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Assessing threats to shallow groundwater quality from soil pollutants in Glasgow, UK: development of a new screening tool

Published online by Cambridge University Press:  19 November 2018

F. M. Fordyce*
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK. Email: fmf@bgs.ac.uk
B. É. Ó Dochartaigh
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK. Email: fmf@bgs.ac.uk
H. C. Bonsor
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK. Email: fmf@bgs.ac.uk
E. L. Ander
Affiliation:
British Geological Survey, Environmental Science Centre, Keyworth, Nottingham NG12 5GG, UK.
M. T. Graham
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK. Email: fmf@bgs.ac.uk
R. McCuaig
Affiliation:
School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK.
M. Lovatt
Affiliation:
Department of Civil and Environmental Engineering, University of Strathclyde, 50 Richmond Street, Glasgow G1 1XN, UK.
*
*Corresponding author

Abstract

A new GIS-based screening tool to assess threats to shallow groundwater quality has been trialled in Glasgow, UK. The GRoundwater And Soil Pollutants (GRASP) tool is based on a British Standard method for assessing the threat from potential leaching of metal pollutants in unsaturated soil/superficial materials to shallow groundwater, using data on soil and Quaternary deposit properties, climate and depth to groundwater. GRASP breaks new ground by also incorporating a new Glasgow-wide soil chemistry dataset. GRASP considers eight metals, including chromium, lead and nickel at 1622 soil sample locations. The final output is a map to aid urban management, which highlights areas where shallow groundwater quality may be at risk from current and future surface pollutants. The tool indicated that 13% of soil sample sites in Glasgow present a very high potential threat to groundwater quality, due largely to shallow groundwater depths and high soil metal concentrations. Initial attempts to validate GRASP revealed partial spatial coincidence between the GRASP threat ranks (low, moderate, high and very high) and groundwater chemistry, with statistical correlation between areas of high soil and groundwater metal concentrations for both Cr and Cu (r2>0.152; P<0.05). Validation was hampered by a lack of, and inconsistency in, existing groundwater chemistry data. To address this, standardised subsurface data collection networks have been trialled recently in Glasgow. It is recommended that, once available, new groundwater depth and chemistry information from these networks is used to validate the GRASP model further.

