Hostname: page-component-77c89778f8-vpsfw Total loading time: 0 Render date: 2024-07-21T06:30:23.933Z Has data issue: false hasContentIssue false
  • English
  • Français

The Fate of Long Chain Esters of 2,4-D in Plants

Published online by Cambridge University Press:  12 June 2017

D. James Morré  and
B. J. Rogers
D. James Morré
Affiliation:
Department of Botany and Plant Pathology, Purdue University
B. J. Rogers
Affiliation:
Department of Botany and Plant Pathology, Purdue University
Get access

Extract

Esters of the chlorophenoxyacetic acids are generally considered to be more phy to toxic than the acid or acid salts. Hence the esters have found wide use in herbicidal formulations. Much research has been done on the mode of action of plant growth regulators, but the fate of neutral derivatives of active acids has received little attention, even though an acid side chain is one of the molecular requirements for growth substance activity.

Type
Research Article
Information
Weeds , Volume 8 , Issue 3 , July 1960 , pp. 436 - 447
Copyright
Copyright © 1960 Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Ammon, R., and Jaarma, M. Enzymes hydrolyzing fats and esters, in The Enzymes, Chemistry and Mechanism of Action, 1:Part 1, 390–442 (Sumner, E. J. B., and Myrback, K., Eds., Academic Press, New York, 724 pp.) 1950.Google Scholar
2. Brecher, A. S., and Balls, A. K. The catalysis of the non-chymotryptic hydrolysis of p-nitrophenyl acetate. J. Biol. Chem. 227:845–851. 1957.CrossRefGoogle ScholarPubMed
3. Carpenter, K., and Walker, R. D. The relative toxicities to plants of aminesalt and ester formulations of 2:4-dichlorophenoxyacetic acid. J. Sci. Food Agr. 3:476–481. 1952.Google Scholar
4. Crafts, A. S. Herbicides—their absorption and translocation. J. Agr. Food Chem. 1:51–55. 1953.Google Scholar
5. Crafts, A. S. Translocation of herbicides. I. The mechanism of translocation: methods of study with C14-labeled 2,4-D. Hilgardia 26:287–334. 1956.Google Scholar
6. Crafts, A. S. The physiology of weed control. Proc. NCWCC 6:9–14. 1949.Google Scholar
7. Day, B. E. The absorption and translocation of 2,4-dichlorophenoxyacetic acid by bean plants. Plant Physiol. 27:143–152. 1952.Google Scholar
8. Gornell, A. G., Bardawill, C. J., and David, M. M. Determination of serum proteins by means of the biruet reaction. J. Biol. Chem. 177:751–766. 1949.Google Scholar
9. Hagen, C. E., Clagett, C. O., and Helgeson, F. A. 2,4-dichlorophenoxy acetic acid inhibition of castor bean lipase. Science 110:116–117. 1949.Google Scholar
10. Hauser, E. W. Penetration of 2,4-D compounds. Research Report, NCWCC 9:157. 1952.Google Scholar
11. Huggins, C., and Lapides, J. Chromogenic substrates. IV. Acyl esters of p-nitrophenol as substrates for the colorimetric determination of esterase. J. Biol. Chem. 170:467–482. 1947.CrossRefGoogle Scholar
12. Kelly, J. A. Commercial herbicides. Present methods of formulation. J. Agr. Food Chem. 1:254–257. 1953.CrossRefGoogle Scholar
13. Koepfli, J. G., Thimann, K. V., and Went, F. W. Phytohormones: structure and physiological activity. I. J. Biol. Chem. 122:763–780. 1938.Google Scholar
14. Leonard, O. A. Studies on the absorption and translocation of 2,4-D in bean plants. Hilgardia 28:115–160. 1958.Google Scholar
15. Linder, P. J., Brown, J. W., and Mitchell, J. W. Movement of externally applied phenoxy compounds in bean plants in relation to conditions favoring carbohydrate translocation. Bot. Gaz. 110:628–632. 1949.Google Scholar
16. Lineweaver, H., and Burk, D. The determination of enzyme dissociation constants. J. Am. Chem. Soc. 56:658–666. 1934.Google Scholar
17. Mehler, A. H. Introduction to Enzymology. (Academic Press, New York, 425 pp.) 1957.Google Scholar
18. Morré, D. J., and Rogers, B. J. Studies concerning the fate of long-chain esters of 2,4-D in plants. Proc. North Central Weed Control Conf. 15:3. (Abstract) 1958.Google Scholar
19. Morré, D. J., and Rogers, B. J. Differential uptake of 2,4-D acid and the octyl ester by plants. Plant Physiol. 34:324–325. 1960.Google Scholar
20. Robbins, W. W., Crafts, A. S., and Raynor, R. N. Weed Control (McGraw-Hill Book Co., New York. 188–198) 1952.Google Scholar
21. Sobotka, H., and Kahn, J. Determination of solubility of sparingly soluble liquids in water. J. Am. Chem. Soc. 53:2935–2938. 1931.Google Scholar
22. Thimann, K. V. The synthetic auxins: relation between structure and activity, Plant Growth Substances (Skoog, F., Ed., University of Wisconsin Press, Madison, Wisc., 476 pp.) 1951.Google Scholar
23. Weinstein, S. S., and Wynne, A. M. Studies on pancreatic lipase. II. Influence of various compounds on the hydrolytic activity. J. Biol. Chem. 112:649–660. 1936.Google Scholar