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Copper- and nickel-based flexible polyester electrodes for energy storage devices

Published online by Cambridge University Press:  23 June 2020

Abdulcabbar Yavuz*
Affiliation:
Engineering Faculty, Metallurgical and Materials Engineering Department, Gaziantep University, Sehitkamil, 27310Gaziantep, Turkey
*
a)Address all correspondence to this author. e-mail: ayavuz@gantep.edu.tr
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Abstract

Lightweight, inexpensive and flexible electrodes are required for flexible technological applications. As polymers are generally low cost, flexible and have low density, they are potential candidates for use as flexible electrodes. However, polymers are not conductive and thus cannot be used as electrodes or current collectors. Polymers have been coated by metals/alloys to make them conductive for use in various applications including electromagnetic shielding and sensors. In this work, a flexible electrode was successfully fabricated by electrodeposition of Cu and Ni on polyester fabric for an energy storage application. The growth of metals was carried out in non-aqueous ionic liquid electrolyte, with the deposition condition of Cu and Ni studied by means of cyclic voltammetry. Non-electrochemical (FTIR, XRD, SEM and EDAX) characterizations of the metal-coated polyester are also presented. Modified flexible electrodes were transferred to an alkaline electrolyte for electrochemical characterization. The specific capacitance of Cu- and Ni-coated polyester reached 33.4 F/g and 50.2 F/g at the same scan rate of 5 mV/s. These results suggest an inexpensive and straightforward method for the fabrication of a flexible electrode for energy storage applications.

Type
Article
Copyright
Copyright © Materials Research Society 2020

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References

Liu, L., Feng, Y., and Wu, W.: Recent progress in printed flexible solid-state supercapacitors for portable and wearable energy storage. J. Power Sources 410, 69 (2019).CrossRefGoogle Scholar
Zhao, Y., Min, X., Ding, Z., Chen, S., Ai, C., Liu, Z., Yang, T., Wu, X., Liu, Y., and Lin, S.: Metal-based nanocatalysts via a iniversal design on cellular structure. Adv. Sci. 7, 1902051 (2020).CrossRefGoogle Scholar
Li, S., Fan, L., and Lu, Y.: Rational design of robust-flexible protective layer for safe lithium metal battery. Energy Storage Mater. 18, 205 (2019).CrossRefGoogle Scholar
Yan, J., Li, S., Lan, B., Wu, Y., and Lee, P.S.: Rational design of nanostructured electrode materials toward multifunctional supercapacitors. Adv. Funct. Mater. 30, 1902564 (2020).CrossRefGoogle Scholar
Schischke, K., Nissen, N.F., and Schneider-Ramelow, M.: Flexible, stretchable, conformal electronics, and smart textiles: Environmental life cycle considerations for emerging applications. MRS Commun 10, 69 (2020).CrossRefGoogle Scholar
Min, X., Sun, B., Chen, S., Fang, M., Wu, X., Liu, Y., Abdelkader, A., Huang, Z., Liu, T., and Xi, K.: A textile-based SnO2 ultra-flexible electrode for lithium-ion batteries. Energy Storage Mater. 16, 597 (2019).CrossRefGoogle Scholar
