Hostname: page-component-8448b6f56d-42gr6 Total loading time: 0 Render date: 2024-04-18T15:22:31.031Z Has data issue: false hasContentIssue false

Effect of neutron radiation on the mechanical and thermophysical properties of nanoengineered polymer composites

Published online by Cambridge University Press:  05 January 2017

Nasim Abuali Galehdari
Affiliation:
Joint School of Nanoscience and Nanoengineering, Department of Nanoengineering, NC A&T State University, Greensboro, NC 27401, USA
Ajit D. Kelkar*
Affiliation:
Joint School of Nanoscience and Nanoengineering, Department of Nanoengineering, NC A&T State University, Greensboro, NC 27401, USA
*
a)Address all correspondence to this author. e-mail: Kelkar@ncat.edu
Get access

Abstract

Polymer nanocomposites are being considered as future materials to effectively attenuate high energy radiations. The present work addresses effects of neutron radiation on the mechanical properties of lightweight multifunctional polymer composite which were fabricated by dispersing nanoparticles with radiation shielding properties in an epoxy polymer. Three different types of nanoparticles including boron nanopowder, gadolinium, and boron carbide, which are known for excellent radiation absorbing characteristics, were dispersed into epoxy resin to form core sheets for final hybrid sandwich structure. The neutron radiation shielding performance of nanocomposites and their mechanical and thermophysical properties were investigated. The study indicates that the neutron shielding efficiency increased significantly by introduction of nanoparticles. Moreover, the mechanical testing and thermophysical analysis showed that the core materials can retain the structural integrity after they are exposed to the highly thermalized neutron radiation in steady-state mode with a flux of 3 × 1013 n/cm2/s.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Cucinotta, F.A.: Space radiation organ doses for astronauts on past and future missions. NASA Johnson Sp. Cent. Rep. (2007).Google Scholar
Cucinotta, F.A., Alp, M., Sulzman, F.M., and Wang, M.: Space radiation risks to the central nervous system. Life Sci. Space Res. 2, 54 (2014).Google Scholar
Kennedy, A.R.: Biological effects of space radiation and development of effective countermeasures. Life Sci. Space Res. 1, 10 (2014).Google Scholar
Cucinotta, F.A.: Space radiation risks for astronauts on multiple international space station missions. PLoS One 9, 16 (2014).CrossRefGoogle ScholarPubMed
Li, Z., Nambiar, S., Zheng, W., and Yeow, J.T.W.: PDMS/single-walled carbon nanotube composite for proton radiation shielding in space applications. Mater. Lett. 108, 79 (2013).Google Scholar
Good, R.C., Shen, S.P., and Dow, N.F.: Active shielding concepts for the ionizing radiation in space. NASA (1994).Google Scholar
Tripathi, R.K., Wilson, J.W., and Youngquist, R.C.: Electrostatic space radiation shielding. Adv. Space Res. 42, 1043 (2008).Google Scholar
Thibeault, S.A., Kang, J.H., Sauti, G., Park, C., Fay, C.C., and King, G.C.: Nanomaterials for radiation shielding. MRS Bull. 40, 836 (2015).Google Scholar
Stiegler, J.O. and Mansur, L.K.: Radiation effects in structural materials. Annu. Rev. Mater. Sci. 9, 405 (1979).Google Scholar
Fintzou, A.T., Badeka, A.V., Kontominas, M.G., and Riganakos, K.A.: Changes in physicochemical and mechanical properties of γ-irradiated polypropylene syringes as a function of irradiation dose. Radiat. Phys. Chem. 75, 87 (2006).CrossRefGoogle Scholar
