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17 - Morphological instability in solid films

Published online by Cambridge University Press:  10 February 2010

Rashmi C. Desai
Affiliation:
University of Toronto
Raymond Kapral
Affiliation:
University of Toronto
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Summary

The growth of thin solid semiconductor films is at the heart of the development of modern electronic and optical devices. A key element in strategies for nanoscale fabrication is the exploitation of growth and kinetic instabilities to form surface nanostructures and patterns with desirable functionality.

Epitaxy is a term that is commonly used for the growth of a thin solid layer on top of a substrate. Homoepitaxy denotes the growth of crystals of a material on a crystal face of the same material, while the term heteroepitaxy is used if the materials of the substrate and the growing film are different. Molecular beam epitaxy (MBE) is a common experimental technique that is used to grow such solid films. A film that grows without defects is called a coherently grown film. In such a film the constituent atoms arrange themselves on top of the substrate as its natural extension. The film has the same crystal structure as the substrate.

In the epitaxial growth of a crystal film on another crystal, elasticity plays a dominant role and leads to long-range effective interactions between the adatoms on the surface. These interactions are repulsive and compete with the stronger shortrange chemical interactions. The repulsive nature of the long-range interactions can be qualitatively understood as follows. Consider a planar solid surface of a semiinfinite crystal. When an adatom is placed on this surface, its interaction with the atoms in the top layer creates a stress which changes the distance between its nearest neighbors in the top atomic layer of the surface.

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Publisher: Cambridge University Press
Print publication year: 2009

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