Hostname: page-component-77c89778f8-7drxs Total loading time: 0 Render date: 2024-07-18T16:54:18.689Z Has data issue: false hasContentIssue false
  • English
  • Français

Extraction of Rare Earth from La–Ni Alloys by the Glass Slag Method

Published online by Cambridge University Press:  31 January 2011

Tetsuji Saito ,
Hironori Sato  and
Tetsuichi Motegi
Tetsuji Saito
Affiliation:
Department of Mechanical Engineering and Science, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino, Chiba 275-0016 Japan
Hironori Sato
Affiliation:
Department of Mechanical Engineering and Science, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino, Chiba 275-0016 Japan
Tetsuichi Motegi
Affiliation:
Department of Mechanical Engineering and Science, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino, Chiba 275-0016 Japan
Get access

Abstract

The use of the glass slag method in the extraction of rare earth from La–Ni alloys was studied. X-ray diffraction and electron probe microanalysis studies revealed that the La–Ni alloys produced by the glass slag method using boron trioxide consisted of Ni and Ni3B phases. No La-containing phase such as the LaNi5 phase and the La oxide phase was found in the resultant alloys. The chemical analyses confirmed that the La content in the alloys produced by the glass slag method was very limited. However, the glass slag materials contained a large amount of lanthanum. The La in the La–Ni alloys was successfully extracted by the glass slag method using boron trioxide.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 12 , December 2003 , pp. 2814 - 2819
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Tourre, J.M., in Proceedings of the Fifteenth International Workshop on Rare-Earth Alloys and Applications, edited by Hadjipanayis, G.C. and Bonder, M.J (Rinton Press, Princeton, NJ, 1998), Vol. 1, p. 31.Google Scholar
2.McCallum, R.W., in Proceedings of the Seventeenth International Workshop on Rare-Earth Alloys and Applications, edited by Schultz, L. and Müller, K-H. (Werkstoff-Informationsgesellschaft mbH, Frankfurt, Germany, 2002), p. 1.Google Scholar
3.Reilly, J.J. and Wiswall, R.H., Jr., Inorg. Chem. 13, 218 (1974).CrossRefGoogle Scholar
4.Lyman, J.W. and Palmer, G.R., High Temp. Mater. Proc. 11, 175 (1993).CrossRefGoogle Scholar
5.Sato, N., Wei, Y., and Tokuda, M., Shigen-to-Sozai 113, 1082 (1997).CrossRefGoogle Scholar
6.Uda, T., Mater. Trans 43, 55 (2002).CrossRefGoogle Scholar
7.Xu, Y., Chumbley, L.S., and Laabs, F.C., J. Mater. Res. 15, 2296 (2000).CrossRefGoogle Scholar
8.Okabe, T.H., Takeda, O., Fukuda, K., and Umetsu, Y., Mater. Trans. 44, 798 (2003).CrossRefGoogle Scholar
9.Katamis, T.Z. and Flemings, M.C., Trans. Metall. Soc. AIME 236, 1523 (1966).Google Scholar
10.Ozawa, S., Sato, H., Saito, T., Motegi, T., and Yu, J., J. Appl. Phys. 91, 8831 (2002).CrossRefGoogle Scholar
11.Saito, T., Sato, H., Ozawa, S., Yu, J., and Motegi, T., J. Alloy Compd. 353, 189 (2003).CrossRefGoogle Scholar
12.Saito, T., Sato, H., Ozawa, S., and Motegi, T., Mater. Trans. 44, 637 (2003).CrossRefGoogle Scholar
13.Rojo, J.M., Hernando, A., Ghannaimi, M. El, Garcia-Escorial, A., Gonzalez, M.A., Garcia-Martinez, R., and Racciarelli, L., Phys. Rev. Lett. 76, 4833 (1996).CrossRefGoogle Scholar
14.Chiazumi, S., Physics of Magnetism (Krieger, Malabar, FL, 1978), p. 19.Google Scholar
15.Levin, E.M., Robbins, C.R., and McMurdie, H.F., Phase Diagram of Ceramists (The American Ceramic Society, Westerville, OH, 1985), p. 124.Google Scholar
16.http://www.canon.co.jp/technology/environmentGoogle Scholar