Reitz, G.: Characteristic of the radiation field in low Earth orbit and in deep space. Z. Med. Phys. 18, 233 (2008).CrossRefGoogle ScholarPubMed
Marshall, P.W., Dale, C.J., and Burke, E.A.: Space radiation effects on optoelectronic materials and components for a 1300 nm fiber optic data bus. IEEE Trans. Nucl. Sci. 39, 1982 (1992).CrossRefGoogle Scholar
Mertens, C.J., Kress, B.T., Wiltberger, M., Blattnig, S.R., Slaba, T.S., Solomon, S.C., and Engle, M.: Aircraft radiation exposure during a high-energy solar energetic particle event in October 2003. Space Weather. This issue No. October, 1 (2009).Google Scholar
Kim, J., Lee, B.C., Uhm, Y.R., and Miller, W.H.: Enhancement of thermal neutron attenuation of nano-B4C, -BN dispersed neutron shielding polymer nanocomposites. J. Nucl. Mater. 453, 48 (2014).CrossRefGoogle Scholar
Slaba, T.C., Blattnig, S.R., Aghara, S.K., Townsend, L.W., Handler, T., Gabriel, T.A., Pinsky, L.S., and Reddell, B.: Coupled neutron transport for HZETRN. Radiat. Meas. 45, 173 (2010).Google Scholar
Nambiar, S. and Yeow, J.T.W.: Polymer-composite materials for radiation protection. ACS Appl. Mater. Interfaces 4, 57175726 (2012).CrossRefGoogle ScholarPubMed
Kodaira, S., Tolochek, R.V., Ambrozova, I., Kawashima, H., Yasuda, N., Kurano, M., Kitamura, H., Uchihori, Y., Kobayashi, I., Hakamada, H., Suzuki, A., Kartsev, I.S., Yarmanova, E.N., Nikolaev, I.V., and Shurshakov, V.A.: Verification of shielding effect by the water-filled materials for space radiation in the International Space Station using passive dosimeters. Adv. Space Res. 53, 1 (2014).Google Scholar
Adams, J.H., Hathaway, D.H., Grugel, R.N., Watts, J.W., Parnell, T.a., Gregory, J.C., and Winglee, R.M.: Revolutionary concepts of radiation shielding for human exploration of space. NASA No. March, 1 (2005).Google Scholar
Jung, C-H., Lee, D-H., Hwang, I-T., Im, D-S., Shin, J., Kang, P-H., and Choi, J-H.: Fabrication and characterization of radiation-resistant LDPE/MWCNT nanocomposites. J. Nucl. Mater. 438, 41 (2013).Google Scholar
Zhong, W.H., Sui, G., Jana, S., and Miller, J.: Cosmic radiation shielding tests for UHMWPE fiber/nano-epoxy composites. Compos. Sci. Technol. 69, 2093 (2009).Google Scholar
Özdemir, T., Akbay, İ.K., Uzun, H., and Reyhancan, İ.A.: Neutron shielding of EPDM rubber with boric acid: Mechanical, thermal properties and neutron absorption tests. Prog. Nucl. Energy 89, 102 (2016).Google Scholar
Chai, H., Tang, X., Ni, M., Chen, F., Zhang, Y., Chen, D., and Qiu, Y.: Preparation and properties of flexible flame-retardant neutron shielding material based on methyl vinyl silicone rubber. J. Nucl. Mater. 464, 210 (2015).Google Scholar
Nelson, A.J., Baby, L., Boroujeni, A.Y., and Hussaini, M.Y.: Effect of proton irradiation on the electrical resistivity of carbon nanotube–epoxy composites. Nanosci. Nanotechnol. Lett. 7, 157 (2015).Google Scholar
Özdemir, T.: Monte Carlo simulations of radioactive waste embedded into EPDM and effect of lead filler. Radiat. Phys. Chem. 98, 150 (2014).Google Scholar
Chang, L., Zhang, Y., Liu, Y., Fang, J., Luan, W., Yang, X., and Zhang, W.: Preparation and characterization of tungsten/epoxy composites for γ-rays radiation shielding. Nucl. Instrum. Methods Phys. Res., Sect. B 356, 88 (2015).Google Scholar
