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Synthesis of nanoscale spherical TiB2 particles in Al matrix by regulating Sc contents

Published online by Cambridge University Press:  30 January 2019

Jing Sun Open the ORCID record for Jing Sun [Opens in a new window] ,
Xuqin Wang ,
Lijie Guo ,
Xiaobo Zhang  and
Haowei Wang
Jing Sun*
Affiliation:
Research and Development Department, Shanghai Aerospace Equipment Manufacturer Limited Company, Shanghai 200245, China; and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
Xuqin Wang
Affiliation:
Research and Development Department, Shanghai Aerospace Equipment Manufacturer Limited Company, Shanghai 200245, China
Lijie Guo
Affiliation:
Research and Development Department, Shanghai Aerospace Equipment Manufacturer Limited Company, Shanghai 200245, China
Xiaobo Zhang
Affiliation:
State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
Haowei Wang
Affiliation:
State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
*
a)Address all correspondence to this author. e-mail: 15216615475@163.com
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Abstract

In situ TiB2 particles with polyhedral or near-spherical morphology with more high-index crystal planes exposed were prepared by controlling the addition amount of Sc in commercial pure aluminum matrix. As the content of Sc increased, TiB2 morphology transformed from hexagonal platelets to polyhedral or near-spherical morphology with a decrease in particle size. In the present paper, a simple method to prepare near-spherical in situ TiB2 particles in Al matrix was explored and it was found that the reinforcement distribution was improved significantly. The different growth mechanism of TiB2 particles in Al and Al–Sc systems was discussed. The key reason for the morphology evolution was that the Sc was preferentially adsorbed on ${\bf \left\{ {1{\bf \overline{2}}12} \right\}}$, ${\bf \left\{ {11\overline{2}0} \right\}}$, and ${\bf \left\{ {10\overline{1}1} \right\}}$ which would inhibit the growth of these faces effectively and retain a lower-energy state of the polyhedral or quasispherical TiB2 particles in Al–Sc systems.

Keywords

Scadsorptioncomposite
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 7: Focus Section: Interconnects and Interfaces in Energy Conversion Materials , 15 April 2019 , pp. 1258 - 1265
Copyright
Copyright © Materials Research Society 2019 

