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ART. 201 - On the Densities of the Principal Gases

Published online by Cambridge University Press:  05 July 2011

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Summary

In former communications I have described the arrangements by which I determined the ratio of densities of oxygen and hydrogen (15·882). For the purpose of that work it was not necessary to know with precision the actual volume of gas weighed, nor even the pressure at which the containing vessel was filled. But I was desirous, before leaving the subject, of ascertaining not merely the relative, but also the absolute, densities of the more important gases, that is, of comparing their weights with that of an equal volume of water. To effect this it was necessary to weigh the globe, used to contain the gases, when charged with water, an operation not quite so simple as at first sight it appears. And, further, in the corresponding work upon the gases, a precise absolute specification is required of the temperature and pressure at which a filling takes place. To render the former weighings available for this purpose, it would be necessary to determine the errors of the barometers then employed. There would, perhaps, be no great difficulty in doing this; but I was of opinion that it would be an improvement to use a manometer in direct connexion with the globe, without the intervention of the atmosphere. In the latter manner of working, there is a doubt as to the time required for full establishment of equilibrium of pressure, especially when the passages through the taps are partially obstructed by grease.

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Scientific Papers , pp. 39 - 53
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1903

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