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Effect of the species of substituted ion on ferroelastic domain switching of rare-earth ion-doped ZrO2 pseudo-single crystals

Published online by Cambridge University Press:  26 July 2012

Takanori Kiguchi
Affiliation:
Department of Inorganic Materials, Faculty of Engineering, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152, Japan
Atsushi Saiki
Affiliation:
Department of Inorganic Materials, Faculty of Engineering, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152, Japan
Kazuo Shinozaki
Affiliation:
Department of Inorganic Materials, Faculty of Engineering, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152, Japan
Nobuyasu Mizutani
Affiliation:
Department of Inorganic Materials, Faculty of Engineering, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152, Japan
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Extract

The difference of domain switching amount of 3 mol% R2O3−ZrO2 (R = Yb, Y, Dy, Gd, Eu, Sm) pseudo-single crystals with additive cation species was investigated from the microstructural aspect. The switching amount of Yb, Y, Dy, and Gd substituted ZrO2 was three times higher than that of Eu and Sm. The amount corresponded to the volume fraction of the t′-phase, and it indicated that phase separation proceeded, especially in Eu and Sm substituted ZrO2.

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Articles
Copyright
Copyright © Materials Research Society 1999

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Effect of the species of substituted ion on ferroelastic domain switching of rare-earth ion-doped ZrO2 pseudo-single crystals
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