We presented new observations in various wavebands of those extragalactic radio sources for which the emission of optical synchrotron light is established by polarimetric investigations (jets of M 87 and 3C 273, hot spots in the lobes of 3C 20, 3C 33 and Pictor A). In addition to optical spectral index and polarization maps, we collected flux measurements at radio, millimetre, and near-infrared frequencies. Our observations result in accurate synchrotron spectra between 109 and 1015 Hz. For some sources a detailed comparison between radio and optical polarization is possible.