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Influence of pH on Detoxication of Herbicides in Soil

Published online by Cambridge University Press:  12 June 2017

F. T. Corbin  and
R. P. Upchurch
F. T. Corbin
Affiliation:
North Carolina State University
R. P. Upchurch
Affiliation:
North Carolina State University Agricultural Division, Monsanto Co., St. Louis, Mo.
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Abstract

The influence of pH and incubation time on the detoxication of 11 herbicides incorporated into high organic matter soils was investigated. Five of the chemicals were detoxified at different rates at the various pH levels. Optimum pH levels for the detoxication of these chemicals were (a) pH 5.3 for 2-methoxy-3,6-dichlorobenzoic acid (dicamba) and 2,4-dichlorophenoxyacetic acid (2,4-D), (b) 6.5 for 2,2-dichloropropionic acid (dalapon) and 3-amino-1,2,4-triazole (amitrole), and (c) pH 7.5 for S-propyl dipropylthiocarbamate (vernolate).

Slow positive detoxication, without pH influence, was observed for 3-(3,4-dichlorophenyl)-1,1-dimethylurea (diuron) and 3-amino-2,5-dichlorobenzoic acid (amiben). No detectable detoxication was observed for 4-amino-2,5,6-trichloropicolinic acid (picloram), α,α,α-tri-fluoro-2,6-dinitro-N,N-dipropyl-p-toluidine (trifluralin), 5-bromo-3-isopropyl-6-methyluracil (isocil), or 2-methoxy-4,6-bis(isopropylamino)-s-triazine (prometone).

Type
Research Article
Information
Weeds , Volume 15 , Issue 4 , October 1967 , pp. 370 - 377
Copyright
Copyright © 1967 Weed Science Society of America 

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References

Literature Cited

1. Akamine, E. K. 1951. Persistence of 2,4-D toxicity in Hawaiian soils. Bot. Gaz. 112:312–319.CrossRefGoogle Scholar
2. Alexander, M. and Aleem, M. I. H. 1961. Effect of chemical structure on microbial decomposition of aromatic herbicides. J. Agr. Food Chem. 9:44–47.CrossRefGoogle Scholar
3. Audus, L. J. 1964. Herbicide behavior in the soil, pp. 163–206. In Audus, L. J. (ed.) The Physiology and Biochemistry of Herbicides. Academic Press, New York.Google Scholar
4. Bollen, W. B. 1961. Interaction between pesticides and soil microorganisms, pp. 69–92. In Clifton, C. E., Sidney, R., and Starr, M. P. (ed.) Annual Review of Microbiology, vol. 15. Annual Reviews, Inc., Palo Alto, California.Google Scholar
5. Bondarenko, D. D. 1958. Decomposition of amitrole in soil. Proc. NCWCC. 15:5–6. (Abstr.) Google Scholar
6. Burschel, P. and Freed, V. H. 1959. The decomposition of herbicides in soils. Weeds 2:157–161.CrossRefGoogle Scholar
7. Castelfranco, P. and Bisalputra, T. 1965. The inhibitory effect of amitrole on Scenedesmus quadricauda . Amer. J. Bot. 52:22–27.CrossRefGoogle ScholarPubMed
8. Day, B. E., Jordan, L. S., and Russell, R. C. 1962. Persistence of dalapon residues in California soils. Soil Sci. 95:326–330.CrossRefGoogle Scholar
9. Ercegovich, C. D. and Frear, D. E. H. 1964. The fate of 3-amino-1,2,4-triazole in soils. J. Agr. Food Chem. 12:26.CrossRefGoogle Scholar
10. Erickson, L. C. and Gault, H. S. 1950. The duration and effect of 2,4-D toxicity to crops grown on calcareous soils under controlled irrigation conditions. Agron. J. 42:226–229.CrossRefGoogle Scholar
11. Hanks, R. W. 1946. Removal of 2,4-dichlorophenoxyacetic acid and its calcium salt from six different soils by leaching. Bot. Gaz. 108:186–191.CrossRefGoogle Scholar
12. Hartley, G. S. 1964. Herbicide behavior in the soil, pp. 111–161. In Audus, L. J. (ed.) The Physiology and Biochemistry of Herbicides. Academic Press, New York.Google Scholar
13. Hilton, J. L. 1960. Effect of histidine on the inhibitory action of 3-amino-1,2,4-triazole. Weeds 8:392–396.CrossRefGoogle Scholar
14. Hilton, J. L. and Kearney, P. C. 1965. Amitrole interference with adenine-214C metabolism by Saccharomyces cerevisiae . Weeds 13:22–25.CrossRefGoogle Scholar
15. Holly, K. 1962. Herbicides acting through the soil—a review. Proc. Brit. Weed Control Conf. 6:467–477.Google Scholar
16. Holstun, J. T. and Loomis, W. E. 1956. Leaching and decomposition of 2,2-dichloropropionic acid in several Iowa soils. Weeds 4:205–217.CrossRefGoogle Scholar
17. Katznelson, H. and Stevenson, I. L. 1956. Observations on the metabolic activity of the soil microflora. Can. J. Microbiol. 2:611–622.CrossRefGoogle ScholarPubMed
18. Kaufman, D. D. 1964. Microbial degradation of 2,2-dichloropropionic acid in five soils. Can. J. Microbiol. 10:843–852.CrossRefGoogle ScholarPubMed
19. Kearney, P. C., Harris, C. I., Kaufman, D. D., and Sheets, T. J. 1965. Behavior and fate of chlorinated aliphatic acid in soils, pp. 1–30. In Metcalf, R. L. (ed.) Advances in Pest Control Research. Interscience Publishers, New York.Google Scholar
20. Klingman, G. C. 1963. Weed Control: As a Science. Second Printing. John Wiley and Sons, Inc., New York. 421 p.Google Scholar
21. Kries, O. H. 1947. Persistence of 2,4-dichlorophenoxyacetic acid in soil in relation to content of water, organic matter and lime. Bot. Gaz. 108:510–525.CrossRefGoogle Scholar
22. Newman, A. S. 1958. Herbicides and the soil. J. Agr. Food Chem. 6:352–353.Google Scholar
23. Sheets, T. J. 1966. Problems in the persistence of herbicides in plants and soils. Proc. Brit. Weed Control Conf. 9:842–851.Google Scholar
24. Upchurch, R. P. 1964. The behavior of herbicides in soil. Proc. Brit. Weed Control Conf. 7:1011–1018.Google Scholar
25. Upchurch, R. P. and Mason, D. D. 1962. The influence of soil organic matter on the phytotoxicity of herbicides. Weeds 10:9–14.CrossRefGoogle Scholar
26. Wolf, F. T. 1962. Growth inhibition of chlorella induced by 3-amino-1, 2,4-triazole and its reversal by purines. Nature 193:901–902.CrossRefGoogle ScholarPubMed