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Conversion of carbon oxides into methane in a nonthermal plasma-catalytic reactor

Published online by Cambridge University Press:  28 October 2011

E.J. Jwa
Affiliation:
Department of Chemical and Biological Engineering, Jeju National University, Jeju, Republic of Korea
Y.S. Moks*
Affiliation:
Department of Chemical and Biological Engineering, Jeju National University, Jeju, Republic of Korea
S.B. Lee
Affiliation:
Department of Chemical and Biological Engineering, Jeju National University, Jeju, Republic of Korea
*
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Abstract

Nonthermal plasma created in a catalyst-packed bed reactor was applied to the conversion of carbon oxides (CO and CO2) into methane. The methanation was performed over a Ni/alumina catalyst with the molar ratios of H2/CO and H2/CO2 at 3.0 and 4.0, respectively. The present work focused on the effect of nickel loading (0–12.5 wt.%) on the methanation rate over the temperature range of 200–300 °C. The applied voltage for creating nonthermal plasma was 6.4–10.3 kV (operating frequency: 1 kHz). For both CO and CO2, the behavior of the methanation in the plasma-catalytic reactor greatly depended on the applied voltage, resulting in higher conversion efficiencies at higher voltages. There was optimal nickel content of 2.5–5.0 wt.% where the plasma effect on the methanation rate was maximized. It is believed that the plasma created in the catalytic reactor can change the rate-determining step by accelerating the dissociation of carbon oxides adsorbed on the catalyst surface.

Type
Research Article
Copyright
© EDP Sciences, 2011

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References

Alstrup, I., J. Catal. 151, 216 (1995)CrossRef
Yadav, R., Rinker, R.G., Can. J. Chem. Eng. 71, 202 (1993)CrossRef
Andersson, M.P., Bligaard, T., Kustov, A., Larsen, K.E., Greeley, J., Johannessen, T., Christensen, C.H., Nørskov, J.K., J. Catal. 239, 501 (2006)CrossRef
Khorsand, K., Marvast, M.A., Pooladian, N., Kakavand, M., Pet. Coal 49, 46 (2007)
Fujita, S.-I., Takezawa, N., Chem. Eng. J. 68, 63 (1997)CrossRef
Juan-Juan, J., Román-Martínez, M.C., Illán-Gómez, M.J., Appl. Catal. A: General 264, 169 (2004)CrossRef
Lee, K.Y., Kim, H.W., J. Korean Ind. Eng. Chem. 4, 365 (1993)
Pangiotopoulou, P., Knonarides, D.I., Verykios, X.E., Appl. Catal. A 344, 45 (2006)CrossRef
Nozaki, T., Tsukijihara, H., Fukui, W., Okazaki, K., Energy Fuels 21, 2525 (2007)CrossRef
Sobacchi, M.G., Saveliev, A.V., Fridman, A.A., Kennedy, L.A., Ahmed, S., Krause, T., Int. J. Hydrogen Energy 27, 635 (2002)CrossRef
Yu, S.J., Chang, M.B., Plasma Chem. Plasma Process. 21, 311 (2002)CrossRef
Cho, W., Kim, Y.C., Kim, S.S., J. Ind. Eng. Chem. 16, 20 (2010)CrossRef
Mok, Y.S., Kang, H.C., Lee, H.J., Koh, D.J., Shin, D.N., Plasma Chem. Plasma Process. 30, 437 (2010)CrossRef
Jwa, E., Mok, Y.S., Lee, S.B., Nonthermal plasma-assisted catalytic methanation of CO and CO2 over nickel-loaded alumina, in 3rd Int. Conf. on Energy and Sustainability, Alicante, Spain, 2011, pp. 361368Google Scholar
Mahmoodi, S., Ehsani, M.R., Ghoreishi, S.M., J. Ind. Eng. Chem. 16, 923 (2010)CrossRef
Seo, J.G., Youn, M.H., Chung, J.S., Song, I.K., J. Ind. Eng. Chem. 16, 795 (2010)CrossRef
Manley, T.C., Trans. Electrochem. Soc. 84, 83 (1943)CrossRef
Mok, Y.S., Kang, H.-C., Koh, D.J., Shin, D.N., Baik, J.H., J. Korean Phys. Soc. 57, 451 (2010)
Thompson, L.T. Jr., Schwank, J., Curtis, M.D., AIChE J. 35, 109 (1989)CrossRef
Sehested, J., Dahl, S., Jacobsen, J., Rostrup-Nielsen, J.R., J. Phys. Chem. B 109, 2432 (2005)CrossRef
Bradford, M.C.J., Vannice, M.A., Ind. Eng. Chem. Res. 35, 3171 (1996)CrossRef