Type
Articles
Copyright
Copyright © British Geological Survey UKRI 2018 

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References

5. References

Aller, L., Bennett, T., Lehr, J. H. & Petty, R. J. 1985. DRASTIC: a standardized system for evaluating groundwater pollution potential using hydrogeological settings. US-EPA Document EPA/600/2-85/018. Washington: US Environmental Protection Agency.Google Scholar
Ball, D., MacDonald, A. M., Ó Dochartaigh, B. É., Del Rio, M., Fitzsimons, V., Auton, C. & Lilly, A. 2004. Development of a groundwater vulnerability screening methodology for the Water Framework Directive. Final Project Report WFD28. Edinburgh: SNIFFER. http://www.envirobase.info/PDF/SNIFFER_WFD28.pdfGoogle Scholar
Bewley, R. 2007. Treatment of chromium contamination and chromium ore processing residue. Technical Bulletin 14. London: CL:AIRE. http://www.claire.co.uk/Google Scholar
BGS. 2012. Assessing subsurface knowledge – ASK Network. Nottingham: British Geological Survey. http://www.bgs.ac.uk/research/engineeringGeology/urbanGeoscience/Clyde/askNetwork/home.html (accessed January 2016).Google Scholar
Blume, H. P. & Brummer, G. 1991. Prediction of heavy metal behaviour in soil by means of simple field tests. Ecotoxicology and Environmental Safety 22, 164174.Google Scholar
Bonsor, H. C., Bricker, S. H., Ó Dochartaigh, B. É. & Lawrie, K. I. G. 2010. Groundwater monitoring in urban areas: pilot investigation in Glasgow, UK, 20102011. Internal Report, IR/10/087. Edinburgh: British Geological Survey. http://nora.nerc.ac.uk/15773/.Google Scholar
Boorman, D. B., Hollis, J. M. & Lilly, A. 1995. Hydrology of soil types: a hydrologically-based classification of the soils of the United Kingdom. Report no.126. Wallingford: Institute of Hydrology. http://nora.nerc.ac.uk/7369/.Google Scholar
BS-ISO. 2004. Soil quality – characterisation of soil related to groundwater protection. Report BS ISO 15175:2004, London: British Standards – International Standards Organisation.Google Scholar
Butler, D. & Parkinson, J. 1997. Towards sustainable urban drainage. Water Science and Technology 35, 5363.Google Scholar
Campbell, S. D. G., Merritt, J. E., Ó Dochartaigh, B. É., Mansour, M., Hughes, A. G., Fordyce, F. M., Entwisle, D. C., Monaghan, A. A. & Loughlin, S. 2010. 3D geological models and hydrogeological applications: supporting urban development – a case study in Glasgow – Clyde, UK. Zeitschrift der Deutschen Gesellschaft fur Geowissenschaften 161, 251262.Google Scholar
Carey, M. & Thursten, N. 2014. Evidence: new groundwater vulnerability mapping methodology. Report SC040016. Bristol: Environment Agency.Google Scholar
CEC. 1998. Water Quality Framework. EU Directive 98/83/EC. Brussels: Commission of the European Community.Google Scholar
COST. 2016. COST Sub-Urban Action – a network to improve understanding and use of the ground beneath our cities. European Cooperation in Science and Technology. http://www.cost.eu/COST_Actions/tud/TU1206 (accessed January 2016).Google Scholar
Dearden, R. A., Marchant, A. & Royse, K. 2013. Development of a suitability map for infiltration sustainable drainage systems. Environmental Earth Sciences 70, 25872602.Google Scholar
Dearden, R. A. & Price, S. J. 2012. A proposed decision-making framework for a national infiltration SuDS map. Management of Environmental Quality 23, 478485.Google Scholar
Eaton, T. T. & Zaporozec, A. 1997. Evaluation of groundwater vulnerability in an urbanizing area. In Chilton, J., Hiscock, K., Younger, P., Morris, B., Puri, S., Nash, H., Aldous, P., Tellam, J., Kimblin, R. & Hennings, S. (eds) Groundwater in the urban environment: problems, processes and management, 577582. Rotterdam: A. A. Balkema.Google Scholar
Environment Agency, Golders Associates. 1999. ConSim Software: contamination impacts on groundwater – simulation by Monte-Carlo Method. Nottingham: Golders Associates (UK) Ltd.Google Scholar
Environmental Protection Act Part IIa. 1990. Contaminated land. London: HSMO.Google Scholar
Evanko, C. R. & Dzombak, D. A. 1997. Remediation of metals contaminated soils and groundwater. Technical Report TE-97-01. Pittsburgh: Groundwater Remediation Technologies Analysis Centre.Google Scholar
Farmer, J. G., Thomas, R. P., Graham, M. C., Geelhoed, J. S., Lumsdon, D. G. & Paterson, E. 2002. Chromium speciation and fractionation in ground and surface waters in the vicinity of chromite ore processing residue disposal sites. Journal of Environmental Monitoring 4, 235243.Google Scholar
