Hostname: page-component-7479d7b7d-q6k6v Total loading time: 0 Render date: 2024-07-12T08:28:34.959Z Has data issue: false hasContentIssue false

Stress and thermal expansion of β–SiC films by the vibrating-membrane method

Published online by Cambridge University Press:  31 January 2011

B.S. Berry
Affiliation:
IBM Research Division, T.J. Watson Research Center, P.O. Box 218, Yorktown Heights, New York 10598
W.C. Pritchet
Affiliation:
IBM Research Division, T.J. Watson Research Center, P.O. Box 218, Yorktown Heights, New York 10598
R.I. Fuentes
Affiliation:
IBM Research Division, T.J. Watson Research Center, P.O. Box 218, Yorktown Heights, New York 10598
I. Babich
Affiliation:
IBM Research Division, T.J. Watson Research Center, P.O. Box 218, Yorktown Heights, New York 10598
Get access

Abstract

The internal tensile stress in heteroepitaxial films of cubic (β) SiC grown on Si substrates by chemical vapor deposition at 1520–1650 K has been determined from the resonant frequencies of membrane samples formed by removal of a central circular region of the substrate. At 293 K, the stress falls in the range 250–500 MPa, and tends to be larger for samples grown at higher temperatures. The temperature dependence of the stress has been studied over the range 90–670 K and found to exhibit a reversible, mild, but convoluted variation that includes a minimum near 160 K and a maximum near 400 K. Analysis of this behavior reveals that the thermal expansion of β–SiC is remarkably close to that of Si, with an expansion curve that intersects that of Si near 80 K and 500 K. This behavior is different from that obtained from available handbook data for α–SiC, and suggests that data for α–SiC should not be relied on to estimate the overall magnitude of the thermal stress component in β–SiC films. Annealing studies carried out in the range 673–1473 K on as-prepared membranes indicate a high degree of membrane stability, with no evidence of stress relaxation. It has also been observed that annealed membranes may exhibit very low levels of mechanical damping, corresponding to Q-values in the range 106−107.

Type
Articles
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 For a recent collection of papers, see Amorphous and Crystalline Silicon Carbide II: Recent Developments, edited by Rahman, M. M., Yang, C. Y-W., and Harris, G. L. (Springer-Verlag, Berlin, 1989), Vol. 43 of the Springer Proceedings in Physics.CrossRefGoogle Scholar
2Davis, R. F., Sitar, Z., Williams, B. E., Kong, H. S., Kim, H. J., Palmour, J. W., Edmond, J. A., Ryu, J., Glass, J. T., and Carter, C. H., Jr., Mater. Sci. Eng. B1, 77 (1988).CrossRefGoogle Scholar
3Warlaumont, J., J. Vac. Sci. Technol. B7, 1634 (1989).CrossRefGoogle Scholar
4DiCarlo, J. A. and Williams, W., Ceramic and Engineering Science Proceedings 1, 671 (1980).Google Scholar
5Berry, B. S., Pritchet, W. C., and Uzoh, C. E., J. Vac. Sci. Technol. B7, 1565 (1989).CrossRefGoogle Scholar
6Berry, B. S. and Pritchet, W. C., J. Appl. Phys. 67, 3668 (1990).CrossRefGoogle Scholar
7McLachlan, N. W., The Theory of Vibrations (Dover, New York, 1945), Chap. 8.Google Scholar
8Berry, B. S., in Diffusion Phenomena in Thin Films and Microelectronic Materials, edited by Gupta, D. and Ho, P. S. (Noyes, Park Ridge, NJ, 1988), Chap. 2.Google Scholar
9Touloukian, Y. S., Kirby, R. K., Taylor, R. E., and Lee, T. Y. R., Thermal Expansion of Nonmetallic Solids, Vol. 13 of the TPRC Data Series: Thermophysical Properties of Matter (IFI/Plenum, New York, 1977).CrossRefGoogle Scholar
10Windischmann, H., SPIE Vol. 1263 Electron-Beam, X-ray, and Ion-Beam Technology: Submicrometer Lithographies IX (1990), p. 241.Google Scholar
11Berry, B. S., Pritchet, W. C., Cuomo, J. J., Guarnieri, C. R., and Whitehair, S. J., Appl. Phys. Lett. 57, 302 (1990).CrossRefGoogle Scholar