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References

Han, Y., Liu, X., and Bian, X.: In situ TiB2 particulate reinforced near eutectic Al–Si alloy composites. Composites, Part A 33, 439 (2002).CrossRefGoogle Scholar
Wang, F., Ma, N., Li, Y., Li, X., and Wang, H.: Impact behavior of in situ TiB2/Al composite at various temperatures. J. Mater. Sci. 46, 5192 (2011).CrossRefGoogle Scholar
Guo, Q., Sun, D.L., Jiang, L.T., Wu, G.H., and Chen, G.Q.: Residual microstructure and damage geometry associated with high speed impact crater in Al2O3 and TiB2 particles reinforced 2024 Al composite. Mater. Charact. 66, 9 (2012).CrossRefGoogle Scholar
Li, P., Wu, Y., and Liu, X.: Controlled synthesis of different morphologies of TiB2 microcrystals by aluminum melt reaction method. Mater. Res. Bull. 48, 2044 (2013).CrossRefGoogle Scholar
Ding, H., Liu, X., and Nie, J.: Study of preparation of TiB2 by TiC in Al melts. Mater. Charact. 63, 56 (2012).CrossRefGoogle Scholar
Lü, L., Lai, M.O., Su, Y., Teo, H.L., and Feng, C.F.: In situ TiB2 reinforced Al alloy composites. Scr. Mater. 45, 1017 (2001).CrossRefGoogle Scholar
Wang, Z., Xie, B., Zhou, W., Shi, G., and Wu, Z.: Thermophysical properties of TiB2–SiC ceramics from 300 °C to 1700 °C. Int. J. Refract. Met. Hard Mater. 41, 609 (2013).CrossRefGoogle Scholar
Uddin, S.M., Mahmud, T., Wolf, C., Glanz, C., Kolaric, I., Volkmer, C., Höller, H., Wienecke, U., Roth, S., and Fecht, H-J.: Effect of size and shape of metal particles to improve hardness and electrical properties of carbon nanotube reinforced copper and copper alloy composites. Compos. Sci. Technol. 70, 2253 (2010).CrossRefGoogle Scholar
El-Kady, O. and Fathy, A.: Effect of SiC particle size on the physical and mechanical properties of extruded Al matrix nanocomposites. Mater. Des. 54, 348 (2014).CrossRefGoogle Scholar
Deng, K.K., Wang, X.J., Wu, Y.W., Hu, X.S., Wu, K., and Gan, W.M.: Effect of particle size on microstructure and mechanical properties of SiCp/AZ91 magnesium matrix composite. Mater. Sci. Eng., A 543, 158 (2012).CrossRefGoogle Scholar
Li, Z., Chen, D., Wang, H., Lavernia, E.J., and Shan, A.: Nano-TiB2 reinforced ultrafine-grained pure Al produced by flux-assisted synthesis and asymmetrical rolling. J. Mater. Res. 29, 2514 (2014).CrossRefGoogle Scholar
Cha, L., Lartigue-Korinek, S., Walls, M., and Mazerolles, L.: Interface structure and chemistry in a novel steel-based composite Fe–TiB2 obtained by eutectic solidification. Acta Mater. 60, 6382 (2012).CrossRefGoogle Scholar
Wang, Y.H., Lin, J.P., He, Y.H., Wang, Y.L., and Chen, G.L.: Microstructural characteristics of Ti–45Al–8.5Nb/TiB2 composites by powder metallurgy. J. Alloys Compd. 468, 505 (2009).CrossRefGoogle Scholar
Wang, Y.H., Lin, J.P., He, Y.H., Wang, Y.L., and Chen, G.L.: Microstructures and mechanical properties of Ti–45Al–8.5Nb–(W,B,Y) alloy by SPS–HIP route. Mater. Sci. Eng., A 489, 55 (2008).CrossRefGoogle Scholar
Guo, M., Shen, K., and Wang, M.: Relationship between microstructure, properties and reaction conditions for Cu–TiB2 alloys prepared by in situ reaction. Acta Mater. 57, 4568 (2009).CrossRefGoogle Scholar
Sun, W., Xiang, H., Dai, F-Z., Liu, J., and Zhou, Y.: Anisotropic surface stability of TiB2: A theoretical explanation for the easy grain coarsening. J. Mater. Res. 32, 2755 (2017).CrossRefGoogle Scholar
Sun, J., Zhang, X., Zhang, Y., Ma, N., and Wang, H.: Effect of alloy elements on the morphology transformation of TiB2 particles in Al matrix. Micron 70, 21 (2015).CrossRefGoogle ScholarPubMed
Cao, Y., Fan, J., Bai, L., Hu, P., Yang, G., Yuan, F., and Chen, Y.: Formation of cubic Cu mesocrystals by a solvothermal reaction. CrystEngComm 12, 3894 (2010).CrossRefGoogle Scholar
