Hostname: page-component-76fb5796d-skm99 Total loading time: 0 Render date: 2024-04-26T07:59:45.932Z Has data issue: false hasContentIssue false

The effect of Hf and Ti additions on microstructure and properties of Cr2Nb–Nb in situ composites

Published online by Cambridge University Press:  31 January 2011

B.P. Bewlay
Affiliation:
General Electric Company, Corporate Research and Development Center, P. O. Box 8, Schenectady, New York 12301
M. R. Jackson
Affiliation:
General Electric Company, Corporate Research and Development Center, P. O. Box 8, Schenectady, New York 12301
Get access

Abstract

The present paper describes the effect of Hf and Ti additions on the microstructures and mechanical properties of two-phase composites based on the Cr2Nb–Nb eutectic. The microstructures of directionally solidified in situ composites containing 50–70% by volume of the Laves phase Cr2Nb which was modified with Hf (7.5–9.2%) and Ti (16.5–26%) are described. Partitioning of Hf and Ti between the two phases is discussed using microprobe and EDS results. The tensile properties at 1100 and 1200 °C are described and compared with those of an analogous niobium silicide-based composite. The Cr2(Nb)–(Nb) composite tensile yield strengths at 1200 °C were increased over that of monolithic Cr2Nb to ∼130 MPa. However, at 1200 °C the yield strengths of the silicide-based composites were approximately twice those of the Cr2(Nb)–(Nb) composites.

Type
Articles
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Anton, D. L. and Shah, D.M., Mater. Sci. Eng. A153, 410415 (1992).CrossRefGoogle Scholar
2.Anton, D. L. and Shah, D. M., in High-Temperature Ordered In-termetallic Alloys IV, edited by Johnson, L. A., Pope, D. A., and Stiegler, J. O. (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), pp. 733738.Google Scholar
3.Goldschmidt, H. J. and Brand, J. A., J. Less-Comm. Met. 3, 4461 (1961).CrossRefGoogle Scholar
4.Fleischer, R. L, Briant, C. L., and Field, R. D., in High-Temperature Ordered Intermetallic Alloys IV, edited by Johnson, L. A., Pope, D. A., and Stiegler, J. O. (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), pp. 463474.Google Scholar
5.Bewlay, B. P., Sutliff, J.A., Jackson, M.R., and Lipsitt, H.A., Acta Metall. Mater. 42 (8), 28692878 (1994).CrossRefGoogle Scholar
6.Bewlay, B. P., Lipsitt, H. A., Jackson, M. R., Reeder, W. J., and Sutliff, J. A., Mater. Sci. Eng. A192/193, 534543 (1995).CrossRefGoogle Scholar
7.Takeyama, M. and Liu, C. T., Mater. Sci. Eng. A132, 6166 (1991).CrossRefGoogle Scholar
8.Takasugi, T., Hanada, S., and Miyamoto, K., J. Mater. Res. 8, 30693077 (1993).CrossRefGoogle Scholar
9.Jackson, M. R. and Jones, K. D., in Refractory Metals Extraction, Processing and Applications, edited by Liddell, K. C., Sad-oway, D. R., and Bautista, R. G. (TMS Publications, Warrendale, PA, 1991), pp. 310320.Google Scholar
10.Bewlay, B. P. and Jackson, M. R. unpublished.Google Scholar
11.Jackson, M. R., Skelly, D.W., and Rowe, R. G.Annual Reports, WRDC Contract #F33615-91-C-5613 (1994, 1995).Google Scholar
12.Venkatraman, M. and Neumann, J. P., Bull. Alloy Phase Diagrams 7 (5), 462466 (1986).CrossRefGoogle Scholar
13.Thoma, D. J. and Perepezko, J. H., in Intermetallic Matrix Composites, edited by Anton, D. L., Martin, P. L., Miracle, D. B., and McMeeking, R. (Mater. Res. Soc. Symp. Proc. 194, Pittsburgh, PA, 1990), pp. 105112.Google Scholar
14.Thoma, D. J. and Perepezko, J. H., Mater. Sci. Eng. A156, 97108 (1992).CrossRefGoogle Scholar
15.Massalski, T. B., Binary Alloy Phase Diagrams (ASM INTERNATIONAL, Materials Park, OH, 1991).Google Scholar
16.Davidson, D. L. and Chan, K. S., AFOSR Final Report (April 1995).Google Scholar
17.Kumar, K. S. and Miracle, D. B., Intermetallics 2, 257274 (1994).CrossRefGoogle Scholar
18.Ravichandran, K. S., Miracle, D. B., and Mendiratta, M. G., in Intermetallic Matrix Composites III, edited by Graves, J. A., Bowman, R. R., and Lewandowski, J. J. (Mater. Res. Soc. Symp. Proc. 350, Pittsburgh, PA, 1994), pp. 249254.Google Scholar