Kipcak, A.S., Gurses, P., Derun, E.M., Tugrul, N., and Piskin, S.: Characterization of boron carbide particles and its shielding behavior against neutron radiation. Energy Convers. Manage. 72, 39 (2013).Google Scholar
Chikhradze, N.M., Marquis, F.D.S., Abashidze, G.S., and Kurdadze, L.: Development and performance of new gadolinium and boron containing radiation-absorbing composite systems. JOM 65, 728 (2013).CrossRefGoogle Scholar
Estevez, J.E., Ghazizadeh, M., Ryan, J.G., and Kelkar, A.D.: Simulation of hydrogenated boron nitride nanotube’s mechanical properties for radiation shielding applications. Int. J. Chem. Sci. Eng. 8, 63 (2014).Google Scholar
Ghazizadeh, M., Estevez, J.E., Kelkar, A.D., and Ryan, J.G.: Mechanical properties prediction of hydrogenated boron nitride nanotube’s using molecular dynamic simulations. JSM Nanotechnol. Nanomed. 2, 2 (2014).Google Scholar
Huang, Y., Zhang, W., Liang, L., Xu, J., and Chen, Z.: A “Sandwich” type of neutron shielding composite filled with boron carbide reinforced by carbon fiber. Chem. Eng. J. 220, 143 (2013).CrossRefGoogle Scholar
Zhang, X., Wang, Y., and Cheng, S.: Properties of UHMWPE fiber-reinforced composites. Polym. Bull. 70, 821 (2013).Google Scholar
Wang, H., Xu, L., Hu, J., Wang, M., and Wu, G.: Radiation-induced oxidation of ultra-high molecular weight polyethylene (UHMWPE) powder by gamma rays and electron beams: A clear dependence of dose rate. Radiat. Phys. Chem. 115, 88 (2015).Google Scholar
Cao, X., Xue, X., Jiang, T., Li, Z., Ding, Y., Li, Y., and Yang, H.: Mechanical properties of UHMWPE/Sm2O3 composite shielding material. J. Rare Earths 28, 482 (2010).Google Scholar
Galehdari, N.A., Mani, V., and Kelkar, A.D.: Fabrication of Nanoengineered Radiation Shielding Multifunctional Polymeric Sandwich Composites. Int. J. Chem. Mol. Nucl. Mater. Metall. Eng. 10, 257 (2016).Google Scholar
Kelkar, A., Komuves, F., Mohan, R., and Kelkar, V.: In 52nd AIAA/ASME/ASCE/AHS/ASC Struct. Struct. Dyn. Mater. Conf. Denver, Color. (2011).Google Scholar
Zhang, X., Yan, X., Guo, J., Liu, Z., Jiang, D., He, Q., Wei, H., Gu, H., Colorado, H.a., Zhang, X., Wei, S., and Guo, Z.: Polypyrrole doped epoxy resin nanocomposites with enhanced mechanical properties and reduced flammability. J. Mater. Chem. C 3, 162 (2015).Google Scholar
Naebe, M., Wang, J., Amini, A., Khayyam, H., Hameed, N., Li, L.H., Chen, Y., and Fox, B.: Mechanical property and structure of covalent functionalised graphene/epoxy nanocomposites. Sci. Rep. 4, (2015).Google Scholar
Jalali, M., Molière, T., Michaud, A., and Wuthrich, R.: Multidisciplinary characterization of new shield with metallic nanoparticles for composite aircrafts. Composites, Part B 50, 309 (2013).CrossRefGoogle Scholar
Lange, F.F. and Radford, K.C.: Fracture energy of an epoxy composite system. J. Mater. Sci. 6, 1197 (1971).Google Scholar
McGrath, L.M., Parnas, R.S., King, S.H., Schroeder, J.L., Fischer, D.A., and Lenhart, J.L.: Investigation of the thermal, mechanical, and fracture properties of alumina–epoxy composites. Polymer 49, 999 (2008).Google Scholar
Arab, B. and Shokuhfar, A.: The effect of cross linking density on the mechanical properties and structure of the epoxy polymers: Molecular dynamics simulation. J. Mol. Model. 19, 3719 (2013).Google Scholar
Li, C., Coons, E., and Strachan, A.: Material property prediction of thermoset polymers by molecular dynamics simulations. Acta Mech. 225, 1187 (2014).Google Scholar