Zasada, F., Piskorz, W., Cristol, S., Paul, J-F., Kotarba, A., and Sojka, Z.: Periodic density functional theory and atomistic thermodynamic studies of cobalt spinel nanocrystals in wet environment: Molecular interpretation of water adsorption equilibria. J. Phys. Chem. C 114, 22245 (2010).CrossRefGoogle Scholar
Zeng, J., Zheng, Y., Rycenga, M., Tao, J., Li, Z-Y., Zhang, Q., Zhu, Y., and Xia, Y.: Controlling the shapes of silver nanocrystals with different capping agents. J. Am. Chem. Soc. 132, 8552 (2010).CrossRefGoogle ScholarPubMed
Ma, Y., Zeng, J., Li, W., McKiernan, M., Xie, Z., and Xia, Y.: Seed-mediated synthesis of truncated gold decahedrons with a AuCl/oleylamine complex as precursor. Adv. Mater. 22, 1930 (2010).CrossRefGoogle ScholarPubMed
Wang, L.B., Song, L.X., Dang, Z., Chen, J., Yang, J., and Zeng, J.: Controlled growth and magnetic properties of α-Fe2O3 nanocrystals: Octahedra, cuboctahedra, and truncated cubes. CrystEngComm 14, 3355 (2012).CrossRefGoogle Scholar
Yang, S., Xu, Y., Sun, Y., Zhang, G., and Gao, D.: Size-controlled synthesis, magnetic property, and photocatalytic property of uniform α-Fe2O3 nanoparticles via a facile additive-free hydrothermal route. CrystEngComm 14, 7915 (2012).CrossRefGoogle Scholar
Gao, X., Li, X., Gao, W., Qiu, J., Gan, X., Wang, C., and Leng, X.: Nanocrystalline/nanoporous ZnO spheres, hexapods and disks transformed from zinc fluorohydroxide, their self-assembly and patterned growth. CrystEngComm 13, 4741 (2011).CrossRefGoogle Scholar
Pengting, L., Chong, L., Jinfeng, N., Jun, O., and Xiangfa, L.: Growth and design of LaB6 microcrystals by aluminum melt reaction method. CrystEngComm 15, 411 (2013).CrossRefGoogle Scholar
Yang, Y., Jin, S., and Jiang, Q.: Effect of reactant C/Ti ratio on the stoichiometry, morphology of TiCx and mechanical properties of TiCx–Ni composite. CrystEngComm 15, 852 (2013).CrossRefGoogle Scholar
Jin, S., Shen, P., Li, Y., Zhou, D., and Jiang, Q.: Synthesis of spherical NbB2−x particles by controlling the stoichiometry. CrystEngComm 14, 1925 (2012).CrossRefGoogle Scholar
Huang, D., Yan, D., Ma, S., and Wang, X.: Scandium on the formation of in situ TiB2 particulates in an aluminum matrix. J. Mater. Res. 33, 2721 (2018).CrossRefGoogle Scholar
Gao, Q., Wu, S., Lü, S., Xiong, X., Du, R., and An, P.: Effects of ultrasonic vibration treatment on particles distribution of TiB2 particles reinforced aluminum composites. Mater. Sci. Eng., A 680, 437 (2017).CrossRefGoogle Scholar
Liu, G., Chen, K., Zhou, H., Tian, J., Pereira, C., and Ferreira, J.: Fast shape evolution of TiN microcrystals in combustion synthesis. Cryst. Growth Des. 6, 2404 (2006).CrossRefGoogle Scholar
Benson, G. and Patterson, D.: Note on an analytical proof of wulff’s theorem in three dimensions. J. Chem. Phys. 23, 670 (1955).CrossRefGoogle Scholar
Abdel-Hamid, A.A., Hamar-Thibault, S., and Hamar, R.: Crystal morphology of the compound TiB2. J. Cryst. Growth 71, 744 (1985).CrossRefGoogle Scholar
Hyman, M., McCullough, C., Levi, C., and Mehrabian, R.: Evolution of boride morphologies in TiAl–B alloys. Metall. Trans. A 22, 1647 (1991).CrossRefGoogle Scholar
Chen, M-W., Wang, X-F., Wang, F., Lin, G-B., and Wang, Z-Z.: The effect of interfacial kinetics on the morphological stability of a spherical particle. J. Cryst. Growth 362, 20 (2013).CrossRefGoogle Scholar
Chen, L., Wang, H-Y., Li, Y-J., Zha, M., and Jiang, Q-C.: Morphology and size control of octahedral and cubic primary Mg2Si in an Mg–Si system by regulating Sr contents. CrystEngComm 16, 448 (2014).CrossRefGoogle Scholar
Li, N., Sakidja, R., and Ching, W-Y.: Ab initio study on the adsorption mechanism of oxygen on Cr2AlC (0001) surface. Appl. Surf. Sci. 315, 45 (2014).CrossRefGoogle Scholar