Hostname: page-component-76fb5796d-r6qrq Total loading time: 0 Render date: 2024-04-26T20:33:50.484Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and spectral investigations of Mn(II) ions doped NaCaAlPO4F3 phosphor

Published online by Cambridge University Press:  06 January 2014

V. Pushpa Manjari ,
Ch. Rama Krishna ,
Sk. Muntaz Begum  and
R.V.S.S.N. Ravikumar
V. Pushpa Manjari
Affiliation:
Department of Physics, University College of Sciences, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
Ch. Rama Krishna
Affiliation:
Department of Physics, University College of Sciences, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
Sk. Muntaz Begum
Affiliation:
Department of Physics, University College of Sciences, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
R.V.S.S.N. Ravikumar*
Affiliation:
Department of Physics, University College of Sciences, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
*
ae-mail: rvssn@yahoo.co.in
Get access

Abstract

Mn(II) ions doped NaCaAlPO4F3 phosphor was synthesized by using solid state reaction method. The prepared sample was characterized by various spectroscopic techniques such as powder XRD, SEM with EDS, Optical absorption, electron paramagnetic resonance (EPR) and photoluminescence. From powder XRD, the average crystallite size was calculated about 46 nm. SEM images showed the irregular shaped entities present in the sample. Optical absorption spectrum gave the absorption bands in UV-VIS region which are the characteristic of Mn(II) ions in octahedral symmetry. The room temperature EPR spectrum exhibited a six weak hyperfine splitting lines centered at g = 2.0. Photoluminescence spectrum showed the emission peaks in visible region, from yellow to red with an excitation wavelength of 465 nm. From the emission spectral data, the CIE chromaticity coordinates were also calculated as (x = 0.661, y = 0.338).

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 65 , Issue 1 , January 2014 , 10403
Copyright
© EDP Sciences, 2014

