Hostname: page-component-76fb5796d-zzh7m Total loading time: 0 Render date: 2024-04-25T16:42:18.739Z Has data issue: false hasContentIssue false

Analysis on data storage area of NiO-ReRAM with secondary electron image

Published online by Cambridge University Press:  14 January 2011

K. Kinoshita*
Affiliation:
Department of Information and Electronics, Graduate School of Engineering, Tottori University, Tottori 680-8552, Japan; and Tottori University Electronic Display Research Center, Tottori 680-0941, Japan
T. Makino
Affiliation:
Department of Information and Electronics, Graduate School of Engineering, Tottori University, Tottori 680-8552, Japan
T. Yoda
Affiliation:
Department of Information and Electronics, Graduate School of Engineering, Tottori University, Tottori 680-8552, Japan
K. Dobashi
Affiliation:
Department of Information and Electronics, Graduate School of Engineering, Tottori University, Tottori 680-8552, Japan
S. Kishida
Affiliation:
Department of Information and Electronics, Graduate School of Engineering, Tottori University, Tottori 680-8552, Japan; and Tottori University Electronic Display Research Center, Tottori 680-0941, Japan
*
a)Address all correspondence to this author. e-mail: Kinoshita@ele.tottori-u.ac.jp
Get access

Abstract

Both low and high resistance states (which were written by voltage application in a local region of NiO/Pt films using conducting atomic force microscopy [C-AFM]) were observed with scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The writing regions are distinguishable as dark areas in a secondary electron image and thus can be specified without using a complicated sample fabrication process to narrow down the writing regions such as the photolithography technique. In addition, the writing regions were analyzed using energy-dispersive x-ray spectroscopy (EDS) mapping. No difference between the inside and outside of the writing regions is observed for all the mapped elements including C and Rh. Here, C and Rh are the most probable candidates for contamination that affect the secondary electron image. Therefore, our results suggested that the observed change in the contrast of the secondary electron image is related to the intrinsic change in the electronic state of the NiO film and a secondary electron yield is correlated to the physical properties of the film.

Type
Articles
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Baek, I.G., Lee, M.S., Seo, S., Lee, M.J., Seo, D.H., Suh, D-S., Park, J.C., Park, S.O., Kim, H.S., Yoo, I.K., Chung, U-In, and Moon, J.T.: Highly scalable non-volatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses. Electron Devices Meeting, IEDM Technical Digest (San Francisco, CA, 2004), p. 587.Google Scholar
2.Kim, K.M., Choi, B.J., and Hwang, C.S.: Localized switching mechanism in resistive switching of atomic-layer-deposited TiO2 thin films. Appl. Phys. Lett. 90, 242906 (2007).Google Scholar
3.Kinoshita, K., Tamura, T., Aoki, M., Sugiyama, Y., and Tanaka, H.: Lowering the switching current of resistance random-access memory using a hetero junction structure consisting of transition metal oxides. Jpn. J. Appl. Phys. 45, L991 (2006).Google Scholar
4.Gibbons, J.F. and Beadle, W.E.: Switching properties of thin NiO films. Solid-State Electron. 7, 785 (1964).Google Scholar
5.Lee, M-J., Han, S., Jeon, S.H., Park, B.H., Kang, S., Ahn, S-E., Kim, K.H., Lee, C.B., Kim, C.J., Yoo, I-K., Seo, D.H., Li, X-S., Park, J-B., Lee, J-H., and Park, Y.: Electrical manipulation of nanofilaments in transition-metal oxides for resistance-based memory. Nano Lett. 9, 1476 (2009).Google Scholar
6.Shima, H., Takano, F., Muramatsu, H., Yamazaki, M., Akinaga, H., and Kogure, A.: Local chemical state change in Co–O resistance random-access memory. Phys. Status Solidi 2, 99 (2008) (RRL).Google Scholar
7.Yoshida, C., Kinoshita, K., Yamasaki, T., and Sugiyama, Y.: Direct observation of oxygen movement during resistance switching in NiO/Pt film. Appl. Phys. Lett. 93, 042106 (2008).Google Scholar
8.Kinoshita, K., Okutani, T., Tanaka, H., Hinoki, T., Yazawa, K., Ohmi, K., and Kishida, S.: Opposite bias polarity dependence of resistive switching in n-type Ga-doped ZnO and p-type NiO thin films. Appl. Phys. Lett. 96, 143506 (2010).Google Scholar
9.Hsu, J., Lai, H., Lin, H., Chuang, C., and Huang, J.: Fabrication of nickel oxide nanostructures by atomic force microscope nano-oxidation and wet etching. J. Vac. Sci. Technol. B 21, 2599 (2003).Google Scholar
10.Hilleret, N., Scheuerlein, C., and Taborelli, M.: The secondary-electron yield of air-exposed metal surfaces. Appl. Phys., A Mater. Sci. Process. 76, 1085 (2003).Google Scholar
11.Nian, Y.B., Strozier, J., Wu, N.J., Chen, X., and Ignatiev, A.: Evidence for an oxygen diffusion model for the electric pulse induced resistance change effect in transition-metal oxides. Phys. Rev. Lett. 98, 146403 (2007).Google Scholar
12.Kinoshita, K., Tamura, T., Aoki, M., Sugiyama, Y., and Tanaka, H.: Bias polarity dependent data retention of resistive random-access memory consisting of binary transition metal oxide. Appl. Phys. Lett. 89, 103509 (2006).Google Scholar
13.Inoue, I.H., Yasuda, S., Akinaga, H., and Takagi, H.: Nonpolar resistance switching of metal/binary-transition-metal oxides/metal sandwiches: Homogeneous/inhomogeneous transition of current distribution. Phys. Rev. B 77, 035105 (2008).Google Scholar
14.Kudo, M., Sakai, Y., and Ichinokawa, T.: Dependencies of secondary electron yields on work function for metals by electron and ion bombardment. Appl. Phys. Lett. 76, 3475 (2000).Google Scholar