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A Direct Electrical Method of Determining Latent Heat of Evaporation at the Boiling Point

Published online by Cambridge University Press:  15 September 2014

A. Cameron Smith
Affiliation:
Heriot Watt College, Edinburgh
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Extract

In this method the liquid of which the latent heat is to be determined is contained in a glass vessel which is suspended by a fine wire from the hook of a balance, and the amount of electrical energy is measured which is required for the evaporation of an observed mass. The electrical energy is supplied by a large current passing through a small resistance in the liquid itself. In order to reduce heat losses as much as possible, the vessel carrying the liquid and the resistance is completely surrounded by a doublewalled shield, which is filled by the saturated vapour of the liquid itself. The estimation of the electrical energy supplied necessitates tne measurement of the current, C (amperes), the resistance R (ohms), of the heating coil, and the time in seconds, T, during which the current flows. It is expressed by C2RT joules, and if M be the mass evaporated in gms., the latent heat expressed in joules per gm. becomes C2RT/M.

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1904

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