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Atmospheric Fossil Fuel CO2 Measurement Using a Field Unit in a Central European City During the Winter of 2008/09

Published online by Cambridge University Press:  18 July 2016

M Molnár ,
L Haszpra ,
É Svingor ,
I Major  and
I Svetlik
M Molnár*
Affiliation:
Hertelendi Laboratory of Environmental Studies, MTA ATOMKI, Bem tér 18/c, H-4026 Debrecen, Hungary
L Haszpra
Affiliation:
Hungarian Meteorological Service, Budapest, Hungary
É Svingor
Affiliation:
Hertelendi Laboratory of Environmental Studies, MTA ATOMKI, Bem tér 18/c, H-4026 Debrecen, Hungary
I Major
Affiliation:
University of Debrecen, Debrecen, Hungary
I Svetlik
Affiliation:
Nuclear Physics Institute AS CR, Prague, Czech Republic
*
Corresponding author. Email: mmol@atomki.hu
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Abstract

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A high-precision atmospheric CO2 monitoring station was developed as a field unit. Within this, an integrating CO2 sampling system was applied to collect samples for radiocarbon measurements. One sampler was installed in the second largest city of Hungary (Debrecen station) and 2 independent 14CO2 sampling lines were installed ∼300 km from Debrecen in a rural site at Hegyhátsál station as independent background references, where high-precision atmospheric CO2 mixing ratios have been measured since 1994. Fossil fuel CO2 content in the air of the large Hungarian city of Debrecen was determined during the winter of 2008 using both the measurements of CO2 mixing ratio and 14C content of air. Fossil fuel CO2 was significantly enhanced at Debrecen relative to the clean-air site at Hegyhátsál.