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Narukawa, Y., Ichikawa, M., Sanga, D., Sano, M., Mukai, T., J. Phys. D 43, 354002 (2010)CrossRef
Schubert, E.F., Kim, J.K., Luo, H., Xi, J.Q., Rep. Prog. Phys. 69, 3069 (2006)CrossRef
Ettis, H., Naїli, H., Mhiri, T., Cryst. Growth Des. 3, 599 (2003)CrossRef
Parreu, I., Solé, R., Gavaldà, Jna., Díaz, J., Massons, F., Aguiló, M., Chem. Mater. 17, 822 (2005)CrossRef
Ramik, R.A., Darkosturman, B., Roberts, A.C., Dunn, P.J., Can. Mineral. 21, 499 (1983)
Pajunen, A., Lahti, S.I., Am. Mineral. 69, 961 (1984)
Shinde, K.N., Dhoble, S.J., Park, K., Nano-Micro Lett. 4, 78 (2012)CrossRef
Dhoble, S.J., Shinde, K.N., Adv. Mater. Lett. 2, 349 (2011)CrossRef
Shinde, K.N., Dhoble, S.J., Luminescence 27, 91 (2012)CrossRefPubMed
Shanshan, H., Wanjun, T., J. Lumin. 145, 100 (2014)CrossRef
Xie, M., Pan, R., J. Alloys Compd. 551, 48 (2013)CrossRef
Xie, M., Pan, R., Opt. Mater. 35, 1162 (2013)CrossRef
Zhou, J., Xia, Z., You, H., Shen, K., Yang, M., Liao, L., J. Lumin. 135, 20 (2013)CrossRef
Yu, J.Y., Zhang, X., Hao, Z.D., Luo, Y.S., Wang, X.J., Zhang, J.H., J. Alloys Compd. 515, 39 (2012)CrossRef
Xia, Z.G., Liu, R.S., Huang, K.W., Drozd, V., J. Mater. Chem. 22, 15183 (2012)CrossRef
Zhang, X.M., Zeng, H.P., Su, Q., J. Alloys Compd. 441, 259 (2007)CrossRef
Lee, D.Y., Kang, Y.C., Park, H.D., Ryu, S.K., J. Alloys Compd. 353, 252 (2003)CrossRef
Zhang, Z., Delsing, A.C.A., Notten, P.H.L., Zhao, J., Dorenbos, P., Hintzena, H.T., ECS J. Solid State Sci. Technol. 2, R70 (2013)CrossRef
Yadav, R.S., Pandey, S.K., Pandey, A.C., J. Lumin. 131, 1998 (2011)CrossRef
Xue, Y.N., Xiao, F., Zhang, Q.Y., Spectrochim. Acta A: Mol. Biomol. Spectrosc. 78, 1445 (2011)CrossRef
Qu, X.F., Cao, L.X., Liu, W., Su, G., Xu, C., Wang, P.P., J. Alloys Compd. 494, 196 (2010)CrossRef
Palumbo, D.T., Brown, J.J., J. Electrochem. Soc. 117, 1184 (1970)CrossRef
Tamatani, M., in Phosphor Handbook, edited by Yen, W.M., Shionoya, S., Yamamoto, H. (CRC, Boca Raton, 2007), p. 167Google Scholar
Berkowitz, J.K., Olsen, J.A., J. Lumin. 50, 111 (1991)CrossRef
Premkumar, H.B., Sunitha, D.V., Nagabhushana, H., Sharma, S.C., Nagabhushana, B.M., Shivakumara, C., Rao, J.L., Chakradhar, R.P.S., J. Lumin. 132, 2409 (2012)CrossRef
Singh, V., Chakradhar, R.P.S., Rao, J.L., Jho, Y.-D., Physica B 407, 2289 (2012)CrossRef
Singh, V., Chakradhar, R.P.S., Rao, J.L., Kwak, H.-Y., J. Lumin. 131, 1789 (2011)CrossRef
Singh, V., Chakradhar, R.P.S., Rao, J.L., Kim, D.-K., Physica B 403, 120 (2008)CrossRef
Gacem, L., Artemenko, A., Ouadjaout, D., Chaminade, J.P., Garcia, A., Pollet, M., Viraphong, O., Solid State Sci. 11, 1854 (2009)CrossRef
Li, G., Xu, X., Peng, C., Shang, M., Geng, D., Cheng, Z., Chen, J., Lin, J., Opt. Express 19, 16423 (2011)CrossRef
Shinde, K.N., Nagpure, I.M., Fulke, A.B., Dhoble, S.J., Luminescence 26, 363 (2012)CrossRef
Pushpamanjari, V., Ramakrishna, Ch., Venkatareddy, Ch., Muntazbegum, Sk., Reddy, Y.P., Ravikumar, R.V.S.S.N., J. Lumin. 145, 324 (2014)CrossRef
Guo, H., Wang, X., Zhang, X., Tang, Y., Chen, L., Ma, C., J. Electrochem. Soc. 157, 310 (2010)CrossRef
Oshio, S., Matsuoka, T., Tanaka, S., Kobayashi, H., J. Electrochem. Soc. 145, 3898 (1998)CrossRef
Smets, B., Rutten, J., Hoeks, G., Verlijsdonk, J., J. Electrochem. Soc. 136, 2119 (1989)CrossRef
Yan, B., Wang, C., Solid State Sci. 10, 82 (2008)CrossRef
Tanabe, Y., Sugano, S., J. Phys. Soc. Jpn 9, 753 (1954)CrossRef
Marfunin, A.S., Physics of Minerals and Inorganic Materials (Springer Verlag, Berlin, 1971), p. 217–223Google Scholar
Chandrasekhar, A.V., Venkataramanaiah, M., Reddy, B.J., Rao, P.S., Indian J. Pure Appl. Phys. 34, 193 (1996)
Griscom, D.L., J. Non-Cryst. Solids. 40, 211 (1980)CrossRef
Van Wieringen, J.S., Faraday Discuss. 19, 118 (1955)CrossRef
Tsay, F.D., Helmholz, L., J. Chem. Phys. 50, 2642 (1969)CrossRef
Chandrasekhar, A.V., Ravikumar, R.V.S.S.N., Reddy, B.J., Reddy, Y.P., Phys. Chem. Glasses 43, 173 (2002)
Yao, S.-S., Xue, L.-H., Yan, Y.-W., Li, Y.-Y., Yan, M.-F., J. Cer. Proce. Res. 11, 669 (2010)
Pires, A.M., Davolos, M.R., Chem. Mater. 13, 21 (2001)CrossRef
Penga, M., Honga, G., J. Lumin. 127, 735 (2007)CrossRef
Han, J.K., Hannah, M.E., Piquette, A., Talbot, J.B., Mishra, K.C., Kittrick, J.Mc., J. Solid State Sci. Technol. 1, R37 (2012)CrossRef
Blasse, G., Grabmaier, B.C., Luminescent Materials (Springer-Verlag, Berlin, 1994)CrossRefGoogle Scholar
Kesavulu, C.R., Muralidhara, R.S., Rao, J.L., Anavekar, R.V., Chakradhar, R.P.S., J. Alloys Compd. 486, 46 (2011)CrossRef
Jagannatha Reddy, A., Kokila, M.K., Nagabhushana, H., Rao, J.L., Nagabhushana, B.M., Shivakumara, C., Chakradhar, R.P.S., Spectrochim. Acta Part A 79, 476 (2011)CrossRef
Molla, A.R., Chakradhar, R.P.S., Kesavulu, C.R., Rao, J.L., Biswas, S.K., J. Alloys Compd. 512, 105 (2012)CrossRef
Satyanarayana, T., Valente, M.A., Nagarjuna, G., Veeraiah, N., J. Phys. Chem. Solids 74, 229 (2013)CrossRef
String Fellow, G.B., Craford, M.G. (eds., High Brightness Light Emitting Diodes, in Semiconductors and Semi Metals, vol. 48 (Academic Press, San Diego, 1997)Google Scholar
Shionoya, S., Yen, W.M., Phosphor Handbook (Phosphor Research Society, CRC Press, London, 1998), p. 459–487Google Scholar
Wang, Z., Zhang, Y., Xiong, L., Li, X., Guo, J., Gong, M., Curr. Appl. Phys. 12, 1084 (2012)CrossRef