Sun, C., Li, X., Cai, Z., and Ge, F.: Carbonized cotton fabric in-situ electrodeposition polypyrrole as high-performance flexible electrode for wearable supercapacitor. Electrochim. Acta 296, 617 (2019).CrossRefGoogle Scholar
Torop, J., Palmre, V., Arulepp, M., Sugino, T., Asaka, K., and Aabloo, A.: Flexible supercapacitor-like actuator with carbide-derived carbon electrodes. Carbon N. Y 49, 3113 (2011).CrossRefGoogle Scholar
Huang, Y., Zhao, Y., Bao, J., Lian, J., Cheng, M., and Li, H.: Lawn-like FeCo2S4 hollow nanoneedle arrays on flexible carbon nanofiber film as binder-free electrodes for high-performance asymmetric pseudocapacitors. J. Alloys Compd. 772, 337 (2019).CrossRefGoogle Scholar
Palchoudhury, S., Ramasamy, K., Gupta, R.K., and Gupta, A.: Flexible supercapacitors: A materials perspective. Front. Mater. 5, 83 (2019).CrossRefGoogle Scholar
Jana, K.K., Lue, S.J., Huang, A., Soesanto, J.F., and Tung, K.: Separator membranes for high energy-density batteries. ChemBioEng Rev. 5, 346 (2018).CrossRefGoogle Scholar
Zhai, S., Karahan, H.E., Wei, L., Qian, Q., Harris, A.T., Minett, A.I., Ramakrishna, S., Ng, A.K., and Chen, Y.: Textile energy storage: Structural design concepts, material selection and future perspectives. Energy Storage Mater. 3, 123 (2016).CrossRefGoogle Scholar
Sumboja, A., Liu, J., Zheng, W.G., Zong, Y., Zhang, H., and Liu, Z.: Electrochemical energy storage devices for wearable technology: A rationale for materials selection and cell design. Chem. Soc. Rev. 47, 5919 (2018).CrossRefGoogle ScholarPubMed
Ramadoss, A., Yoon, K.-Y., Kwak, M.-J., Kim, S.-I., Ryu, S.-T., and Jang, J.-H.: Fully flexible, lightweight, high performance all-solid-state supercapacitor based on 3-Dimensional-graphene/graphite-paper. J. Power Sources 337, 159 (2017).CrossRefGoogle Scholar
He, W., Sun, Y., Xi, J., Abdurhman, A.A.M., Ren, J., and Duan, H.: Printing graphene-carbon nanotube-ionic liquid gel on graphene paper: Towards flexible electrodes with efficient loading of PtAu alloy nanoparticles for electrochemical sensing of blood glucose. Anal. Chim. Acta. 903, 61 (2016).CrossRefGoogle ScholarPubMed
Liu, L., Ye, D., Yu, Y., Liu, L., and Wu, Y.: Carbon-based flexible micro-supercapacitor fabrication via mask-free ambient micro-plasma-jet etching. Carbon N. Y 111, 121 (2017).CrossRefGoogle Scholar
Han, Y. and Dai, L.: Conducting polymers for flexible supercapacitors. Macromol. Chem. Phys. 220, 1800355 (2019).CrossRefGoogle Scholar
Dutta, S., Pal, S., and De, S.: Mixed solvent exfoliated transition metal oxides nanosheets based flexible solid state supercapacitor devices endowed with high energy density. New J. Chem. 43, 12385 (2019).CrossRefGoogle Scholar
Chen, F., Wan, P., Xu, H., and Sun, X.: Flexible transparent supercapacitors based on hierarchical nanocomposite films. ACS Appl. Mater. Interfaces 9, 17865 (2017).CrossRefGoogle ScholarPubMed
Wang, Q., Shao, L., Ma, Z., Xu, J., Li, Y., and Wang, C.: Hierarchical porous PANI/MIL-101 nanocomposites based solid-state flexible supercapacitor. Electrochim. Acta 281, 582 (2018).CrossRefGoogle Scholar
Jiang, H., Wang, Z., Yang, Q., Hanif, M., Wang, Z., Dong, L., and Dong, M.: A novel MnO2/Ti3C2Tx MXene nanocomposite as high performance electrode materials for flexible supercapacitors. Electrochim. Acta 290, 695 (2018).CrossRefGoogle Scholar