Type
Methods, Applications, and Developments
Information
Radiocarbon , Volume 52 , Issue 2: 20th Int. Radiocarbon Conference Proceedings , 2010 , pp. 835 - 845
Copyright
Copyright © 2010 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Bakwin, PS, Tans, PP, Zhao, CL, Ussler, W, Quesnell, E. 1995. Measurements of carbon dioxide on a very tall tower. Tellus B 47(5):535–49.Google Scholar
Bakwin, PS, Tans, PP, Hurst, DF, Zhao, C. 1998. Measurements of carbon dioxide on very tall towers: results of the NOAA/CMDL program. Tellus B 50(5):401–5.Google Scholar
Csongor, É, Hertelendi, E. 1986. Low-level counting facility for 14C dating. Nuclear Instruments and Methods in Physics Research B 17(5–6):493–5.CrossRefGoogle Scholar
Csongor, É, Szabó, I, Hertelendi, E. 1982. Preparation of counting gas of proportional counters for radiocarbon dating. Radiochemical and Radioanalytical Letters 55:303–7.Google Scholar
de Jong, AFM, Mook, WG. 1982. An anomalous Suess effect above Europe. Nature 298(5875):641–4.CrossRefGoogle Scholar
Denning, AS, Fung, IY, Randall, D. 1995. Latitudinal gradient of atmospheric CO2 due to seasonal exchange with land biota. Nature 376(6537):240–3.Google Scholar
Gurney, KR, Law, RM, Denning, AS, Rayner, PJ, Baker, D, Bousquet, P, Bruhwiler, L, Chen, YH, Ciais, P, Fan, S, Fung, IY, Gloor, M, Heimann, M, Higuchi, K, John, J, Maki, T, Maksyutov, S, Masarie, KA, Peyli, P, Prather, M, Pak, BC, Randerson, J, Sarmiento, JL, Taguchi, S, Takahashi, T, Yuen, CW. 2002. Towards robust regional estimates of CO2 sources and sinks using atmospheric transport models. Nature 415(6872):626–30.CrossRefGoogle ScholarPubMed
Haszpra, L, Barcza, Z, Bakwin, PS, Berger, BW, Davis, KJ, Weidinger, T. 2001. Measuring system for the long-term monitoring of biosphere/atmosphere exchange of carbon dioxide. Journal of Geophysical Research 106(D3):3057–70.Google Scholar
Haszpra, L, Barcza, Z, Davis, KJ, Tarczay, K. 2005. Long-term tall tower carbon dioxide flux monitoring over an area of mixed vegetation. Agricultural and Forest Meteorology 132(1–2):58–77.Google Scholar
Haszpra, L, Barcza, Z, Hidy, D, Szilágyi, I, Dlugokencky, E, Tans, P. 2008. Trends and temporal variations of major greenhouse gases at a rural site in Central Europe. Atmospheric Environment 42(38):8707–16.Google Scholar
Hertelendi, E. 1990. Developments of methods and equipment for isotope analytical purposes and their applications [CSc thesis]. Hungarian Academy of Sciences. In Hungarian.Google Scholar
Hertelendi, E, Gál, J, Paál, A, Fekete, S, Györffi, M, Gál, I, Kertész, Zs, Nagy, S. 1987. Stable isotope mass spectrometer. In: Wand, U, Strauch, G, editors. Fourth Working Meeting Isotopes in Nature. Leipzig: Akademie der Wissenschaften der DDR Zentralinstitut für Isotopen und Strahlenforschung. p 323–8.Google Scholar
Hertelendi, E, Csongor, É, Záborszky, L, Molnár, J, Gál, J, Györffi, M, Nagy, S. 1989. A counter system for high-precision 14C dating. Radiocarbon 31(3):399–406.Google Scholar
Hesshaimer, V. 1997. Tracing the global carbon cycle with bomb radiocarbon [PhD dissertation]. Heidelberg: University of Heidelberg.Google Scholar
Hsueh, DY, Krakauer, NY, Randerson, JT, Xu, X, Trumbore, SE, Southon, JR. 2007. Regional patterns of radiocarbon and fossil fuel-derived CO2 in surface air across North America. Geophysical Research Letters 34: L02816, doi:10.1029/2006GL027032.CrossRefGoogle Scholar
IPCC. 2007. Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. New York: Cambridge University Press.Google Scholar
Keeling, RF. 2008. Recording Earth's vital signs. Science 319(5871):1771–2.Google Scholar
Kyoto Protocol. 1997. Kyoto Protocol to the United Nations Framework Convention on Climate Change. UN Doc FCCC/CP/1997/7/Add.1, Dec. 10, 1997; 37 ILM 22 (1998). http://unfccc.int/essential_background/kyoto_protocol/background/items/1351.php.Google Scholar
Kuc, T, Rozanski, K, Zimnoch, M, Necki, J, Chmura, L, Jelen, D. 2007. Two decades of regular observations of 14CO2 and 13CO2 content in atmospheric carbon dioxide in central Europe: long-term changes of regional anthropogenic fossil CO2 emissions. Radiocarbon 49(2):807–16.Google Scholar
Levin, I, Hesshaimer, V. 2000. Radiocarbon—a unique tracer of global carbon cycle dynamics. Radiocarbon 42(1):69–80.CrossRefGoogle Scholar
Levin, I, Kromer, B. 2004. The tropospheric 14CO2 level in mid-latitudes of the Northern Hemisphere (1959–2003). Radiocarbon 46(3):1261–72.Google Scholar
Levin, I, Münnich, KO, Weiss, W. 1980. The effect of anthropogenic CO2 and 14C sources on the distribution of 14CO2 in the atmosphere. Radiocarbon 22(2):379–91.CrossRefGoogle Scholar
Levin, I, Schuchard, J, Kromer, B, Münnich, KO. 1989. The continental European Suess effect. Radiocarbon 31(3):431–40.Google Scholar
Levin, I, Kromer, B, Schmidt, M, Sartorius, H. 2003. A novel approach for independent budgeting of fossil fuel CO2 over Europe by 14CO2 observations. Geophysical Research Letters 30(23):2194, doi:10.1029/2003GL018477.Google Scholar
Levin, I, Hammer, S, Kromer, B, Meinhardt, F. 2008. Radiocarbon observations in atmospheric CO2: determining fossil fuel CO2 over Europe using Jungfraujoch observations as background. Science of the Total Environment 391(2–3):211–6.Google Scholar
Marland, G, Rotty, RM. 1984. Carbon dioxide emissions from fossil fuels: a procedure for estimation and results for 1950–1982. Tellus B 36(4):232–61.CrossRefGoogle Scholar
Molnár, M, Bujtás, T, Svingor, É, Futó, I, Svetlik, I. 2007. Monitoring of atmospheric excess 14C around Paks nuclear power plant, Hungary. Radiocarbon 49(2):1031–43.Google Scholar
Nakazawa, T, Ishizawa, M, Higuchi, K, Trivett, NBA. 1997. Two curve fitting methods applied to CO2 flask data. Environmetrics 8(3):197–218.Google Scholar
Nisbet, E. 2007. Earth monitoring: Cinderella science. Nature 450(7171):789–90.Google Scholar
Randerson, JT, Enting, IG, Schuur, EAG, Caldeira, K, Fung, IY. 2002. Seasonal and latitudinal variability of troposphere 14CO2: post bomb contributions from fossil fuels, oceans, the stratosphere, and the terrestrial biosphere. Global Biogeochemical Cycles 16(4):1112, doi:10.1029/2002GB001876.CrossRefGoogle Scholar
Riley, WJ, Hsueh, DY, Randerson, JT, Fischer, ML, Hatch, JG, Pataki, DE, Wang, W, Goulden, ML. 2008. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model. Journal of Geophysics Research 113: G04002. doi:10.1029/2007JG000625.Google Scholar
Stuiver, M, Polach, H. 1977. Discussion: reporting of 14C data. Radiocarbon 19(3):355–63.CrossRefGoogle Scholar
Stuiver, M, Quay, PD. 1981. Atmospheric 14C changes resulting from fossil fuel CO2 release and cosmic ray flux variability. Earth and Planetary Science Letters 53(3):349–62.CrossRefGoogle Scholar
Suess, HE. 1955. Radiocarbon concentration in modern wood. Science 122(3166):415–7.Google Scholar
Tans, PP, de Jong, AFM, Mook, WG. 1979. Natural atmospheric 14C variation and the Suess effect. Nature 280(5725):826–7.Google Scholar
Turnbull, JC, Miller, JB, Lehman, SJ, Tans, PP, Sparks, RJ, Southon, J. 2006. Comparison of 14CO2, CO, and SF6 as tracers for recently added fossil fuel CO2 in the atmosphere and implications for biological CO2 exchange. Geophysical Research Letters 33: L01817, doi:10.1029/2005GL024213.CrossRefGoogle Scholar
Uchrin, G, Hertelendi, E. 1992. Development of a reliable differential carbon-14 sampler for environmental air and NPP stack monitoring. Final Report of the OMFB contract No. 00193/1991. In Hungarian.Google Scholar
Veres, M, Hertelendi, E, Uchrin, G, Csaba, E, Barnabás, I, Ormai, P, Volent, G, Futó, I. 1995. Concentration of radiocarbon and its chemical forms in gaseous effluents, environmental air, nuclear waste and primary water of a pressurized water reactor power plant in Hungary. Radiocarbon 37(2):497–504.Google Scholar
Zhao, CL, Bakwin, PS, Tans, PP. 1997. A design for unattended monitoring of carbon dioxide on a very tall tower. Journal of Atmospheric and Oceanic Technology 14(5):1139–45.2.0.CO;2>CrossRefGoogle Scholar