Hostname: page-component-848d4c4894-2xdlg Total loading time: 0 Render date: 2024-06-27T22:48:55.307Z Has data issue: false hasContentIssue false

Effects of Borosilicate Glass on Densification and Properties of Borosilicate Glass + TiO2 Ceramics

Published online by Cambridge University Press:  31 January 2011

Jau-Ho Jean
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan, Republic of China
Shih-Chun Lin
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan, Republic of China
Get access

Abstract

Effects of borosilicate glass (BSG) on densification and dielectric and thermal expansion properties of a binary composite of BSG + TiO2 ceramics have been investigated. Two different phases of TiO2 including anatase and rutile are used. A much greater densification is observed with anatase because it has a much better wetting with BSG than rutile. With increasing BSG content, the densification of BSG + TiO2 increased. Activation analysis shows that the densification is controlled by viscous flow of BSG. Both dielectric constant and coefficient of thermal expansion of the binary composite of BSG + TiO2 increase with decreasing BSG content and increasing the degree of anatase-to-rutile transformation, as well.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Kwon, O-H. and Messing, G. L., J. Am. Ceram. Soc. 73, 275 (1990).Google Scholar
2.Singh, V.K., J. Am. Ceram. Soc. 64, C133 (1981).Google Scholar
3.Ewsuk, K.G. and Harrison, L. W., Advances in Ceramics, edited by Handwerker, C., Blendell, J., and Kaysser, W. (The American Ceramic Society, Westerville, OH, 1990), Vol. 29, p. 356.Google Scholar
4.Kingery, W.D., Niki, E., and Narasimhan, M. D., J. Am. Ceram. Soc. 44, 29 (1961).Google Scholar
5.German, R. M., Liquid Phase Sintering (Plenum Press, New York, 1985), Chap. 1.Google Scholar
6.Jean, J-H. and Gupta, T. K., J. Mater. Sci. 27, 1575 (1992).CrossRefGoogle Scholar
7.Jean, J-H. and Gupta, T. K., J. Mater. Sci. 27, 4967 (1992).CrossRefGoogle Scholar
8.Jean, J-H. and Gupta, T. K., J. Mater. Res. 9, 771 (1994).CrossRefGoogle Scholar
9.Jean, J-H. and Gupta, T. K., J. Mater. Res. 9, 486 (1994).Google Scholar
10.Barringer, E.A. and Bowen, H. K., J. Am. Ceram. Soc. 65, C199 (1982).Google Scholar
11.Yan, M. F. and Rhodes, W.W., Mater. Sci. Eng. 61, 59 (1983).Google Scholar
12.Hahn, H., Logas, J., and Averback, R. S., J. Mater. Res. 5, 609 (1990).Google Scholar
13.Gamboa, J. A. and Pasquevich, D.M., J. Am. Ceram. Soc. 75, 2934 (1992).Google Scholar
14.Jean, J-H. and Lin, S-C., unpublished.Google Scholar
15.Cannon, H.S. and Lenel, F. V., Proc. Plansee Semin., edited by Benesovsky, F. (Metallwerk Plansee, Reutte, 1953), p. 106.Google Scholar
16.Kingery, W.D., J. Appl. Phys. 30, 301 (1959).Google Scholar
17.Epse, W., Materials of High Vacuum Technology (Pergamon Press, Oxford, 1968), Vol. 2, Chap. 10.Google Scholar
18.Jean, J-H. and Kuan, T.H., Jpn. J. Appl. Phys. 34, 1901 (1995).Google Scholar
19.Greenhut, V.A., Engineered Materials Handbook (ASM INTERNATIONAL, Materials Park, OH, 1991), Vol. 4, p. 30.Google Scholar