Fordyce, F. M., Brown, S. E., Ander, E. L., Rawlins, B. G., O'Donnell, K. E., Lister, T. R., Breward, N. & Johnson, C. C. 2005. GSUE: urban geochemical mapping in Great Britain. Geochemical Exploration and Environment A 5, 325336.Google Scholar
Fordyce, F. M., Nice, S. E., Lister, T. R., Ó Dochartaigh, B. É., Cooper, R., Allen, M., Ingham, M., Gowing, C., Vickers, B. P. & Scheib, A. 2012. Urban soil geochemistry of Glasgow. Open Report, OR/08/002. Edinburgh: British Geological Survey. http://nora.nerc.ac.uk/18009/.Google Scholar
Fordyce, F. M., Bonsor, H. C. & Ó Dochartaigh, B. É. 2013. Developments to GRASP 2012/13. GRASP: a GIS tool to assess pollutant threats to shallow groundwater in the Glasgow area. Internal Report, IR/13/024. Edinburgh: British Geological Survey.Google Scholar
Fordyce, F. M., Everett, P. A., Bearcock, J. M. & Lister, T. R. 2018. Soil metal/metalloid concentrations in the Clyde Basin, Scotland, UK: implications for land quality. Earth and Environmental Science Transactions of the Royal Society of Edinburgh. DOI: 10.1017/S1755691018000282.Google Scholar
Fordyce, F. M. & Ander, E. L. 2003. Urban Soils Geochemistry and GIS-aided Interpretation – A Case Study from Stoke-on-Trent. British Geological Survey Research Report IR/01/35/R. Nottingham: British Geological Survey. http://nora.nerc.ac.uk/7018/.Google Scholar
Fordyce, F. M. & Ó Dochartaigh, B. É. 2011. Developments to GRASP 2009/10. GRASP: a GIS tool to assess pollutant threats to shallow groundwater in the Glasgow area. Internal Report, IR/10/034. Edinburgh: British Geological Survey.Google Scholar
Graham, M. T., Ó Dochartaigh, B. É., Fordyce, F. M. & Ander, E. L. 2008. Preliminary GRoundwater-quality Assessment from Soil Pollutants (GRASP) tool for Glasgow. Internal Report IR/08/057. Edinburgh: British Geological Survey.Google Scholar
Grunsky, E. C. 2010. The interpretation of geochemical survey data. Geochemistry, Exploration, Environment Analysis 10, 2774.Google Scholar
Hall, I. H. S., Browne, M. A. E. & Forsyth, I. H. 1998. Geology of Glasgow District. British Geological Survey Memoir for 1:50 000 Geological Sheet 30E (Scotland). London: HMSO.Google Scholar
Howard, K. W. F. (ed.) 2008. Urban groundwater – meeting the challenge. Abingdon, Oxford: Taylor Francis.Google Scholar
Johnson, C. C., Demetriades, A., Locutura, J. & Ottesen, R. T. (eds) 2011. Mapping the chemical environment of urban areas. London: John Wiley & Sons.Google Scholar
Lerner, D. (ed.) 2003. Urban groundwater pollution: IAH International Contributions to Hydrogeology 24. Abingdon, Oxford: Taylor Francis.Google Scholar
Lovatt, M. J. 2008. Assessing the Importance of Depth to Groundwater in a Methodology for Prioritising Threats to Groundwater Quality from Surface Contaminants in the Clyde Gateway. Unpublished MSc Thesis, University of Strathclyde, UK.Google Scholar
Luo, X.-S., Yu, S., Zhu, Y.-G. & Li, X.-D. 2012. Trace metal contamination in urban soils of China. Science of the Total Environment 421–422, 1730.Google Scholar
MacDonald, N. & Jones, P. 2006. The inclusion of sustainable drainage systems in flood management in the post-industrial city: a case study of Glasgow. Scottish Geographical Journal 122, 233246.Google Scholar
McBride, M. B. 1994. Environmental chemistry of soils. Oxford: Oxford University Press.Google Scholar
McBride, M. B., Richards, B. K., Steenhuis, T. & Spiers, G. 1999. Long-term leaching of trace elements in a heavily sludge amended silly clay loam soil. Soil Science 164, 613623.Google Scholar
McCuaig, R. 2011. Validation of a GIS-based tool for prioritising threats to shallow groundwater quality from soil pollutants in Glasgow. Unpublished MSc Thesis, Birmingham University, UK.Google Scholar
McGrath, S. P. & Loveland, P. J. 1992. Soil geochemical atlas of England and Wales. Glasgow: Blackie Academic and Professional.Google Scholar
McKinley, J. M., Hron, K., Grunsky, E. C., Reimann, C., de Caritat, P., Filzmoser, P. & Tolosana-Delgado, R. 2016. The single component geochemical map: fact or fiction? Journal of Geochemical Exploration 162, 1628.Google Scholar
McLaren, R. G., Clucas, L. M. & Taylor, M. D. 2005. Leaching of macronutrients and metals from undisturbed soils treated with metal-spiked sewage sludge. 3. Distribution of residual metals. Australian Journal of Soil Research 43, 159170.Google Scholar
