Hostname: page-component-848d4c4894-tn8tq Total loading time: 0 Render date: 2024-07-01T08:07:18.019Z Has data issue: false hasContentIssue false
  • English
  • Français

Formation process of BaTiO3 particles by reaction between barium hydroxide aqueous solution and titania obtained by hydrolysis of titanium alkoxide

Published online by Cambridge University Press:  31 January 2011

Min Zeng ,
Naofumi Uekawa ,
Takashi Kojima  and
Kazuyuki Kakegawa
Min Zeng
Affiliation:
Graduate School of Science and Technology, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan
Naofumi Uekawa*
Affiliation:
Graduate School of Science and Technology, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan; and Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan
Takashi Kojima
Affiliation:
Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan
Kazuyuki Kakegawa
Affiliation:
Graduate School of Science and Technology, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan; and Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Inage-ku, Chiba-shi 263-8522, Japan
*
a)Address all correspondence to this author. e-mail: uekawa@faculty.chiba-u.jp
Get access

Abstract

BaTiO3 particles were prepared by heating a suspension of titania derived from the hydrolysis of titanium isopropoxide in a barium hydroxide [Ba(OH)2] aqueous solution. Well-crystallized cubic phase BaTiO3 fine particles were obtained by heating at a temperature >328 K for 24 h. The morphology and size of the obtained particles were affected by the reaction temperature and the Ba(OH)2/titanium alkoxide molar ratio. The secondary particles with a larger size were obtained at a lower reaction temperature. The nucleation process of BaTiO3 depended on the reaction temperature. The formation mechanism of BaTiO3 and the formation kinetics were investigated by measuring the concentrations of Ba2+ ions in the solution during the heating process. The BaTiO3 particle formation occurred on the surface of the titania particles after strong adsorption of the Ba2+ ions from the solution. The experimental results showed that the heterogeneous nucleation of BaTiO3 occurred on the titania surface.

