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Controls on ore metal ratios in granite-related ore systems: an experimental and computational approach

Published online by Cambridge University Press:  03 November 2011

Philip A. Candela
Philip A. Candela
Affiliation:
Philip A. Candela, Laboratory for Mineral Deposit Research, Department of Geology,University of Maryland, College Park, Maryland, 20742-4211, U.S.A
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Abstract

Size and composition (bulk metal ratios) of magmatic hydrothermal mineral deposits are affected by a number of chemical and physical processes including the nature of the source region and mode of emplacement. At shallow levels, rising plumes of vapour bubbles + melt, and the advection of water through interconnected vapour bubbles, allows access of the magmatic aqueous phase to the upper reaches of a magma chamber. These processes are operative at shallow levels where low water solubility and high molar volume for water make these processes more efficient.

Partitioning experiments suggest that oxygen fugacity-dependent crystal/melt partitioning of ore metals leads to different efficiencies of removal of Cu, W, and Mo from silicate melts into ore-forming aqueous fluids. For example, the Mo/W ratio in magmatic hydrothermal deposits should increase as the oxygen fugacity of the magma increases. Further, Cu should behave as a crystal-compatible element in H2O-undersaturated, sulfide-saturated felsic magmas with fO2 NNO + 1 due to the strong partitioning of Cu from the melt into pyrrhotite.

Cycling of oxidised, hydrated, sulfidised and Cl-enriched oceanic crust into mantle can give rise to magmas that contain S but are oxidised (≥NNO). The combination of high oxidation state, relatively hydrous but shallow conditions and a high Cl/H2O ratio leads to saturation with respect to H2O early during crystallisation, and loss of a large proportion of magmatic Cu to the aqueous phase. Ores formed from these oxidised magmas also possess high Mo/W ratios due to the effect of oxygen fugacity on the sequestering of Mo vs W.

In less oxidised magmas, Cu and Mo are partitioned into sulfides and Ti-bearing phases, respectively, resulting in lower efficiencies of removal of Cu and Mo from melts into aqueous fluids. Further, the partitioning of W into crystallising phases is reduced, producing a more efficient removal of W into ore-forming fluids. This ultimately leads to mineral deposits with higher W/(Mo + Cu) ratios relative to deposits associated with more oxidised systems. Silicic, high-F magmas with fO2 = NNO can be found in tensional environments (e.g. rocks associated with the Climax-type deposits of the Colorado Mineral Belt). High HF/H2O activity ratios in the source regions yield melts that evolve an aqueous phase late during crystallisation, leading to relatively low ratios of compatible/incompatible elements in the melt at H2O saturation.

Keywords

magmatic-hydrothermal processesore metalsgranites
Type
Research Article
Information
Earth and Environmental Science Transactions of The Royal Society of Edinburgh , Volume 83 , Issue 1-2: Second Hutton Symposium: The Origin of Granites and Related Rocks , 1992 , pp. 317 - 326
Copyright
Copyright © Royal Society of Edinburgh 1992

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