Hostname: page-component-84b7d79bbc-g78kv Total loading time: 0 Render date: 2024-07-26T14:54:28.024Z Has data issue: false hasContentIssue false
  • English
  • Français

X-ray photoelectron spectroscopy studies of bond structure between polyvinyl alcohol and a titanate cross-coupling agent

Published online by Cambridge University Press:  03 March 2011

Mehmet A. Gülgün ,
Oludele O. Popoola  and
Waltraud M. Kriven
Mehmet A. Gülgün
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 105 S. Goodwin Avenue, Urbana, Illinois 61801
Oludele O. Popoola*
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 105 S. Goodwin Avenue, Urbana, Illinois 61801
Waltraud M. Kriven
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 105 S. Goodwin Avenue, Urbana, Illinois 61801
*
a)Present address: Material Systems Rcliability Department, Ford Research Laboratory, Dearborn, Michigan 48121.
Get access

Abstract

Chemical interactions between polyvinyl alcohol (PVA) and triethanol amine titanate chelate were studied using x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The titanate chelate cross coupled the PVA solution and produced a viscous gel. The gel had a three-dimensional network structure containing -CPVA-O-Ti-O-CPVA- organic complexes. A new C(ls) signature at 285.7 eV and an O(ls) signature at 531.25 eV were associated with the formation of these complexes. The water of the PVA solution was physically retained in the gelled structure and was readily available for chemical reactions. The removal of this entrapped water was irreversible and led to a collapsed film of Ti-cross-linked PVA.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 6 , June 1995 , pp. 1565 - 1571
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Birchall, J. D., Howard, A. J., and Kendall, K., Nature (London) 289, 388 (1981).CrossRefGoogle Scholar
2Kendall, K., Birchall, J. D., and Howard, A. J., Philos. Trans. R. Soc. London A310, 139 (1983).Google Scholar
3Popoola, O. O., Kriven, W. M., and Young, J. F., in Proc. Xllth Int. Congress for Electron Microscopy, edited by Peachey, L. D. and Williams, D.B. (Seattle, WA, 1990), Vol. 4, pp. 1068–1069.Google Scholar
4Popoola, O. O., Kriven, W. M., and Young, J. F., Ultramicroscopy 37, 318 (1991).CrossRefGoogle Scholar
5Desai, R. A., Thesis, M. S., University of Illinois at Urbana-Champaign, Urbana, IL (1990).Google Scholar
6Popoola, O. O., Kriven, W. M., and Young, J. F., J. Am. Ceram. Soc. 74(8), 1928 (1991).CrossRefGoogle Scholar
7Boyer, M. A., Thesis, M. S., University of Illinois at Urbana-Champaign, Urbana, IL (1993).Google Scholar
8Popoola, O. O. and Kriven, W. M., J. Mater. Res. 7, 1545 (1992).CrossRefGoogle Scholar
9“Tyzor, Organic Titanates”, Product Literature by DuPont, E.I.du Pont de Nemours & Co., Wilmington, DE.Google Scholar
10Gulgun, M. A., Popoola, O. O., and Kriven, W.M., J. Am. Ceram. Soc. 77(2), 531 (1994).CrossRefGoogle Scholar
11Gulgun, M. A., Popoola, O. O., Nettleship, I., Kriven, W. M., and Young, J. F., in Advanced Cementitious Systems: Mechanisms and Properties, edited by Glasser, F. P., McCarthy, G. J., Young, J. F., Mason, T. O., and Pratt, P. L. (Mater. Res. Soc. Symp. Proc. 245, Pittsburgh, PA, 1992), pp. 199–204.Google Scholar
