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3. The Action of Sulphide of Potassium upon Chloroform

Published online by Cambridge University Press:  15 September 2014

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Abstract

The author, after referring to the paper by Pfankuch, who obtained by the action of sulphide of potassium upon chloroform a crystalline substance which he held to be a compound of sulphide of potassium and sulphoform, and to the paper by Bouchardat on sulphoform, gives a detailed account of his own investigation.

The products formed when chloroform acts on an alcoholic solution of sulphide of potassium (prepared by dissolving caustic potash in alcohol, saturating one-half with sulphuretted hydrogen and then adding the other half) are sulphydrate of potassium and thioformiate of potassium (HCOSK, analogous in constitution to thiacetate). The action is probably as follows :— HCCI3 + 2K2S = 3KCI + HCSSK, and HCSSK + H2O = HCOSK + H2S, this sulphuretted hydrogen forming sulphydrate with the sulphide of potassium.

Type
Proceedings 1879–80
Copyright
Copyright © Royal Society of Edinburgh 1880

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References

page 425 note * Journal für pr. Chem. 〈2〉. 6, 99.

page 425 note † Journal de Pharmacie, xxiii. 12.