Hostname: page-component-76fb5796d-9pm4c Total loading time: 0 Render date: 2024-04-28T15:50:25.025Z Has data issue: false hasContentIssue false
  • English
  • Français

Powder diffraction data for fluorocomplexes of niobium IV: MNbF6 (M=Ca, Mg, Cd, Zn)

Published online by Cambridge University Press:  10 January 2013

Fabrice Goubard ,
Samuel Llorente ,
Joël Gaubicher ,
Daniel Bizot  and
Jean Chassaing
Fabrice Goubard
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Samuel Llorente
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Joël Gaubicher
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Daniel Bizot
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Jean Chassaing
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Get access Rights & Permissions [Opens in a new window]

Abstract

Four compounds in the hexafluoroniobates IV series MNbF6 (M=Ca, Mg, Cd, Zn) have been synthesized by solid-state reactions. CaNbF6, MgNbF6, and the “high temperature” form of CdNbF6 are isostructural with f.c. cubic NaSbF6 (space group Fm3m). ZnNbF6 and the room temperature form of CdNbF6 are isostructural with rhombohedral LiSbF6 (space group R3¯). Syntheses and powder diffraction data are reported.

Type
Research Article
Information
Powder Diffraction , Volume 13 , Issue 3 , September 1998 , pp. 163 - 165
Copyright
Copyright © Cambridge University Press 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bizot, D., Chassaing, J., Pannetier, J., Leblanc, M., Le Bail, A., and Ferey, G. (1986). “Fluorocomplexes of niobium IV: Part V the magnetic structure of MnNbF 6,”Solid State Commun. 58, 71.CrossRefGoogle Scholar
Burns, J. H. (1962). “The crystal structure of lithium fluoroantimonate (V),” Acta Crystallogr. 15, 1098.CrossRefGoogle Scholar
Chassaing, J., Bizot, D., and Monteil, C. (1983). “Propriétés magnétiques des fluoroniobates de structure dérivée de ReO 3. I. Les composés MgNbF 6 et CaNbF 6,”Rev. Chim. Miner. 20, 753.Google Scholar
Chassaing, J., de Bournonville, M. B., Bizot, D., and Quarton, M. (1991). “Structural and magnetic studies of Rb 2NbF 6 and Cs 2NbF 6,”Eur. J. Solid State Inorg. Chem. 28, 441.Google Scholar
Delobbe, V., Chassaing, J., Bizot, D., Quarton, M., Lacorre, P., Calage, Y., Leblanc, M., and Ferey, G. (1988). “Fluorocomplexes of niobium IV: Part VI Mossbauer study and magnetic structure of FeNbF 6,”J. Magn. Magn. Mater. 74, 165.Google Scholar
Goubard, F., Le Mercier, T., Chassaing, J., Bizot, D., Quarton, M., and André, G. (1995). “Fluorocomplexes of niobium IV: The magnetic structure of VNbF 6,”J. Magn. Magn. Mater. 146, 129.CrossRefGoogle Scholar
Mitchell, A. D., Hubbard, C. R., and Stalick, J. K. (1981). NBS*AIDS83 is a development of NBS*AIDS80, a FORTRAN Program for Crystallographic Data Evaluation Nat. Bur. Stand. (U.S.) Tech. Note 1141.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-patter indexing,” J. Appl. Crystallogr. 12, 60.Google Scholar
Teufer, G. (1956). “Die Kristallstruktur des natriumhexafluoroantimonats (V),” Acta Crystallogr. 9,539.CrossRefGoogle Scholar