Yang, H., Xu, H., Li, M., Zhang, L., Huang, Y., and Hu, X.: Assembly of NiO/Ni (OH)2/PEDOT nanocomposites on contra wires for fiber-shaped flexible asymmetric supercapacitors. ACS Appl. Mater. Interfaces 8, 1774 (2016).CrossRefGoogle ScholarPubMed
Khattak, A.M., Yin, H., Ghazi, Z.A., Liang, B., Iqbal, A., Khan, N.A., Gao, Y., Li, L., and Tang, Z.: Three dimensional iron oxide/graphene aerogel hybrids as all-solid-state flexible supercapacitor electrodes. RSC Adv. 6, 58994 (2016).CrossRefGoogle Scholar
Xiao, X., Peng, X., Jin, H., Li, T., Zhang, C., Gao, B., Hu, B., Huo, K., and Zhou, J.: Freestanding mesoporous VN/CNT hybrid electrodes for flexible all-solid-state supercapacitors. Adv. Mater. 25, 5091 (2013).CrossRefGoogle ScholarPubMed
Zhu, Y.G., Wang, Y., Shi, Y., Wong, J.I., and Yang, H.Y.: CoO nanoflowers woven by CNT network for high energy density flexible micro-supercapacitor. Nano Energy 3, 46 (2014).CrossRefGoogle Scholar
Jin, Y., Chen, H., Chen, M., Liu, N., and Li, Q.: Graphene-patched CNT/MnO2 nanocomposite papers for the electrode of high-performance flexible asymmetric supercapacitors. ACS Appl. Mater. Interfaces 5, 3408 (2013).CrossRefGoogle ScholarPubMed
Chou, S.-L., Wang, J.-Z., Chew, S.-Y., Liu, H.-K., and Dou, S.-X.: Electrodeposition of MnO2 nanowires on carbon nanotube paper as free-standing, flexible electrode for supercapacitors. Electrochem. Commun. 10, 1724 (2008).CrossRefGoogle Scholar
Kang, Y.J., Kim, B., Chung, H., and Kim, W.: Fabrication and characterization of flexible and high capacitance supercapacitors based on MnO2/CNT/papers. Synth. Met. 160, 2510 (2010).CrossRefGoogle Scholar
Karthika, P., Rajalakshmi, N., and Dhathathreyan, K.S.: Flexible polyester cellulose paper supercapacitor with a gel electrolyte. ChemPhysChem. 14, 3822 (2013).CrossRefGoogle ScholarPubMed
Guo, M.-X., Bian, S.-W., Shao, F., Liu, S., and Peng, Y.-H.: Hydrothermal synthesis and electrochemical performance of MnO2/graphene/polyester composite electrode materials for flexible supercapacitors. Electrochim. Acta 209, 486 (2016).CrossRefGoogle Scholar
Shao, W., Tebyetekerwa, M., Marriam, I., Li, W., Wu, Y., Peng, S., Ramakrishna, S., Yang, S., and Zhu, M.: Polyester@MXene nanofibers-based yarn electrodes. J. Power Sources 396, 683 (2018).CrossRefGoogle Scholar
Shao, F., Bian, S., Zhu, Q., Guo, M., Liu, S., and Peng, Y.: Fabrication of polyaniline/graphene/polyester textile electrode materials for flexible supercapacitors with high capacitance and cycling stability. Chem. Asian J. 11, 1906 (2016).CrossRefGoogle ScholarPubMed
Berendjchi, A., Khajavi, R., Yousefi, A.A., and Yazdanshenas, M.E.: Improved continuity of reduced graphene oxide on polyester fabric by use of polypyrrole to achieve a highly electro-conductive and flexible substrate. Appl. Surf. Sci. 363, 264 (2016).CrossRefGoogle Scholar
Kumar, N., Ginting, R.T., Ovhal, M., and Kang, J.-W.: All-solid-state flexible supercapacitor based on spray-printed polyester/PEDOT: PSS electrodes. Mol. Cryst. Liq. Cryst. 660, 135 (2018).CrossRefGoogle Scholar
Ji, H., Zhao, R., Zhang, N., Jin, C., Lu, X., and Wang, C.: Lightweight and flexible electrospun polymer nanofiber/metal nanoparticle hybrid membrane for high-performance electromagnetic interference shielding. NPG Asia Mater. 10, 749 (2018).CrossRefGoogle Scholar
