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Application of Sellmeier's Dynamical Theory to the Dark Lines D1, D2 produced by Sodium-Vapour

Published online by Cambridge University Press:  15 September 2014

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§ 1. For a perfectly definite mechanical representation of Sellmeier's theory, imagine for each molecule of sodium-vapour a spherical hollow in ether, lined with a thin rigid spherical shell, of mass equal to the mass of homogeneous ether which would fill the hollow. This rigid lining of the hollow we shall call the sheath of the molecule, or briefly the sheath. Within this put two rigid spherical shells, one inside the other, each movable and each repelled from the sheath with forces, or distribution of force, such that the centre of each is attracted towards the centre of the hollow with a force varying directly as the distance. These suppositions merely put two of Sellmeier's single-atom vibrators into one sheath.

§ 2. Imagine now a vast number of these diatomic molecules, equal and similar in every respect, to be distributed homogeneously through all the ether which we have to consider as containing sodium-vapour. In the first place, let the density of the vapour be so small that the distance between nearest centres is great in comparison with the diameter of each molecule. And in the first place also, let us consider light whose wave-length, is very large in comparison with the distance from centre to centre of nearest molecules. Subject to these conditions we have (Sellmeier's formula)

where m, m denote the ratios of the sums of the masses of one and the other of the movable shells of the diatomic molecules in any large volume of ether, to the mass of undisturbed ether filling the same volume; k, k the periods of vibration of one and the other of the two movable shells of one molecule, on the supposition that the sheath is held fixed; ve the velocity of light in pure undis turbed ether; vs the velocity of light of period τ in the sodium-vapour.

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Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1899

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References

page 524 note * Rowland, , Phil. Mag., 1887Google Scholar, first half-year; Bell, , Phil. Mag., 1888Google Scholar, first half-year.

page 524 note † “Michron” is the name which I have given to a special unit of time such that the velocity of light is one mikrom of space per michron of time, the mikrom being one millionth of a metre. The best determinations of the velocity of light in undisturbed ether give 300,000 kilometres, or 3 × 1014 mikroms, per second. This makes the michron ⅓ × 10−14 of a second.

page 525 note * A description of Professor Becquerel's experiments and results will be found in Comptes Rendus, Dec. 5, 1898, and Jan. 16, 1899.

page 525 note † Sellmeier, , Pogg. Ann., vol. cxlv. (1872) pp. 399, 520Google Scholar; vol. cxlvii. (1872) pp. 387, 525.