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Preparation and characterization of poly(tetramethyl-p-phenylenediamine)/clay hybrids via intercalative polymerization

Published online by Cambridge University Press:  31 January 2011

Guangming Chen ,
Nobuo Iyi  and
Taketoshi Fujita
Guangming Chen
Affiliation:
State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China, and Advanced Materials Laboratory (AML), National Institute for Materials Science (NIMS), 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan
Nobuo Iyi
Affiliation:
Advanced Materials Laboratory (AML), National Institute for Materials Science (NIMS), 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan
Taketoshi Fujita
Affiliation:
Advanced Materials Laboratory (AML), National Institute for Materials Science (NIMS), 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan
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Abstract

New noncovalent bonding polymer/clay hybrids were prepared, including the polymer poly(tetramethyl-p-phenylenediamine) (poly-TMPD). Polymerization occurred in the interlayer space of clay mineral successively after intercalation of monomers. Two types of clay minerals with different surface properties—a hydrophilic lithium fluorotaeniolite (TN) and four kinds of organophilic fluorotaeniolites (org-TNs)—were used as the hosts. Powder x-ray diffraction results showed an increase of 0.7–1.0 nm in the basal spacings, indicating the formation of poly–TMPD in the interlayer space of the hosts. Intercalative polymerization was also supported by Fourier transform infrared spectroscopy. The orientation of the poly-TMPD and thermal behavior were also discussed.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 2 , February 2003 , pp. 482 - 486
Copyright
Copyright © Materials Research Society 2003

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