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This paper describes two aspects of research aimed at harnessing the triplet energy generated in electron-hole recombination in polymer electroluminescent devices. The purpose is to design solution-processible phosphorescent organometallic triplet emitters and to design high triplet energy polymer hosts that can transfer triplet energy to the phosphorescent guests. The method employed Suzuki cross coupling reactions to incorporate either phosphorescent cores or high energy triplet monomers covalently into polymer hosts to evaluate their optoelectronic properties. The results showed (i) efficient energy transfer from polyfluorene hosts to red phosphorescent guests and (ii) that pyridine and carbazole monomers could raise triplet energies of hosts. It is concluded that these approaches offer promise in the design of solution processible electrophosphorescent materials for red and green light emitting devices.
Commission 5 has been very active during the IAU XXVI General Assembly in Prague: the Commission, its Working Groups and its Task Force held business meetings. In addition, Commission 5 sponsored two Special Sessions: Special Session 3 on The Virtual Observatory in Action: New Science, New Technology, and Next Generation Facilities which was held for three days 17–22 August, and Special Session 6 on Astronomical Data Management, which was held on 22 August. Commission 5 also participated in the organisation of Joint Discussion 16 on Nomenclature, Precession and New Models in Fundamental Astronomy, which was held 22-23 August. The General Assembly and Commission 5 web sites provides links to detailed information about all these meetings.
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