soluble 2,5-dimercapto-1,3,4-thiadiazole at the air/water interface and the growth of metal sulfide nanostructures in their templated Langmuir-Schaefer films. Langmuir 19, 8280 2003CrossRefGoogle Scholar
19Graham, P.M., Pike, R.D., Sabat, M., Bailey, R.D.Pennington, W.T.: Coordination polymers of copper(I) halides. Inorg. Chem. 39, 5121 2000CrossRefGoogle Scholar
20Ford, P.C., Cariati, E.Bourassa, J.: Photoluminescence properties of multinuclear copper(I) compounds. Chem. Rev. 99, 3625 1999CrossRefGoogle ScholarPubMed
21Hu, X., Yu, J.C., Gong, J.Li, Q.: A facile surface-etching route to thin films of metal iodides. Cryst. Growth Des. 7, 262 2007CrossRefGoogle Scholar
22Kyle, K.R., Ryu, C.K., DiBenedetto, J.A.Ford, P.C.: Photophysical studies in solution of the tetranuclear copper(I) clusters Cu414L4 (L = pyridine or substituted pyridine). J. Am. Chem. Soc. 113, 2954 1991CrossRefGoogle Scholar
23JCPDS No. 65-9743. International Center for Diffraction Data Newton Square, PA 2008Google Scholar
24JCPDS No. 06-0246. International Center for Diffraction Data Newton Square, PA 1995Google Scholar
25JCPDS No. 26-1763. International Center for Diffraction Data Newton Square, PA 1972Google Scholar
26Rath, N.P., Holt, E.M.Tanimura, K.: Fluorescent copper(I) complexes: correlation of structural and emission characteristics of [{CuI(quin)2}2] and [Cu4l4(quin)4] (quin = quinoline). J. Chem. Soc., Dalton Trans. 2303 1986CrossRefGoogle Scholar