Merrington, G. & Alloway, B. J. 1994. The flux of Cd, Cu, Pb and Zn in mining polluted soils. Water, Air and Soil Pollution 73, 333344.Google Scholar
Meteorological Office. 2013. Meteorological Office Rainfall and Evaporation Calculation System (MORECS). http://www.metoffice.gov.uk/ (accessed April 2013).Google Scholar
Ó Dochartaigh, B. É., Ball, D. F., MacDonald, A. M., Lilly, A., Fitzsimons, V., Del Rio, M. & Auton, C. A. 2005. Mapping groundwater vulnerability in Scotland: a new approach for the water framework directive. Scottish Journal of Geology 41, 2130.Google Scholar
Ó Dochartaigh, B. É., Graham, M. T. & MacDonald, A. M. 2007. A summary of groundwater work within the Clyde Basin Project, 20052006. Internal Report, IR/07/042. Edinburgh: British Geological Survey.Google Scholar
Ó Dochartaigh, B. É., Fordyce, F. M. & Bonsor, H. C. 2009. Developments to GRASP 2008/09. GRASP: a GIS tool to assess pollutant threats to shallow groundwater in the Glasgow area. Internal Report, IR/09/026. Edinburgh: British Geological Survey.Google Scholar
Ó Dochartaigh, B. É., Bonsor, H. C. & Bricker, S. H. 2012. Project progress report 2011–12: groundwater monitoring in urban areas – a pilot study in Glasgow, UK. Internal Report, IR/12/027. Edinburgh: British Geological Survey.Google Scholar
Ó Dochartaigh, B. É., Bonsor, H. C. & Bricker, S. H. 2018. Improving understanding of shallow urban groundwater: the Quaternary groundwater system in Glasgow, UK. Earth and Environmental Science Transactions of the Royal Society of Edinburgh. DOI: 10.1017/S1755691018000385.Google Scholar
Palmer, R. C. & Lewis, M. A. 1998. Assessment of groundwater vulnerability in England and Wales. In Robins, N. S. (ed.) Groundwater pollution, aquifer recharge and vulnerability, 130, 191198. London: Geological Society.Google Scholar
Paterson, E. 2011. Geochemical atlas for Scottish top soils. Aberdeen: Macaulay Land Use Research Institute.Google Scholar
Robins, N. S., MacDonald, A. M. & Allen, D. J. 2007. The vulnerability paradox for hard fractured Lower Palaeozoic and Precambrian rocks. In Witkowski, A. J. & Vrba, J. (eds) Selected papers from the Groundwater Vulnerability Assessment and Mapping International Conference, Ustron, Poland, 2004, 1319. London: Taylor & Francis.Google Scholar
Rowell, D. L. 1994. Soil science: methods and applications. London: Longman Scientific and Technical.Google Scholar
SEPA. 2005. Drainage assessment – a guide for Scotland. Stirling: Scottish Environment Protection Agency.Google Scholar
Spijker, J., Groenenberg, J. E. & Comans, R. N. J. 2014. Evaluation of metals leaching from soils to groundwater using a geochemical modelling approach. In Oral Presentation Abstracts of the 30th International Conference of the Society for Environmental Geochemistry and Health, 30 June–3 July 2014, Newcastle University, UK, 1718.Google Scholar
Sposito, G. 1989. The chemistry of soils. New York: Oxford University Press.Google Scholar
Tait, N. G., Davison, R. M., Whittaker, J. J., Leharne, S. A. & Lerner, D. N. 2004. Borehole Optimisation System (BOS) – a GIS based risk analysis tool for optimizing the use of urban groundwater. Environmental Modelling and Software 19, 11111124.Google Scholar
Thomas, A. & Tellam, J. H. 2006. Modelling of recharge and pollutant fluxes to urban groundwaters. Science of the Total Environment 360, 158179.Google Scholar
US-EPA. 1996. Soil screening guidance: user's guide. EPA/540/R-96/018. Washington: US Environmental Protection Agency.Google Scholar
Whalley, C., Hursthouse, A., Rowlatt, S., Iqbal-Zahid, P., Vaughan, H. & Durant, R. 1999. Chromium speciation in natural waters draining contaminated land, Glasgow, UK. Water Air and Soil Pollution 112, 389405.Google Scholar
Wilcke, W., Müller, S., Kanchanakool, N. & Zech, W. 1998. Urban soil contamination in Bangkok: heavy metal and aluminium partitioning in topsoils. Geoderma 86, 211228.Google Scholar
Woods-Ballard, B., Kellagher, R., Martin, P., Jeffries, C., Bray, R. & Shaffer, P. 2007. The SuDS manual. C697. London: CIRIA.Google Scholar
Wuana, R. A. & Okieimen, F. E. 2011. Heavy metals in contaminated soils: a review of sources, chemistry, risks and best available strategies for remediation. International Scholarly Research Notices Ecology 2011, 120.Google Scholar