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Model Compound Approach for Polymer-Metal InterFaces: ESCA Studies

Published online by Cambridge University Press:  22 February 2011

P. N. Sanda
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
J. W. Bartha
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
B. D. Silverman
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
P. S. Ho
Affiliation:
IBM Thomas J. Watson Research Center Yorktown Heights, New York 10598
A. R. Rossi
Affiliation:
Department of Chemistry University of Connecticut Storrs, Connecticut 06268
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Abstract

ESCA studies of two molecules which are similar in structure to the PMDA and ODA constituents of the PMDA-ODA polyimide monomer are discussed. Their interaction with in-situ evaporated Cr and Cu films are compared. The PMDA model compound interacts with Cr through the imide group, while very little interaction is observed with Cu. The ODA model compound (oxydianiline) interacts with Cr via the ether linkage and the terminal amino groups, whereas very little interaction is observed with Cu.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

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References

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