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Electron Microscopic Studies of Some Lunar Minerals

Published online by Cambridge University Press:  07 February 2017

P. E. Champness
Affiliation:
Dept. of Geology, University of Manchester, England
G. W. Lorimer
Affiliation:
Dept. of Metallurgy, University of Manchester, England

Abstract

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Ion-thinned samples of rock 12052 have been examined in the electron microscope at 100 kV. This rock contains numerous phenocrysts of pyroxene, Ca1 – P (Mg, Fe)1 + P Si2O6, and a few rounded olivine crystals (Mg, Fe)2 SiO4 set in a finer-grained groundmass of pyroxene, plagioclase (Na, Ca) (Al, Si)4O8, ilmenite, FeTiO3 and other minor minerals (Champness et al., 1971). The cores of the pyroxene phenocrysts consist of a calcium-poor pyroxene, pigeonite, with an epitaxially grown rim of a calcium-rich pyroxene, augite. Both the pigeonite and augite are zoned, and indication of non-equilibrium crystallisation (Bence et al., 1970).

The outer parts of the pigeonite cores of the phenocrysts show very finescale composition modulations on (001) (major) and (100) (minor) (Figure 1). This texture is interpreted as exsolution by a spinodal mechanism (Cahn, 1968).

The augite rim of the phenocryst exhibits a coarse exsolution of pigeonite on (001) on which is superimposed fine-scale composition modulations on (001) and (100) (Figure 2).

The two-stage exsolution process indicates that the cooling rate of the pyroxene increased suddenly, possibly when the magma was extruded on the Moon's surface.

Antiphase domains produced during the polymorphic transition from space group C2/c to P21/c have been found in all primary and precipitated pigeonites (Figure 3). This confirms Morimoto and Tokonami's (1969) suggestion that all clino-pyroxenes have the C2/c space group at high temperatures.

Cristobalite, a high-temperature polymorph of silica, occurs as very small grains in the groundmass. It contains numerous microtwins on {100} planes produced during the β→α polymorphic transition which occurs at 268°C (Figure 4a). Diffraction patterns show extensive diffuse streaks in various directions (Figure 4b) which correspond to intersections of planes in reciprocal space with the Ewald Sphere. These diffuse planes originate from the cooperative thermal vibration of Si-O chains parallel to {100} and {111}.

Type
Part II: Scientific Papers
Copyright
Copyright © Reidel 1972 

References

Bence, A. E., Papike, J. J., and Prewitt, C. T.: 1970, Earth Planetary Sci. Letters 8, 393.CrossRefGoogle Scholar
Cahn, J. W.: 1968, Trans. AIME 242, 166.Google Scholar
Champness, P. E., Dunham, A. C., Gibb, F. G. F., Giles, H. N., MacKenzie, W. S., Stumpfl, E. F., and Zussman, J.: 1971, Proc. Second Lunar Sci. Conf. 1, 449.Google Scholar
Morimoto, N. and Tokonami, M.: 1969, Amer. Mineral. 54, 725.Google Scholar