Jiang, S.X. and Guo, R.H.: Electromagnetic shielding and corrosion resistance of electroless Ni–P/Cu–Ni multilayer plated polyester fabric. Surf. Coatings Technol. 205, 4274 (2011).CrossRefGoogle Scholar
Celen, R. and Ulcay, Y.: Investigating electromagnetic shielding effectiveness of knitted fabrics made by barium titanate/polyester bicomponent yarn. J. Eng. Fiber. Fabr. 14, 1 (2019).Google Scholar
Lin, J.-H., Lin, T.A., Lin, T.R., Jhang, J.-C., and Lou, C.-W.: Processing techniques and properties of metal/polyester composite plain material: Electromagnetic shielding effectiveness and far-infrared emissivity. J. Ind. Text 49, 365 (2019).CrossRefGoogle Scholar
Xiang, Y., Li, T., Suo, Z., and Vlassak, J.J.: High ductility of a metal film adherent on a polymer substrate. Appl. Phys. Lett. 87, 161910 (2005).CrossRefGoogle Scholar
Younis, A.A.: Protection of polyester fabric from ignition by a new chemical modification method. J. Ind. Text 47, 363 (2017).CrossRefGoogle Scholar
Hirayama, T. and Urban, M.W.: Distribution of melamine in melamine/polyester coatings; FT-IR spectroscopic studies. Prog. Org. Coatings 20, 81 (1992).CrossRefGoogle Scholar
Cazacu, M., Dragan, S., and Vlad, A.: Organic–inorganic polymer hybrids and porous materials obtained on their basis. J. Appl. Polym. Sci. 88, 2060 (2003).CrossRefGoogle Scholar
Rajesh, K.M., Ajitha, B., Reddy, Y.A.K., Suneetha, Y., and Reddy, P.S.: Assisted green synthesis of copper nanoparticles using Syzygium aromaticum bud extract: Physical, optical and antimicrobial properties. Optik (Stuttg) 154, 593 (2018).CrossRefGoogle Scholar
Kamel, M.M., El Zawahry, M.M., Helmy, H., and Eid, M.A.: Improvements in the dyeability of polyester fabrics by atmospheric pressure oxygen plasma treatment. J. Text. Inst. 102, 220 (2011).CrossRefGoogle Scholar
Abou-Elela, S.I., Ibrahim, H.S., Kamel, M.M., and Gouda, M.: Application of nanometal oxides in situ in nonwoven polyester fabric for the removal of bacterial indicators of pollution from wastewater. Sci. World J., 2014 (2014).Google ScholarPubMed
Li, W., Hao, J., Mu, S., and Liu, W.: Electrochemical behavior and electrodeposition of Ni-Co alloy from choline chloride-ethylene glycol deep eutectic solvent. Appl. Surf. Sci. 507, 144889 (2020).CrossRefGoogle Scholar
Fashu, S., Gu, C.D., Zhang, J.L., Bai, W.Q., Wang, X.L., and Tu, J.P.: Electrodeposition and characterization of Zn–Sn alloy coatings from a deep eutectic solvent based on choline chloride for corrosion protection. Surf. Interface Anal. 47, 403 (2015).CrossRefGoogle Scholar
Fashu, S., Gu, C.D., Zhang, J.L., Zheng, H., Wang, X.L., and Tu, J.P.: Electrodeposition, morphology, composition, and corrosion performance of Zn-Mn coatings from a deep eutectic solvent. J. Mater. Eng. Perform 24, 434 (2015).CrossRefGoogle Scholar
Li, R., Liang, J., Hou, Y., and Chu, Q.: Enhanced corrosion performance of Zn coating by incorporating graphene oxide electrodeposited from deep eutectic solvent. RSC Adv. 5, 60698 (2015).CrossRefGoogle Scholar
Shinagawa, S., Kumagai, Y., and Urabe, K.: Conductive papers containing metallized polyester fibers for electromagnetic interference shielding. J. Porous Mater. 6, 185 (1999).CrossRefGoogle Scholar