Hostname: page-component-7479d7b7d-t6hkb Total loading time: 0 Render date: 2024-07-11T19:20:44.961Z Has data issue: false hasContentIssue false
  • English
  • Français

IX.—The Synthesis of 8-Phenyl-7H-Benz[de]anthracene*

Published online by Cambridge University Press:  14 February 2012

Neil Campbell  and
Jamieson Walker
Neil Campbell
Affiliation:
Department of Chemistry, University of Edinburgh.
Jamieson Walker
Affiliation:
Department of Chemistry, University of Edinburgh.
Get access Rights & Permissions [Opens in a new window]

Extract

2-Benzylidene-2,3-dihydrophenalen-i-one with ethyl acetoacetate and sodium ethoxide yields four products depending on the concentration of the alkali. One of these, ethyl 7a,8,9,10-tetrahydro-10-oxo-8- phenyl-7H-benz[de]-anthracene-9-carboxylate has been converted into 8-phenyl-7H-benz[de]anthracene and its reduction with sodium borohydride or hydrogen in the presence of platinum oxide or Raney nickel presents points of interest.

Type
Research Article
Information
Proceedings of the Royal Society of Edinburgh Section A: Mathematics , Volume 69 , Issue 2 , 1971 , pp. 132 - 138
Copyright
Copyright © Royal Society of Edinburgh 1971

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

References to Literature

Anderson, D. M. W., Campbell, N., Leaver, D., and Stafford, W. H., 1959, J. Chem. Soc., 3992.CrossRefGoogle Scholar
Anderson, D. M. W., and Leaver, D., 1962, J. Chem. Soc., 450.CrossRefGoogle Scholar
Campbell, N., Neale, R. F., and Wall, R. A., 1959, J. Chem. Soc., 1409.CrossRefGoogle Scholar
Campbell, N., Neale, R. F., Swan, B. M., and Walker, J., 1966, J. Chem. Soc., 2011.Google Scholar
Cole, A. R. H., and Miller, C. T. A., 1959, J. Chem. Soc., 1224.CrossRefGoogle Scholar
Kuhn, L. P., van Schleyer, P., Bartinger, W. F., Eberson, L., 1964, J. Am. Chem. Soc., 86, 650.CrossRefGoogle Scholar