Hostname: page-component-7479d7b7d-8zxtt Total loading time: 0 Render date: 2024-07-11T12:16:42.601Z Has data issue: false hasContentIssue false
  • English
  • Français

Structure of lead zirconium oxide: Evidence from NMR

Published online by Cambridge University Press:  15 July 1999

S. M. Korniyenko ,
I. P. Bykov ,
M. D. Glinchuk ,
V. V. Laguta  and
L. Jastrabik
S. M. Korniyenko
Affiliation:
Institute for Problems of Materials Science, NASc of Ukraine, Krjijanovskogo 3, 252180 Kiev, Ukraine
I. P. Bykov
Affiliation:
Institute for Problems of Materials Science, NASc of Ukraine, Krjijanovskogo 3, 252180 Kiev, Ukraine
M. D. Glinchuk*
Affiliation:
Institute for Problems of Materials Science, NASc of Ukraine, Krjijanovskogo 3, 252180 Kiev, Ukraine
V. V. Laguta
Affiliation:
Institute for Problems of Materials Science, NASc of Ukraine, Krjijanovskogo 3, 252180 Kiev, Ukraine
L. Jastrabik
Affiliation:
Institute of Physics, Academy of Science of the Czech Republic, Na Slovance 2, Praha 8, Czech Republic
*
glin@ipms.kiev.ua
Get access

Abstract

Two different lead ion positions with tetragonal and orthorhombic local symmetry were revealed in PbZrO3 ceramics on the base of 207Pb NMR spectra measurements at room temperature. The obtained data and their analysis on the base of the spectra shape calculations are in agreement with a symmetry of Pbam nonpolar group space of PbZrO3. The comparison of observed spectra in PbTiO3 and PbZrO3 with calculated spectra allowing for resonance frequency chemical shift and spin-spin interaction show that the displacements of lead and oxygen ions are not random quantities in the investigated PbZrO3 ceramic samples.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 7 , Issue 1 , July 1999 , pp. 13 - 17
Copyright
© EDP Sciences, 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Haun, M.J., Furman, E., Jang, S.J., Cross, L.E., Ferroelectrics 99, 13 (1989). CrossRef
E.G. Fesenko, A.Ya. Dantsiger, O.N. Razumovskaya, Novie piezokeramicheskie materiali (Rostov, 1983).
Roleder, K., Kugel, G.E., Fontana, M.D., Honderek, J., Lahlou, S., Carabatos-Nedelec, C., J. Phys. Cond. Matter 1, 2257 (1989)
Megaw, H.D., Proc. Phys. Soc. (London) 58, 133 (1946). CrossRef
Jona, F., Shirane, G., Mazzi, F., Pepinsky, R., Phys. Rev. 105, 899 (1957).
Fujishita, H., Shiozaki, Y., Achima, N., Samaguchi, E., J. Phys. Soc. Jpn 51, 3583 (1982). CrossRef
Glinchuk, M.D., Skorokhod, V.L., Bykov, I.P., Grachov, V.G., Ferroelectrics 143, 195 (1993). CrossRef
Laguta, V.V., Antimirova, T.V., Glinchuk, M.D., Bykov, I.P., Wangzong, Y., Jianrong, Z., Gaomin, L., J. Korean Phys. Soc. 32, 5700 (1998).
Dai, K., Li, J.F., Viehland, D., Phys. Rev. 51, 2651 (1995). CrossRef
Teslie, S., Egami, T., Viehland, D., Ferroelectrics 194, 271 (1997). CrossRef
A. Abragam, The Principles of Nuclear Magnetism (Clarendon, Oxford, 1961).
Irwin, A.D., Chandler, C.D., Assink, R., Hampden-Smith, M.J., Inorg. Chem 33, 1005 (1994). CrossRef
Glinchuk, M.D., Laguta, V.V., Bykov, I.P., Nokhrin, S.N., J. Appl. Phys. 81, 3561 (1997). CrossRef
Malibert, C., Dkhil, B., Kiat, J.M., Durand, D., J. Phys. Cond. Matter 9, 7485 (1997). CrossRef
Bykov, I.P., Glinchuk, M.D., Laguta, V.V., Maximenko, Y.L., Jastrabik, L., Trepakov, V.A., Dimza, V., Hrabovsky, M., J. Phys. Chem. Solids 56, 919 (1995). CrossRef
Neul, G., Dybowski, C., Matthew, M., Smith, L., Hepp, M., Perry, D.L., Solid State NMR 6, 241 (1996).
Yushin, N.K., Smirnova, E.P., Taracanov, E.A., Sommer, P., Fizika Tverdogo Tela 36, 1321 (1994).