We show that the OPAL opacities, in addition to explaining the origin of β Cep stars pulsations, also predict existence of a large region in the Main Sequence band at lower luminosities, where high-order g-modes of low harmonic degrees, l, are unstable. The excitation mechanism remains the same and is due to the usual κ-effect acting in the metal opacity bump (T ≈ 2 × 105K). The new instability domain nearly bridges the gap in spectral types between δ Set and β Cep stars. Periods of unstable modes are in the range 0.4–3.5 days for l = 1 and l = 2. We propose that this excitation mechanism causes photometric variability in the Slowly Pulsating B-type stars (SPB stars, Waelkens 1991) and perhaps in other B stars whose variability in the same period range has been reported.