Keywords

Surface chemistryHydrothermalParticulate
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 9 , September 2007 , pp. 2631 - 2638
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Hennings, D.: Barium titanate based ceramic materials for dielectric use. Int. J. High Technol. Ceram. 3, 91 1987CrossRefGoogle Scholar
2Pithan, C., Hennings, D.Waster, R.: Progress in the synhesis of nanocrystalline BaTiO3 powders for MLCC. Int. J. Appl. Ceram. Technol. 2, 1 2005CrossRefGoogle Scholar
3Battisha, I.K., Speghini, A., Polizzi, S., Agnoli, F.Bettinelli, M.: Molten chloride synthesis, structural characterization and luminescence spectroscopy of ultrafine Eu3+-doped BaTiO3 and SrTiO3. Mater. Lett. 57, 183 2002CrossRefGoogle Scholar
4Zuhang, M.S., Yin, Z., Chen, Q., Zhang, W.Chen, W.: Study of structural and photoluminescent properties in barium titanate nanocrystals synthesized by hydrothermal process. Solid State Commun. 119, 659 2001CrossRefGoogle Scholar
5Urek, S.Drofenik, M.: The hydrothermal synthesis of BaTiO3 fine particles from hydroxide-alkoxide precursors. J. Eur. Ceram. Soc. 18, 279 1998CrossRefGoogle Scholar
6Moon, J., Suvaci, E., Morrone, A., Costantino, S.A.Adair, J.H.: Formation mechanisms and morphological changes during the hydrothermal synthesis of BaTiO3 particles from a chemically modified, amorphous titanium (hydrous) oxide precursor. J. Eur. Ceram. Soc. 23, 2153 2003CrossRefGoogle Scholar
7Clark, I.J., Takeuchi, T., Ohtori, N.Sinclair, D.C.: Hydrothermal synthesis and characterization of BaTiO3 fine powders: Precursors, polymorphism and properties. J. Mater. Chem. 9, 83 1999CrossRefGoogle Scholar
8Feng, Q., Hirasawa, M.Kajiyoshi, K.: Hydrothermal soft chemical synthesis and particle morphology control of BaTiO3 in surfactant solutions. J. Am. Ceram. Soc. 88, 1415 2005CrossRefGoogle Scholar
9Kareiva, A., Tautkus, S., Rapalaviciute, R., Jorgensen, J-E.Lundtoft, B.: Sol-gel synthesis and characterization of barium titanate powders. J. Mater. Sci. 34, 4853 1999CrossRefGoogle Scholar
10Zhu, X., Zhu, J., Zhou, S., Liu, Z., Ming, N.Hesse, D.: BaTiO3 nanocrystals: Hydrothermal synthesis and structural characterization. J. Cryst. Growth 284, 486 2005CrossRefGoogle Scholar
11Golubko, N.V., Yanovskaya, M.I., Golubko, L.A., Kovsman, E.P., Listoshina, M.B.Rotenberg, B.A.: Preparation of barium titanate and related materials by the alkoxide-hydroxide route. J. Sol.-Gel Sci. Technol. 20, 135 2001CrossRefGoogle Scholar
12Kwon, S.G., Park, B.H., Choi, K., Choi, E.S., Nam, S., Kim, J.W.Kim, J.H.: Solvothermally synthesized tetragonal barium titanate powders using H2O/EtOH solvent. J. Eur. Ceram. Soc. 26, 1401 2006CrossRefGoogle Scholar
13Hung, K-M., Yang, W-D.Huang, C-C.: Preparation of nanometer-sized barium titanate powders by a sol-precipitation process with surfactants. J. Eur. Ceram. Soc. 23, 1901 2003CrossRefGoogle Scholar
14Moon, J., Suvaci, E., Morrone, A., Costantino, S.A.Adair, J.H.: Formation mechanisms and morphological changes during the hydrothermal synthesis of BaTiO3 particles from a chemically modified, amorphous titanium (hydrous) oxide precursor. J. Eur. Ceram. Soc. 23, 2153 2003CrossRefGoogle Scholar
15Hertil, W.: Kinetics of barium titanate synthesis. J. Am. Ceram. Soc. 71, 879 1988CrossRefGoogle Scholar
16Pinceloup, P., Courtois, C., Vicens, J., Leriche, A.Thierry, B.: Evidence of a dissolution–precipitation mechanism in hydrothermal synthesis of barium titanate powders. J. Eur. Ceram. Soc. 19, 973 1999CrossRefGoogle Scholar
17Eckert, J.O. Jr., Hung-Houston, C.C., Gersten, B.L., Lencka, M.M.Riman, R.E.: Kinetics and mechanism of hydrothermal synthesis of barium titanate. J. Am. Ceram. Soc. 79, 2929 1996CrossRefGoogle Scholar
18Xu, H.Gao, L.: New evidence of a dissolution-precipitation mechanism in hydrothermal synthesis of barium titanate powders. Mater. Lett. 57, 490 2002CrossRefGoogle Scholar
19Testino, A., Buscaglia, V., Buscaglia, M.T., Viviani, M.Nanni, P.: Kinetic modeling of aqueous and hydrothermal synthesis of barium titanate. Chem. Mater. 17, 5346 2005CrossRefGoogle Scholar
20Walton, R.I., Millange, F., Smith, R.I., Hansen, T.C.O’Hare, D.: Real time observation of the hydrothermal crystallization of barium titanate using in situ neutron powder diffraction. J. Am. Chem. Soc. 123, 12547 2001CrossRefGoogle ScholarPubMed
21Testino, A., Buscaglia, M.T., Buscaglia, V., Viviani, M., Bottino, C.Nanni, P.: Kinetics and mechanism of aqueous chemical synthesis of BaTiO3 particles. Chem. Mater. 16, 1536 2004CrossRefGoogle Scholar
22Cranston, R.W.Inkley, F.A.: Advances in Catalysis Vol. 9, Academic Press New York and London 1957 143Google Scholar