12Akther, S., Allan, K., Buchanan, D., Cook, J. A., Campion, A., and White, J.M., Appl. Surf. Sci. 35, 241 (1988–89).Google Scholar
13Akther, S., Zhou, X-L., and White, J. M., Appl. Surf. Sci. 37, 201 (1989).Google Scholar
14Clark, D. T. and Thomas, H. R., J. Polmer Sci.: Polymer Chem. Ed. 14, 1701 (1976).Google Scholar
15Idriss, H., Kim, K. S., and Barteau, M. A., Surf. Sci. 262, 113 (1992).CrossRefGoogle Scholar
16Murata, M., Wakino, K., and Ikeda, S., J. Electr. Spec. Rel. Phenom. 6, 459 (1975).CrossRefGoogle Scholar
17Badyal, J. P. S., Chambers, R. D., and Chvatal, Z., J. Fluorine Chem. 57, 159 (1992).CrossRefGoogle Scholar
18Clark, D. T. and Thomas, H. R., J. Polym. Sci.: Polymer Chem. Ed. 14, 1671 (1976).Google Scholar
19Clark, D. T. and Dilks, A., J. Polym. Sci.: Polymer Chem. Ed. 14, 533 (1976).Google Scholar
20Clark, D. T., Dilks, A., and Thomas, H. R., J. Polym. Sci.: Polymer Chem. Ed. 16, 1461 (1978).Google Scholar
21Burkstrand, J. M., J. Appl. Phys. 52(7), 4795 (1981).CrossRefGoogle Scholar
22Greenlief, C. M. and White, J. M., J. Phys. Chem. 89, 5025 (1985).CrossRefGoogle Scholar
23Porta, G. M., Rancourt, J. D., and Taylor, L. T., Chem. Mater. 3(3), 423 (1991).CrossRefGoogle Scholar
24Saha, N. C. and Tompkins, H. G., J. Appl. Phys. 72(7), 3072 (1992).CrossRefGoogle Scholar
25Werfel, F. and Brummer, O., Phys. Scripta 28, 92 (1983).CrossRefGoogle Scholar
26Jerome, R., Teyssie, Ph., Pireaux, J. J., Verbist, J. J., Appl. Surf. Sci. 27, 93 (1986).CrossRefGoogle Scholar
27Tolman, C. A., Riggs, W. M., Linn, W. J., King, C. M., and Wendt, R. C., Inorg. Chem. 12, 2770 (1973).CrossRefGoogle Scholar
28Zeller, M. V. and Hayes, R. G., Chem. Phys. Lett. 10(5), 610 (1971).CrossRefGoogle Scholar
29Briggs, D. and Kendall, C. R., Int. J. Adhesion and Adhesives 2(1), 13 (1982).CrossRefGoogle Scholar
30Asensio, M. C., Kerkar, M., Woodruff, D. P., de Carvalho, A.V., Fernandez, A., Gonzales-Elipe, A. R., Fernandez-Garcia, M., and Conesa, J. C., Surf. Sci. 273, 31 (1992).CrossRefGoogle Scholar
31Rao, C. N. R., Sarma, D. D., Vasudevan, S., and Hegde, M. S., Proc. R. Soc. London A367, 239 (1979).Google Scholar
32Zhao, L. Z., Liu, S. H., Wang, D. H., and Pan, C. H., J. Electr. Spec. Rel. Phenom. 52, 571 (1990).CrossRefGoogle Scholar
33Johansson, L. I., Hagstrom, A. L., Jacobson, B. E., and Hagstrom, S. B. M., J. Electr. Spec. Rel. Phenom. 10, 259 (1977).CrossRefGoogle Scholar
34Hagstrom, A. L., Johansson, L. I., Jacobsson, B. E., and Hagstrom, S. B. M., Solid State Commun. 19, 647 (1976).CrossRefGoogle Scholar
35Popoola, O. O., Denanot, M. F., Moine, P., Cahoreau, M., and Caisso, J., Acta Metall. 37(3), 867 (1989).CrossRefGoogle Scholar
36Porte, L., Demonsthenous, M., and Due, T. M., J. Less-Comm. Met. (in French) 56, 183 (1977).CrossRefGoogle Scholar
37Porte, L., Demonsthenous, M., Hollinger, G., Jugnet, Y., Pertosa, P., and Due, T. M., Proc. 7th Int. Vac. Congr. & 3rd Int. Conf. Solid Surfaces (Vienna, 1977), p. 923.Google Scholar